242 resultados para 219
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采用时空互代法,以黄土丘陵区纸坊沟流域生态恢复过程中不同年限的人工柠条和沙棘林为研究对象,选取坡耕地和天然侧柏林为对照,分析了植被恢复过程中土壤有机碳(TOC)、活性有机碳(LOC)、非活性有机碳(NLOC)及碳库管理指数的演变特征。结果表明,侵蚀环境下的坡耕地由于人为干扰,土壤碳库含量偏低,退耕营造柠条林可以显著增加土壤碳库各组分含量,并随恢复年限呈显著线性关系,25 a时TOC、LOC和NLOC分别较坡耕地增加271%、144%和204%,仅为侧柏林的32%、30%和29%,碳库指数和碳库管理指数较坡耕地明显增加,增幅分别达到144%和108%,仅为侧柏林的28%和43%;不同灌木林对土壤碳库管理的改善作用不同,恢复年限相同的沙棘林土壤碳库组分含量和管理指数明显高于柠条林,坡耕地营造灌木林后土壤经营和管理水平得到了显著改善,土壤系统向着良性方向转变。相关性分析表明有机碳、活性有机碳、非活性有机碳、碳库指数、碳库管理指数与土壤主要肥力因子相关性极其密切,可以作为反映生态恢复过程土壤质量演变的指标。
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采用时空互代法,以典型侵蚀环境纸坊沟流域生态恢复过程中不同年限的人工刺槐林为研究对象,选取坡耕地和天然侧柏林为参照,分析了植被恢复过程中土壤水稳性团聚体变化规律及其与土壤养分状况之间的相互关系。结果表明,侵蚀环境下的坡耕地由于人为耕作干扰,土壤水稳性团聚体含量低下,抗蚀性能较差。营造刺槐林前5 a土壤水稳性团聚体含量较坡耕地显著快速增加,随后增幅变缓,成对数增长,恢复25 a后土壤水稳性团聚体含量已经达到天然侧柏林水平。在植被恢复过程中土壤小粒径的水稳性团聚体逐渐聚集转变形成大粒径的团聚体。相关性分析和回归分析表明,植被恢复过程中>0.25 mm土壤水稳性团聚体与有机碳、全氮、碱解氮、速效钾、容重等相关性达到显著(p<0.05)或极显著水平(p<0.01),与全磷和速效磷相关性较弱。坡耕地退耕营造刺槐林后可以减少人为干扰,增加碳素和氮素供给,提高水稳性团聚体含量,使土壤抗蚀性能提高。
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本文通过LnCl_3·nTHF和[C_5H_4(SiMe_3)]Na反应得到了两类配合物[C_5H_4(SiMe_3)] LnCl_2·nTHF (Ln = Nd,Sm,Gd;n = 0,1,2)、[C_5H_4(SiMe_3)] LnCl_2·HCl·nTHF (Ln = Nd,Sm,Gd;n = 1,2)。通过元素分析、红外分析、质谱、核磁共振和热重分析确定了配合物的分子组成,特别是带氯化氢的产品在红外光谱中有1250 cm~(-1),835 cm~(-1),748 cm~(-1)自的三甲基硅基特征吸收峰。对氯化稀上进行了结构分析,结果发现LnCl_3·4THF (Ln = Sm,Gd)是与NdCl_3·4THF之间存在着变态关系。GdCl_3·4THF。晶体属单斜晶系,空间群为P21/C,晶胞参数为a = 30.765(7),b = 8.219(3),C = 17.534(3)A~·,β = 93.71(2)°;SmCl_3·4THF。晶体属单斜晶系,空间群为P21/C,晶胞参数为a = 30.921(13),b = 8.287(7),C = 17.665(8),β = 94.17(4)°。LnCl_3·4THF的单位晶胞中存在着八个分子,每对分子互相等同,但每对分子内部两个分子之间互不等同。SmCl_3·2THF·DME晶体属单斜晶系,空间群为P21/a,晶胞参数为a = 13.547(8),b = 8.607(4),C = 16.029(9)A°,β = 90.53(5)°。铲原子与三个氯原子。两个四氢呋喃中的氧原子以及DME中的两个氧原子键合,形成七配位的配合物,但是配位多面体不是理想的五角双锥,而是形成了比五角双锥(D_(5h))对称性更低的多面体(C_(3v))。它能看作是在正八面体的一个面的中心加上第七个原子的结果,而且这八面体主要受到决定上述那个面的三个原子伸展开的畸变。在制备C_5H_5SiMe_3时,如果不用减压蒸馏,而在常压下直接蒸馏,则得到的不是C_5H_5SiMe_3而是它的二聚体(C_5H_5SiMe_3)_2。用红外光谱和核磁共振确定了它的组成和结构,特别是在1650 cm~(-1)处出现(C_5H_5SiMe_3)_2的孤立双键吸收峰。用C_5H_5SiMe_3和Ee(CO)_5回流反应制得了[C_5H_4(SiMe_3) Ee(CO)_2]_2。