El volcanismo neógeno-cuaternario de Catalunya: caracteres estructurales, petrológicos y geodinámicos

El volcanismo neógenocuaternario de Catalunya está asociado al sistema de fracturas escalonadas, de orientación preferente SW-NE y NW-SE, que condiciona también las depresiones tectónicas o fosas neógenas. Las dataciones radiométricas ponen de manifiesto una actividad volcánica entre 10 y 0.1 m.a., localizándose las erupciones más antiguas en la fosa del Empordà, mientras que el volcanismo cuaternario se concentra en las proximidades de Olot (La Garrotxa). El magmatismo es de carácter alcalino, con términos exclusivamente básicos (basanitas), salvo un afloramiento traquítico. Son frecuentes los xenolitos de rocas sedimentarias y plutónicas básicas y ácidas, presentando estos últimos el mayor grado de transformación. Los caracteres estructurales, geoquímicos y mineralógicos, junto a las relaciones isotópicas Sr8YlSr86 apoyan un origen profundo, subcrustal, del magma, y definen un volcanismo intraplaca como el que corresponde a un modelo de rift embrionario sin atenuación litosférica y con escasas manifestacion

Preparation of benzolactams by Pd(II)-catalyzed carbonylation of N-unprotected arylethylamines

An unprecedented NH2-directed Pd(II)-catalytic carbonylation of quaternary aromatic α -amino esters to yield 6-membered 10 benzolactams has been developed. The reaction shows a strong bias to 6-membered lactams over 5-membered ones. The steric hindrance around the amino group seems to be pivotal for the success of the process.

Haciendo visible lo invisible : Peralada, un estudio de caso

Las diferencias entre municipios rurales y urbanos definen escenarios diferentes donde las personas mayores se enfrentan a necesidades también diferentes. En general, la falta de estudios sobre el envejecimiento entendido como un reto y que, además, asuman la variabilidad del proceso, pone al descubierto la necesidad particular de investigaciones que busquen comprender cómo viven los mayores en entornos como el rural. Este artículo describe nuestra experiencia investigadora en un municipio de la Comarca del Alt Empordà, Cataluña, España. El objetivo principal era entender a las personas mayores establecidas en entornos rurales a través de las situaciones de su vida cotidiana, identificar sus necesidades, contribuir a su autonomía funcional y elaborar propuestas de intervención. La muestra la formaron las 223 personas mayores residentes en el municipio de Peralada y Vilanova de la Muga. Los datos se recogieron utilizando los cuestionarios de Barber, Pfeifer y Barthel, y se realizaron entrevistas en profundidad. Los resultados proporcionan cinco claves relevantes al plantear intervenciones en el contexto rural. Básicamente, la intervención profesional en este ámbito debe ir orientada a mantener y fortalecer las redes de apoyo naturales funcionales en el territorio

Clinico-Pathological discrepancies in the Diagnosis of Causes of Maternal Death in Sub-Saharan Africa: Retrospective Analysis

Background Maternal mortality is a major public-health problem in developing countries. Extreme differences in maternal mortality rates between developed and developing countries indicate that most of these deaths are preventable. Most information on the causes of maternal death in these areas is based on clinical records and verbal autopsies. Clinical diagnostic errors may play a significant role in this problem and might also have major implications for the evaluation of current estimations of causes of maternal death. Methods and Findings A retrospective analysis of clinico-pathologic correlation was carried out, using necropsy as the gold standard for diagnosis. All maternal autopsies (n ¼ 139) during the period from October 2002 to December 2004 at the Maputo Central Hospital, Mozambique were included and major diagnostic discrepancies were analyzed (i.e., those involving the cause of death). Major diagnostic errors were detected in 56 (40.3%) maternal deaths. A high rate of false negative diagnoses was observed for infectious diseases, which showed sensitivities under 50%: HIV/AIDS-related conditions (33.3%), pyogenic bronchopneumonia (35.3%), pyogenic meningitis (40.0%), and puerperal septicemia (50.0%). Eclampsia, was the main source of false positive diagnoses, showing a low predictive positive value (42.9%). Conclusions Clinico-pathological discrepancies may have a significant impact on maternal mortality in sub-Saharan Africa and question the validity of reports based on clinical data or verbal autopsies. Increasing clinical awareness of the impact of obstetric and nonobstetric infections with their inclusion in the differential diagnosis, together with a thorough evaluation of cases clinically thought to be eclampsia, could have a significant impact on the reduction of maternal mortality.

