217 resultados para Inhomogeneous broadening


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A novel Littman-Metcalf external cavity laser diode array with two feedback mirrors is introduced. The line-width broadening effect caused by smile can be reduced by the novel external cavity. At the drive current of 16A, the line-width is narrowed to 0.1nm from free-running width of 1.6nm with output efficiency of 84%.

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在摩尔分数组成x(BaO),r(Ga2O),r(GeO2)为0.20,0.15,0.65的玻璃中,分别以摩尔分数0.05,0.10.0.15和0.20的BaF2替代BaO,研究了氟化物对玻璃折射率和光吸收性质的影响。结果表明,在玻璃中加入氟化物.玻璃折射率和色散降低,玻璃的紫外吸收边向短波侧迁移,而红外吸收边无明显变化。不含氟化物的氧化物玻璃中含有大量的OH基.这些OH基在2.24μm、2.97μm和4.23μm附近引起光吸收.在含氟化物的玻璃中,2.24μm的吸收峰消失,而2.97μm和4.23μm附近

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The flattening and broadening effects of Ga2O3, GeO2, P2O5 in TeO2-BaCO3-SrCO3- Nb2O5 (TBSN) glass system were studied. The results showed that P2O5 can broaden the vibration band in Raman spectra and Ga2O3, GeO2 can flatten the spectra compared with TBSN glass. And also, they can extend the main vibration band and decrease the vibration intensity of 730 cm-1 and 780 cm-1 nonbridging oxygen connected with Te. They also make for the decrease of flatness in 600-870 cm-1 vibration band and GeO2 has larger effect than Ga2O3 in weakening the vibration of nonbridging oxygen.

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Raman scattering experiments for nominally pure and uranium doped CaF2 single crystals were presented. In all crystals, the Raman active T_(2g) vibration mode of CaF2 was observed, whose frequency shift and full-width at half-maximum (FWHM) broadening correspond well with defects and impurities in CaF2 lattice. Additional Raman peaks develop in nominally pure CaF2 with high etch pits density and U^(6+):CaF2 crystals. Part of additional Raman peaks in the experimental results, which are assumed due to vibration modes from F- interstitials and vacancies, are in well agreement with the theoretical predications by employing the Green-function formulation.

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Nonpolar a-plane (1 1 2 0) ZnO films are fabricated on (3 0 2)gamma-LiAlO2 substrate by pulsed laser deposition. When substrate temperature is low, c-plane ZnO is dominant. As growth temperature increases to similar to 500 degrees C, pure (1 1 2 0)-oriented ZnO film can be obtained. The X-ray rocking curve of a-plane ZnO film broadens sharply when growth temperature is up to similar to 650 degrees C; such a broadening may be related to the anisotropic lateral growth rate of (1 12 0)-oriented ZnO grains. Atomic force microscopy reveals the surface morphology changes of ZnO films deposited at different temperatures. Raman spectra reveal that a compressive stress exists in the a-plane ZnO film. (C) 2007 Published by Elsevier B.V.

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探讨了双源共蒸法制备非均匀薄膜的堆积模型,并给出了非均匀膜的沉积速率与两种膜料沉积速率的关系.当两种膜料的沉积单分子大小近似相等或者小分子沉积速率远大于大分子时,可以近似认为混合介质膜的沉积速率等于两种膜料的沉积速率之和;当两种膜料的沉积单分子大小不满足近似相等且两种膜料的沉积速率可比较时,非均匀膜的沉积速率不能简单地用两种膜料的沉积速率之和来近似,它将随两种膜料沉积单分子的大小不同和沉积速率比不同按照不同的规律变化,并在文中给出了不同情况下的非均匀膜的沉积速率变化规律。

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基于非均匀膜理论提出一种存在微缺陷的介质基底的折射率分层模型,将基底依次分为表面层、亚表面层和体材料层,其中表面层和亚面层分别等效为折射率服从统计分布的非均匀膜,将它们分别再次细分为N1和N2个子层,每一子层均视为均匀介质膜.应用光学薄膜特征矩阵法对其进行理论分析,并对单层介质膜的光学性能进行数值计算.研究结果表明:基底的表面和亚表面微缺陷改变了薄膜和基底的等效折射率,导致了准Brewster角和组合反射率与理想情形的偏离.同时这些微缺陷也改变了光在薄膜和基底中的传播特性,因此反射相移和相位差均偏离理想情

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渐变折射率薄膜,又称为非均匀膜。利用德鲁德理论分析了混合介质膜的介电常量与各个膜料的介电常量之间的关系,介绍了共蒸法制备非均匀膜的制备机理。对混合膜的沉积速率为两种膜料的沉积速率之和的情况,分别从两种膜料的单分子体积是否相等和总的沉积速率是否为常数两个方面,探讨了双源共蒸法制备的非均匀膜的折射率分布规律与膜料的沉积速率之间的关系,并给出了几种常见的折射率分布如线性变化、正弦变化、指数变化和双曲变化规律的膜料沉积速率表达式。最后以混合介质膜的总沉积速率为常数、折射率按照线性变化为例进行了说明。

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ZrO2 thin films were prepared on BK7 glass substrates by electron beam evaporation deposition method. The influence of deposition rate varying from 1.2 to 6.3 nm s(-1) on surface morphology and other properties of ZrO2 films were examined. With increasing deposition rate, the surface defect density increased. The decrease in half width at full maximum in X-ray diffraction pattern with deposition rate indicates an increase in crystal dimension with increasing deposition rate. Electron beam deposited ZrO2 films are known to be inhomogeneous. From the change of the peak transmittance value, it can be deduced that the inhomogeneity of ZrO2 films strengthened gradually with increasing deposition rate. The type of surface defects changed from nodules to craters when the deposition rate was high enough.