经过元素分析,红外光谱,质谱,顺磁共振确定了配合物的组成,红外光谱中有桥羰基的吸收峰,质谱图中498的离子峰的出现标志着上述二聚体的存在。用[C_5H_5Fe(CO)_2]_2作为制备双金属配合物的原料,用Na/Hg并还原[C_5H_5Fe(CO)_2]_2。反应时间为6-7小时得到中间体[C_5H_5Fe(CO)_2]_2Na·4THF的深紫红色晶体。反应时间加长,中间体被破坏,反应到15小时时生成了[C_5H_5Fe(CO)_2]Na·TMEDA的黄色晶体,特别是中间体的获得及晶体结构的测定对我们解释反应的机理非常重要。[C_5H_5Fe(CO)_2]_2Na·4THF为单斜晶系,空间群为P21/n,晶胞参数为a = 10.155(5),b = 17.121(4),C = 18.667(6)A°,β = 97.61(3)°,V = 3216.9A°~3, 2 = 4。铁的配位数为七,钠的配位数为六,钠离子和桥连羰基氧以配位键结合,每个钠离子连结着两个[C_5H_5Fe(CO)_2]_2~-,而每个[C_5H_5Fe(CO)_2]_2~-又连结着两个钠离子,组成一个无限链状分子,键状分子间以Van de W力结合。[C_5H_5Fe(CO)_2]Na·TMEDA正交晶系,空间群为P_(2,2,2,)。晶胞参数为a = 6.001(4),b = 10.644(6),C = 24.214(11)A~·。α = β = r = 90°。z = 4 V = 1546·7A°~3,铁的配位数为五。钠的配位数为四,钠离子和羰基氧以配位键结合,每个钠离子连结着两个[C_5H_5Fe(CO)_2]~-,每个[C_5H_5Fe(CO)_2]~-又连结着两个钠离子,体系就是以这种连结方式或正负电荷交替的形式无限螺旋分子,每个链节存在着两个[C_5H_5Fe(CO)_2]Na·TMEDA分子,链节的长度为a轴的轴长,说明螺旋分子以a轴轴长向上平移。用LnCl_3·nTHF和[C_5H_5Fe(CO)_2]Na反应制得了[C_5H_5Fe(CO)_2] LnCl_2·nTHF (Ln = Nd, Sm, Gd; n = 1, 2),用[C_5H_5Fe(CO)_2] LnCl_2和[C_5H_4(SiMe_3)]Na或用[C_5H-4(SiMe_3)] LnCl_2和[C_5H_5Fe(CO)_2]Na得到[C_5H_5Fe(CO)_2] [C_5H_4(SiMe_3)] LnCl·nTHF (Ln = Nd, Sm, Gd; n = 0, 1, 3),配合物[C_5H_5Fe(CO)_2] LnCl_2·nTHF及[C_5H_5Fe(CO)_2] [C_5H_4(SiMe_3)] LnCl·nTHF中存在着2000 cm~(-1)左右的终端羰基吸收峰及1766 cm~(-1)左右的桥连羰基吸收峰。说明稀土和铁之间是以羰基相连的。在TOTOE质谱仪上,配合物[C_5H_5Fe(CO)_2]Gd~·Cl·THF出现[C_5H_5Fe(CO)]GdCl_2、[Fe(CO)_2] Gd~+Cl_2的离子峰,配合物[C_5H_5Fe(CO)_2]-[C_5H_4(SiMe_3)] GdCl·THF出现[C_5H_5Fe(CO)_2] [C_5H_4]Gd~+Cl、[C_5H_5Fe(CO)_2]Gd~+Cl·[C_5H_4C(SiMe_3)] Gd~+Cl等离子峰。所有稀土有机配合物都溶于四氢呋喃、苯,对空气和水敏感。
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目的 了解河南省艾滋病病毒Ⅰ型( HIV21) 新近感染者的耐药情况。方法 2006 年8 月- 2007 年6 月,在河南省艾滋病自愿咨询(VCT) 检测点发现的未进行抗病毒治疗的HIV21 感染者,以酶联免疫吸附试验初筛、 蛋白印迹试验确认HIV21 感染,BED2CEIA 方法检测新近感染。检出的新近感染样品进行基因型耐药检测,提取 血浆中RNA ,套式聚合酶链反应(Nested2PCR) 扩增HIV21 pol 基因区,PCR 产物双脱氧法测序,所得序列与Los Alamos HIV 标准株序列比对,构建系统进化树分析亚型;利用Stanford HIVdb Drug Resistance Database 分析耐 药相关突变(DRM) 和耐药情况。结果 共检出HIV21 新近感染39 例,扩增测序有34 例新近感染样品分析成功。 亚型分析结果为B′亚型32 例(9411 %) ,CRF01_AE 重组亚型1 例(219 %) ,C 亚型1 例(219 %) 。未发现蛋白酶抑 制剂( PI) 主要DRM ,检测到10 例(2914 %) 存在PI 次要DRM;未发现核苷类逆转录酶抑制剂(NRTI) 的DRM;3 例(818 %) 存在非核苷类逆转录酶抑制剂(NNRTI) 的DRM。耐药分析显示,有2 例(519 %) 对NNRTI 类药物耐 药。结论 目前河南省HIV21 新近感染人群中耐药状况处于中等水平,有必要加强HIV21 的耐药监测。