The Rose Bengal test in human brucellosis: a neglected test for the diagnosis of a neglected disease

Brucellosis is a highly contagious zoonosis affecting livestock and human beings. The human disease lacks pathognomonic symptoms and laboratory tests are essential for its diagnosis. However, most tests are difficult to implement in the areas and countries were brucellosis is endemic. Here, we compared the simple and cheap Rose Bengal Test (RBT) with serum agglutination, Coombs, competitive ELISA, Brucellacapt, lateral flow immunochromatography for IgM and IgG detection and immunoprecipitation with Brucella proteins. We tested 208 sera from patients with brucellosis proved by bacteriological isolation, 20 contacts with no brucellosis, and 1559 sera of persons with no recent contact or brucellosis symptoms. RBT was highly sensitive in acute and long evolution brucellosis cases and this related to its ability to detect IgM, IgG and IgA, to the absence of prozones, and to the agglutinating activity of blocking IgA at the pH of the test. RBT was also highly specific in the sera of persons with no contact with Brucella. No test in this study outperformed RBT, and none was fully satisfactory in distinguishing contacts from infected patients. When modified to test serum dilutions, a diagnostic titer >4 in RBT resulted in 87.4% sensitivity (infected patients) and 100% specificity (contacts). We discuss the limitations of serological tests in the diagnosis of human brucellosis, particularly in the more chronic forms, and conclude that simplicity and affordability of RBT make it close to the ideal test for small and understaffed hospitals and laboratories.

Electronic transport in low temperature nanocrystalline silicon thin-film transistors obtained by Hot-Wire CVD

Hydrogenated nanocrystalline silicon (nc-Si:H) obtained by hot-wire chemical vapour deposition (HWCVD) at low substrate temperature (150 °C) has been incorporated as the active layer in bottom-gate thin-film transistors (TFTs). These devices were electrically characterised by measuring in vacuum the output and transfer characteristics for different temperatures. The field-effect mobility showed a thermally activated behaviour which could be attributed to carrier trapping at the band tails, as in hydrogenated amorphous silicon (a-Si:H), and potential barriers for the electronic transport. Trapped charge at the interfaces of the columns, which are typical in nc-Si:H, would account for these barriers. By using the Levinson technique, the quality of the material at the column boundaries could be studied. Finally, these results were interpreted according to the particular microstructure of nc-Si:H.

Microcrystalline silicon thin film transistors obtained by Hot-Wire CVD

Polysilicon thin film transistors (TFT) are of great interest in the field of large area microelectronics, especially because of their application as active elements in flat panel displays. Different deposition techniques are in tough competition with the objective to obtain device-quality polysilicon thin films at low temperature. In this paper we present the preliminary results obtained with the fabrication of TFT deposited by hot-wire chemical vapor deposition (HWCVD). Some results concerned with the structural characterization of the material and electrical performance of the device are presented.

Thin Film Transistors obtained by Hot-Wire CVD

Hydrogenated microcrystalline silicon films obtained at low temperature (150-280°C) by hot wire chemical vapour deposition at two different process pressures were measured by Raman spectroscopy, X-ray diffraction (XRD) spectroscopy and photothermal deflection spectroscopy (PDS). A crystalline fraction >90% with a subgap optical absortion 10 cm -1 at 0.8 eV were obtained in films deposited at growth rates >0.8 nm/s. These films were incorporated in n-channel thin film transistors and their electrical properties were measured. The saturation mobility was 0.72 ± 0.05 cm 2/ V s and the threshold voltage around 0.2 eV. The dependence of their conductance activation energies on gate voltages were related to the properties of the material.

Regio- and stereoselective microwave-assisted synthesis of 5-alkyl-4-alkenyl-4-phenyl-1,3-oxazolidin-2-ones

Chiral symmetrical alk-2-yne-1,4-diols have been stereoselectively transformed into 5-alkyl-4-alkenyl-4-phenyl-1,3-oxazolidin- 2-ones, which are precursors of quaternary α-amino β-hydroxy acids. The key step was the cyclization of the bis(tosylcarbamates) of 2- phenylalk-2-yne-1,4-diols, easily obtained from the starting chiral diols. These cyclizations were accomplished with complete regioselectivity and up to 92:8 dr in the presence of catalytic amounts of Ni(0) or Pd (II) derivatives under microwave heating.

