913 resultados para Relative errors


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Manual diseñado para ayudar a los profesores de primaria a identificar en los niños sus conceptos erróneos en matemáticas. Considera tres perspectivas diferentes: el nivel del plan de estudios, el nivel del aula y el nivel de cada alumno. La comprensión de cómo los niños construyen su conocimiento matemático y los errores que cometen, permite identificar y explicar por qué ocurre el error. También permite adelantarse a conceptos erróneos habituales y a planificar las lecciones. Tiene un índice con referencias cruzadas para el programa nacional británico.

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Resumen tomado de la publicación

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Resumen basado en el de la publicaci??n

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Resumen basado en el de la publicaci??n

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To obtain a state-of-the-art benchmark potential energy surface (PES) for the archetypal oxidative addition of the methane C-H bond to the palladium atom, we have explored this PES using a hierarchical series of ab initio methods (Hartree-Fock, second-order Møller-Plesset perturbation theory, fourth-order Møller-Plesset perturbation theory with single, double and quadruple excitations, coupled cluster theory with single and double excitations (CCSD), and with triple excitations treated perturbatively [CCSD(T)]) and hybrid density functional theory using the B3LYP functional, in combination with a hierarchical series of ten Gaussian-type basis sets, up to g polarization. Relativistic effects are taken into account either through a relativistic effective core potential for palladium or through a full four-component all-electron approach. Counterpoise corrected relative energies of stationary points are converged to within 0.1-0.2 kcal/mol as a function of the basis-set size. Our best estimate of kinetic and thermodynamic parameters is -8.1 (-8.3) kcal/mol for the formation of the reactant complex, 5.8 (3.1) kcal/mol for the activation energy relative to the separate reactants, and 0.8 (-1.2) kcal/mol for the reaction energy (zero-point vibrational energy-corrected values in parentheses). This agrees well with available experimental data. Our work highlights the importance of sufficient higher angular momentum polarization functions, f and g, for correctly describing metal-d-electron correlation and, thus, for obtaining reliable relative energies. We show that standard basis sets, such as LANL2DZ+ 1f for palladium, are not sufficiently polarized for this purpose and lead to erroneous CCSD(T) results. B3LYP is associated with smaller basis set superposition errors and shows faster convergence with basis-set size but yields relative energies (in particular, a reaction barrier) that are ca. 3.5 kcal/mol higher than the corresponding CCSD(T) values

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This is a descriptive study that analyzes the spelling abilities as well as a specific spelling error made by children between the ages of 5 and 9 who are deaf and wear cochlear implants.

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This paper reviews a speech intelligibility experiment using the same subjects as both talkers and listeners.

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This paper discusses a study done to test tactile errors of localization abilities, with and without a Tactaid VII communication aid.

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This paper presents a study of common errors made during speech discrimination testing.

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This paper discusses a study to test two methods of hearing screening for infants--visual reinforcement audiometry and auditory brainstem responses.

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The goals of the present study are: to determine if dialogue journals are an effective activity within a balanced literacy program to improve on written language errors in students who are deaf and hard of hearing.

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Spontaneous writing samples of deaf children with cochlear implants were analyzed for syntactic errors and other descriptive characteristics. These results were compared to a small sample of writings from hearing children.