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对红河断裂带及其邻区219个地震的相关数据进行震源机制解分析,阐述了红河
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重新系统描述了蜂窝蛋科蜂窝蛋属的模式蛋种宁夏蜂窝蛋(Faveoloolithus ningxiaensis)和杨氏蛋属的模式蛋种夏馆杨氏蛋(Youngoolithus xiaguanensis), 并记述了产自浙江天台的蜂窝蛋科新材料,建立一个新的蛋属——副蜂窝蛋属(Parafaveoloolithus), 及3个新的蛋种——Parafaveoloolithus microporus, P. macroporus和P. tiansicunensis。根据赵资奎1994年提出的恐龙蛋分类中具有鉴定意义的几个特征,重新讨论了现有蜂窝蛋的分类地位,提出杨氏蛋属应当提升为科一级的分类单元,总结了蜂窝蛋科内属级和种级分类单元的主要鉴定特征以及蜂窝蛋类的鉴定方法。
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The oxidation dynamics and morphology of undoped and heavily phosphorus-doped polycrystalline silicon films oxidized at a wide temperature and time range in dry and wet O2 atmosphere have been investigated. It is shown that the oxidation rates of polycrystalline silicon films are different from that of single-crystal silicon when the oxidation temperature is below 1000-degrees-C. There is a characteristic oxidation time, t(c), under which the undoped polysilicon oxide is not only thicker than that of (100)-oriented single-crystal silicon, but also thicker than that of (111)-oriented single-crystal silicon. For phosphorus-doped polycrystalline silicon films, the oxide thickness is thinner not only than that of (111)-oriented, single-crystal silicon, but also thinner than that of (100)-oriented, single-crystal silicon. According to TEM cross-sectional studies, these characteristics are due to the enhanced oxidation at grain boundaries of polycrystalline silicon films. A stress-enhanced oxidation model has been proposed and used to explain successfully the enhanced oxidation at grain boundaries of polycrystalline silicon films. Using this model, the oxidation linear rate constant of polysilicon (B/A)poly has been calculated and used in the modeling of the oxidation dynamics. The model results are in good agreement with the experimental data over the entire temperature and time ranges studied.
