共溅射和离子注入制备的SiO_2（Eu）薄膜中Eu~（3＋）到Eu~（2＋）的转变

采用共溅射方法和Eu离子注入热生长的SiO_2方法得到SiO_2(Eu)薄膜，Eu离子的浓度为4%和0.5%。对样品X射线吸收近边结构(XANES)的研究和分析表明，在高温氮气中发生了Eu~(3+)向Eu~(2+)的转变。SiO_2(Eu)薄膜高温氮气退火下蓝光的发射证明了这一结论。

Three-body force effect on P-3 F-2 neutron superfluidity in neutron matter, neutron star matter, and neutron stars

We investigate the effect of microscopic three-body forces on the P-3 F-2 neutron superfluidity in neutron matter, beta-stable neutron star matter, and neutron stars by using the BCS theory and the Brueckner-Hartree-Fock approach. We adopt the Argonne V18 potential supplemented with a microscopic three-body force as the realistic nucleon-nucleon interaction. We have concentrated on studying the three-body force effect on the P-3 F-2 neutron pairing gap. It is found that the three-body force effect considerably enhances the P-3 F-2 neutron superfluidity in neutron star matter and neutron stars.

catena-Poly[diammonium [diaquabis(pyridine-2,4-dicarboxylato-kappa N-2,O-2)cuprate(II)] [[diaquacopper(II)]-mu-pyridine-2,4-dicarboxylato-kappa N-3,O-2:O-2 '-[tetraaquacadmium(II)]-mu-pyridine-2,4-dicarboxylato-kappa O-3(2):N,O-2 '] hexahydrate]

The title mixed-metal complex, {(NH4)(2)[Cu(C7H3NO4)(2)(H2O)(2)][CdCu(C7H3NO4)(2)(H2O)(6)]center dot 6H(2)O}(n), contains one octahedrally coordinated Cd-II center and two octahedrally coordinated Cu-II centers, each lying on an inversion center. The two Cu-II atoms are each coordinated by two O atoms and two N atoms from two 2,4-pydc (2,4-H(2)pydc = pyridine-2,4-dicarboxylic acid) ligands in the equatorial plane and two water molecules at the axial sites, thus producing two crystallographically independent [Cu(2,4-pydc)(2)(H2O)(2)](2-) metalloligands. One metalloligand exists as a discrete anion and the other connects the Cd(H2O)(4) units, forming a neutral chain.

One-step synthesis of Ru(2,2 '-bipyridine)(3)Cl-2-immobilized silica nanoparticles for use in electrogenerated chemiluminescence detection

One-step synthesis of Ru (bpy)(3) Cl-2-immobilized (bpy = 2,2'-bipyridine) silica nanoparticles (Ru-silica nanoparticles) for use in electrogenerated-chemiluminescence (ECL) detection is reported. Ru-silica nanoparticles are prepared by using the Stober method. Compared with free Ru(bpy)(3)Cl-2, Ru-silica nanoparticles are seen to exhibit a red-shift of the UV-vis absorbance peak and a longer fluorescence lifetime, which are attributed to the electrostatic interaction of Ru(bpy)(3)(2+) and silica. Because silica nanoparticles are used as immobilization matrices, the surfaces of Ru-silica nanoparticles are easily modified or functionalized via the assembly of other nanoparticles, such as Au. For ECL detection, Au-colloid-modified Ru-silica nanoparticles are immobilized on a 3-mercaptopropyl-trimethoxysilane-modified indium tin oxide electrode surface by Au-S interaction; the surface concentration of electroactive Ru(bpy)(3)Cl-2 is obviously higher than that in silica films.

Phase conversion and spectral properties of long lasting phosphor Zn-3 (PO4)(2): Mn2+, Ga3+

A red long lasting phosphor Zn-3(PO4)(2): Mn2+ Ga3+ (ZPMG) was prepared by ceramic method, and phase conversion and spectral properties were investigated. Results indicated that the phase conversion from alpha-Zn-3(PO4), beta-Zn-3(PO4)(2) to gamma-Zn-3(PO4)(2) occurs with different manganese concentration incorporated and sinter process. The structural change induced by the phase transformation results in a remarkable difference in the spectral properties. The possible luminescence mechanism for this red LLP with different forms has been illustrated.

Citrate-gel synthesis and luminescent properties of alpha-Zn-3(PO4)(2) doped with Eu3+

By using inorganic salts as raw materials and citric acid as complexing agent, alpha-Zn-3(PO4)(2) and Eu3+ doped alpha-Zn-3(PO4)(2) phosphor powders were prepared by a citrate-gel process. X-ray diffraction, (XRD), TG - DTA, FT - IR and luminescence excitation and emission spectra were used to characterize the resulting products. The results of XRD reveal that the powders begin to crystallize at 500 degreesC and pure alpha-Zn-3(PO4)(2) phase is obtained at 800 degreesC. And the results of XRD reveal that Eu3+ exists Lis EoPO(4) ill the powder. In the phosphor powders, the Eu3+ shows its characteristic red-orange (592 nm, D-5(0) - F-7(1)) emission and has no quenching concentration.