El Barceloneta I. Una embarcación medieval a tingladillo en Barcelona

El año 2008 una intervención arqueológica en un solar cercano al Port Vell de Barcelona permitió estudiar y localizar una importante área del puerto medieval de la ciudad entre el que destacaría el muelle construido en el año 1477 y un pecio de construcción de casco previo y a tingladillo. El presente artículo realiza una aproximación al pecio Barceloneta I desde diferentes enfoques como los estudios palinológicos, dendrocronológicos, además del estudio histórico y arquitectónico. El conjunto de resultados permite situar la embarcación como la evidencia material de las complejas redes de comunicación marítima entre el Atlántico y el Mediterráneo en época Bajo Medieval así como avanzar en el conocimiento de la construcción naval en este periodo.

Late and postmagmatic alterations in the tin-bearing batholith of Ricobayo (Iberian Massif, NW Spain)

The deuteric alteration processes undergone by the granites of the Ricobayo Batholith were: microclinization, chloritization, albitization, muscovitization, tourmalinization and garnetization. These processes must be interpreted in a dynamic context so that the different reactions that take place are the consequence of a successive interaction between rock and fluids. The physicochemical conditions deduced from these fluids are: temperature lower than 600 OC, pressure between 1.5 and 1 Kb, fugacity of oxygen between 10-25 and 10-35 bars, fugacity of sulphur lower than 10-l5 bars, the composition was kept stable and their log (a(K+)/a(Ht)) and log (a(Na+)/a(H+)) varied between 3.8 and 3.2 and between 3.5 and 4.6, respectively, and the pH of the fluids was higher than 5 during the microclinization, muscovitization and tourmalinization, and lower during chloritization and albitization. The deposition of cassiterite occurs with pH episodes that exceed 5.

Clinico-Pathological discrepancies in the Diagnosis of Causes of Maternal Death in Sub-Saharan Africa: Retrospective Analysis

Background Maternal mortality is a major public-health problem in developing countries. Extreme differences in maternal mortality rates between developed and developing countries indicate that most of these deaths are preventable. Most information on the causes of maternal death in these areas is based on clinical records and verbal autopsies. Clinical diagnostic errors may play a significant role in this problem and might also have major implications for the evaluation of current estimations of causes of maternal death. Methods and Findings A retrospective analysis of clinico-pathologic correlation was carried out, using necropsy as the gold standard for diagnosis. All maternal autopsies (n ¼ 139) during the period from October 2002 to December 2004 at the Maputo Central Hospital, Mozambique were included and major diagnostic discrepancies were analyzed (i.e., those involving the cause of death). Major diagnostic errors were detected in 56 (40.3%) maternal deaths. A high rate of false negative diagnoses was observed for infectious diseases, which showed sensitivities under 50%: HIV/AIDS-related conditions (33.3%), pyogenic bronchopneumonia (35.3%), pyogenic meningitis (40.0%), and puerperal septicemia (50.0%). Eclampsia, was the main source of false positive diagnoses, showing a low predictive positive value (42.9%). Conclusions Clinico-pathological discrepancies may have a significant impact on maternal mortality in sub-Saharan Africa and question the validity of reports based on clinical data or verbal autopsies. Increasing clinical awareness of the impact of obstetric and nonobstetric infections with their inclusion in the differential diagnosis, together with a thorough evaluation of cases clinically thought to be eclampsia, could have a significant impact on the reduction of maternal mortality.

Tractament digital de la imatge com a suport per a la recerca

La investigació actual necessita recórrer en nombroses ocasions a la imatge, i encara ho podria fer més. El registre d'imatges s'ha convertit avui en una feina senzilla i económica, almenys en relació amb la situació de fa vint anys. I des de fa amb prou feines un parell d'anys, el tractament de la imatge animada mitjançant tècniques digitals encara s'ha simplificat més, alhora que ha proporcionat nous canvis que permeten explorar la realitat.

Excavaciones (1981-1983) en el poblado de Carretela (Aitona, Segrià, Lleida)

Con este artículo damos a conocer un poco más en profundidad un yacimiento al que muchas veces se ha hecho referencia en la bibliografía sin que existiera aún una publicación monográfica al respecto. Las excavaciones del poblado fechados a principios de los CC.UU. Antiguos, reflejan la sucesión de diversas ocupaciones de un mismo espacio habitado. El conocimiento de este período queda igualmente completado a partir de diversos estudios adicionales.

Nota sobre una localidad con pirita (Sta. Creu d'Olorde, Barcelona)

Se estudia la situación geolgóica y las características de yacimiento de una localidad con pirita (Santa Creu d'Olorde, Barcelona). Las muestras mineralógicas y petrológicas son estudiadas mediante las técnicas, de luz reflejada, difractometría y espectrografia por fluorescencia de rayos X.