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The electronic structure of a microporous titanosilicate framework, ETS-10 is calculated by means of a first-principles self-consistent method. It is shown that without the inclusion of the alkali atoms whose positions in the framework are unknown, ETS-10 is an electron deficient system with 32 electrons per unit cell missing at the top of an otherwise semiconductor-like band structure. The calculated density of slates are resolved into partial components. It is shown that the states of the missing electrons primarily originate from the Ti-O bond. The local density of states of the Ti-3d orbitals in the ETS-10 framework is quite different from the perovskite BaTiO3. The possibilities of ETS-10 crystal being ferroelectric or having other interesting properties are discussed.
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The surface reconstruction on Si(337) at room temperature has been studied by low energy electron diffraction (LEED). It has been found that: (I) the Si(337) gave a clear LEED pattern which indicates the existence of another high index stable surface besides Si(113); (II) in addition to a strong Si(337)-(1 X 1), we observed for the first time a (2 X 1) LEED pattern indicating a surface reconstruction along the [1(1) over bar0$] direction; (III) a surface model has been proposed for the observed Si(337)-(2 X 1) structure.
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Experimental study of the reverse annealing of the effective concentration of ionized space charges (N-eff, also called effective doping or impurity concentration) of neutron irradiated high resistivity silicon detectors fabricated on wafers with various thermal oxides has been conducted at room temperature (RT) and elevated temperature (ET). Various thermal oxidations with temperatures ranging from 975 degrees C to 1200 degrees C with and without trichlorethane (TCA), which result in different concentrations of oxygen and carbon impurities, have been used. It has been found that, the RT annealing of the N-eff is hindered initially (t < 42 days after the radiation) for detectors made on the oxides with high carbon concentrations, and there was no carbon effect on the long term (t > 42 days after the radiation) N-eff reverse annealing. No apparent effect of oxygen on the stability of N-eff has been observed at RT. At elevated temperature (80 degrees C), no significant difference in annealing behavior has been found for detectors fabricated on silicon wafers with various thermal oxides. It is apparent that for the initial stages (first and/or second) of N-eff reverse annealing, there may tie no dependence on the oxygen and carbon concentrations in the ranges studied.
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近年来,集成电路制造工艺的巨大提高使得FPGA有能力实现大的数字系统电路。这些大的系统通常需要大量的存储器以存储数据。很多FPGA生产商已经推出了含有大的嵌入式存储器的FPGA芯片。然而,大多数学术方面的CAD工具只针对于同质的FPGA结构(即只包括逻辑模块和布线通道的FPGA结构)。FPGA的布线结构通常被表示为RRG(布线资源图)。本文将介绍一种包含嵌入式存储器模块的FPGA的灵活结构以及一种建立RRG的方法。文中我们对VPR(versatile placing and routing)进行了改进,使得VPR可以处理包含嵌入式存储器结构的FPGA的布局布线问题,同时保持了VPR的灵活性。
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In this paper, we present simulation results of an electrooptical variable optical attenuator (VOA) inte-grated in silicon-on-insulator waveguide. The device is functionally based on free carriers absorption toachieve attenuation. Beam propagation method (BPM) and two-dimensional semiconductor device simu-lation tool PISCES-Ⅱ were used to analyze the dc and transient characteristics of the device. The devicehas a response time (including rise time and fall time) less than 200 ns, much faster than the thermoopticand micro-electromechanical systems (MEMSs) based VOAs.