3{1-[2-(-3-羟基-1-甲基-2-亚丁烯氨基)-苯亚氨基]-乙基}4-甲硫基-2,4-戊二烯-2-醇的不对称Schiff碱镍(Ⅱ)配合物的合成、结构和性质

由 5-(2-乙酰基-1-甲硫基-3-羰基-亚丁基)-丙二酸亚异丙酯 (1)与邻苯二胺及乙酸镍()经一步反应合成了3{1-[2-( -3-羟基-1-甲基-2-亚丁烯氨基)-苯亚氨基 ]-乙基} 4-甲硫基-2,4-戊二烯-2-醇(3)的不对称四齿 Schiff碱镍()配合物(2),X射线衍射结果表明,配合物 2属单斜晶系,P21/C空间群.a=1.1476(2)nm,b=1.1782(2)nm,c=1.4810(3)nm;β=111.73(2)°,V=1.8602(7)nm3,Z=4,Rf=0.0535.电化学(循环伏安)测定结果表明,该配合物在测定条件下(阳极峰电位为1.1)发生了不可逆的氧化-还原反应.

BaLiF_3∶Eu,Gd中Gd~(3+)→Eu~(2+)的能量传递

研究了 Ba Li F3中 Gd3+和 Eu2 +的光谱性质及 Gd3+对 Eu2 +的能量传递过程 ,讨论了传递机理 .Gd3+的含量 (物质的量分数 )为 0 .3 %时 ,传递效率最高 ,传递几率 PSA=1 .3 5× 1 0 5s- 1 .当 Gd3+的含量高于 0 .3 %时 ,由于 Gd3+ 和 Eu2 + 竞争吸收 Gd3+ 占优势 ,增加 Gd3+ 含量 ,竞争吸收比相应增加 ,Eu2 + 自身吸收光子数目减少 ,发射强度降低

ABF_3:Eu,Gd(A:K,Li;B:Ba,Mg)中Gd~(3+)→Eu~(2+)的能量传递

通过高温固相反应法,在高纯N_2气氛中合成了BaLiF_3,KMgF_3中单掺和双掺Eu,Gd的ABF_3型复合氟化物。研究了各类掺杂体系的光谱特性,观察到了Gd~(3+)→Eu~(2+)的能量传递,分析了能量传递过程,探讨了能量传递机理,并讨论了Gd~(3+)和Eu~(2+)的取代格位。

Synthesis and characterization of a novel hybrid single crystal [Ga-3(PO4)(3)F-2]H3O center dot (H3NCH2CH2)(2)NH2

A novel three-dimensional fluorinated gallium phosphate has been hydrothermally,synthesized by using diethylenetriamine as an organic structure-directing agent. X-ray single crystal structure analysis indicates this compound crystallizes in the orthorhombic space group P-bca, a = 1. 605 6 (7) nm, b = 1.011 4 (4) nm, c=1. 854 6(5) nm, V=3. 011 6(19) nm(3), Z=4. The three-dimensional framework based on linkage of corner-sharing polyhedron PO4, GaO4F and GaO4F2 delimit ten-ring channels along b axis in which the triply protonated amines are located serving as charge compensating guests and supporters.

BaY_2F_8∶Ce,Eu中Ce~(3+)→Eu~(2+)的能量传递和Ce~(3+)→Eu~(3+)的电子转移

采用高温固相反应法制备了 Ba Y2 F8∶ Ce3 + ,Ba Y2 F8∶ Eu2 + 和 Ba Y2 F8∶ Ce,Eu,测定了它们的激发、发射和漫反射光谱 .首次发现并研究了在 Ba Y2 F8共掺 Ce F3 和 Eu F3 体系中存在 Ce3 + → Eu2 + 的能量传递和Ce3 +→ Eu3 +的电子转移两种过程及其竞争 .根据光谱数据 ,讨论了 Ce4 +的可能取代格位

KZnF_3中Ce~(3+)→Eu~(2+)的能量传递

研究了KZnF3中Ce3+和Eu2+的光谱特性，在共掺Ce3+和Eu2+的体系中，观察到了Ce3+对Eu2+的能量传递过程．计算了能量传递的鼻子效率，探讨了能量传递机理．研究发现，Ce3+的存在有利于Eu2+的f-f跃迁线状发射.