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A model for refractive index of stratified dielectric substrate was put forward according to theories of inhomogeneous coatings. The substrate was divided into surface layer, subsurface layer and bulk layer along the normal direction of its surface. Both the surface layer (separated into N-1 sublayers of uniform thickness) and subsurface layer (separated into N-2 sublayers of uniform thickness), whose refractive indices have different statistical distributions, are equivalent to inhomogeneous coatings, respectively. And theoretical deduction was carried Out by employing characteristic matrix method of optical coatings. An example of mathematical calculation for optical properties of dielectric coatings had been presented. The computing results indicate that substrate subsurface defects can bring about additional bulk scattering and change propagation characteristic in thin film and Substrate. Therefore, reflectance, reflective phase shift and phase difference of an assembly of coatings and substrate deviate from ideal conditions. The model will provide some beneficial theory directions for improving optical properties of dielectric coatings via substrate surface modification. (c) 2005 Elsevier B.V. All rights reserved.

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A model for refractive index of stratified dielectric substrate was presented according to inhomogeneous coatings theories. The substrate was divided into surface layer, subsurface layer and bulk layer along the normal direction of its surface. The former two layers were equivalent to inhomogeneous coatings. Theoretical deduction was executed by employing the characteristic matrix method of optical coatings, and one mathematical calculation example was presented. The results indicate that reflectance, reflective phase shift and phase difference of polarized light deviate from ideal conditions. It shows that substrate microdefects can induce volume scattering and change propagation characteristic of light both in coatings and substrate. (c) 2005 Elsevier GmbH. All rights reserved.

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从德鲁德理论出发,对多元共蒸法镀制的非均匀膜的折射率分布与沉积速率的关系进行了探讨;然后利用计算机辅助模拟,对德鲁德分布非均匀光学薄膜,从单周期和多周期、正变和负变、完整周期和存在半周期几个方面对其光学特性进行了系统分析.研究发现:其透射率的极小值和周期数的关系遵从周期数的三次多项式衰减规律,不同规律的德鲁德分布非均匀膜可用来设计不同功能的滤光片.

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对双源线性共蒸法制备的非均匀薄膜折射率分布与光学特性的关系作了探讨,并与均匀介质膜的光学特性作了对比;从折射率正变和负变两个方面.讨论了混合介质膜折射率不同变化规律对光学性能带来的影响;讨论了厚度误差和折射率极值误差对非均匀膜光学性能的影响。结果发现:折射率变化规律误差主要对非均匀膜的应用波段范围产生影响,而膜层厚度误差和折射率极值误差超过一定值时,将对薄膜光学特性产生重要影响。

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TiO2 single layers and TiO2/SiO2 high reflectors (HR) are prepared by electron beam evaporation at different TiO2 deposition rates. It is found that the changes of properties of TiO2 films with the increase of rate, such as the increase of refractive index and extinction coefficient and the decrease of physical thickness, lead to the spectrum shift and reflectivity bandwidth broadening of HR together with the increase of absorption and decrease of laser-induced damage threshold. The damages are found of different morphologies: a shallow pit to a seriously delaminated and deep crater, and the different amorphous-to-anatase-to-rutile phase transition processes detected by Raman study. The frequency shift of Raman vibration mode correlates with the strain in. film. Energy dispersive X-ray analysis reveals that impurities and non-stoichiometric defects are two absorption initiations resulting to the laser-induced transformation. (C) 2008 Elsevier B. V. All rights reserved.

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The phytoplankton community in Lake Dianchi (Yunnan Province, Southwestern China) is dominated in April by a bloom of Aphanizomenon, that disappears Suddenly and is displaced by a Microcystis bloom in May. The reasons for the rapid bloom disappearance phenomenon and the temporal variability in the composition of phytoplankton assemblages are poorly understood. Cell growth, ultrastructure and physiological changes were examined in cultures of Aphanizomenon sp. DC01 isolated from Lake Dianchi exposed to different closes of rnicrocystin-RR (MC-RR) produced by the Microcystis bloom. MC-RR concentrations above 100 mu g L-1 markedly inhibited the pigment (chlorophyll-a, phycocyanin) synthesis and caused an increase of soluble carbohydrate and protein contents and nitrate reductase activity of toxin-treated blue-green algae. A drastic. reduction in photochemical efficiency of PSII (Fv/Fm) was also found. Morphological examinationn showed that the Aphanizomenon filaments disintegrated and file cells lysed gradually after 48 h Of toxin exposure. Transmission electron microscopy revealed that cellular inclusions of stressed cells almost leaked out completely and the cell membranes were grossly damaged. These findings demonstrate the allelopathic activity of Microcystis aeruginosa inducing physiological stress and cell death of Aphanizomenon sp. DC01 Although the active concentrations of microcystin were rather high, we propose that microcystin may function as allelopathic Substance due to inhomogeneous toxin concentrations close to Microcystis cells. Hence, it may play a role in species Succession of Aphanizomenon and Microcystis in Lake Dianchi.