959 resultados para statistical quantum field theory


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Solitons in the Skyrme-Faddeev model on R-2 x S-1 are shown to undergo buckling transitions as the circumference of the S-1 is varied. These results support a recent conjecture that solitons in this field theory are well-described by a much simpler model of elastic rods.

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We study general properties of the Landau-gauge Gribov ghost form factor sigma(p(2)) for SU(N-c) Yang-Mills theories in the d-dimensional case. We find a qualitatively different behavior for d = 3, 4 with respect to the d = 2 case. In particular, considering any (sufficiently regular) gluon propagator D(p(2)) and the one-loop-corrected ghost propagator, we prove in the 2d case that the function sigma(p(2)) blows up in the infrared limit p -> 0 as -D(0) ln(p(2)). Thus, for d = 2, the no-pole condition sigma(p(2)) < 1 (for p(2) > 0) can be satisfied only if the gluon propagator vanishes at zero momentum, that is, D(0) = 0. On the contrary, in d = 3 and 4, sigma(p(2)) is finite also if D(0) > 0. The same results are obtained by evaluating the ghost propagator G(p(2)) explicitly at one loop, using fitting forms for D(p(2)) that describe well the numerical data of the gluon propagator in two, three and four space-time dimensions in the SU(2) case. These evaluations also show that, if one considers the coupling constant g(2) as a free parameter, the ghost propagator admits a one-parameter family of behaviors (labeled by g(2)), in agreement with previous works by Boucaud et al. In this case the condition sigma(0) <= 1 implies g(2) <= g(c)(2), where g(c)(2) is a "critical" value. Moreover, a freelike ghost propagator in the infrared limit is obtained for any value of g(2) smaller than g(c)(2), while for g(2) = g(c)(2) one finds an infrared-enhanced ghost propagator. Finally, we analyze the Dyson-Schwinger equation for sigma(p(2)) and show that, for infrared-finite ghost-gluon vertices, one can bound the ghost form factor sigma(p(2)). Using these bounds we find again that only in the d = 2 case does one need to impose D(0) = 0 in order to satisfy the no-pole condition. The d = 2 result is also supported by an analysis of the Dyson-Schwinger equation using a spectral representation for the ghost propagator. Thus, if the no-pole condition is imposed, solving the d = 2 Dyson-Schwinger equations cannot lead to a massive behavior for the gluon propagator. These results apply to any Gribov copy inside the so-called first Gribov horizon; i.e., the 2d result D(0) = 0 is not affected by Gribov noise. These findings are also in agreement with lattice data.

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In this paper we discuss some ideas on how to define the concept of quasi-integrability. Our ideas stem from the observation that many field theory models are "almost" integrable; i.e. they possess a large number of "almost" conserved quantities. Most of our discussion will involve a certain class of models which generalize the sine-Gordon model in (1 + 1) dimensions. As will be mentioned many field configurations of these models look like those of the integrable systems and so appear to be close to those in integrable model. We will then attempt to quantify these claims looking in particular, both analytically and numerically, at field configurations with scattering solitons. We will also discuss some preliminary results obtained in other models.

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This thesis contains four different studies on the dynamics of gender in households and workplaces. The relationship between family life and work life is in focus, particularly in the paper on labour market outcomes after divorce. In the introductory chapter, the Swedish context is briefly described. The description focuses on gender differences in the labour market and in the home. Theories concerning the division of work in the household are discussed, as are two theories on labour market discrimination, viz. taste discrimination and statistical discrimination. The theory part is concluded with a discussion of social closure processes and gendered organizational structures. The Reproduction of Gender. Housework and Attitudes Towards Gender Equality in the Home Among Swedish Boys and Girls. The housework boys and girls age 10 to 18 do, and their attitudes towards gender equality in the home are studied. One aim is to see whether the work children do is gendered and if so, whether they follow their parents’, often gendered, pattern in housework. A second aim is to see whether parents’ division of work is related to the children’s attitude towards gender equality in the home. The data used are taken from the Swedish Child Level of Living Survey (Child-LNU) 2000. Results indicate that girls and boys in two-parent families are more prone to engage in gender-atypical work the more their parent of the same sex engages in this kind of work. The fact that girls still do more housework than boys indicates that housework is gendered work also among children. No relation between parents’ division of work and the child’s attitude towards gender equality in the home was found. Dependence within Families and the Household Division of Labor – A Comparison between Sweden and the United States. This paper assesses the relative explanatory value of the resource-bargaining perspective and the doing-gender approach in analysing the division of housework in the United States and Sweden from the mid-1970s to 2000. Data from the Swedish Level of Living Survey (LNU) and the Panel Study of Income Dynamics (PSID) were used. Overall results indicate that housework is truly gendered work in both countries during the entire period. Even so, the results also indicate that gender deviance neutralization is more pronounced in the United States than in Sweden. Unlike Swedish women, American women seem to increase their time spent in housework when their husbands are to some extent economically dependent on them, as if to neutralize the presumed gender deviance. Divorce and Labour Market Outcomes. Do Women Suffer or Gain? In this paper, the interconnected nature of work and family is studied by looking at labour market outcomes after divorce. The data used are retrospective work and family histories collected in LNU 1991. A hazard regression model with competing risks reveals that women’s chances of improving their occupational prestige appear to be better after divorce compared to before. Increased working hours and perhaps also increased energy invested in the job may pay off in better occupational opportunities. Worth noting, however, is that the outcome among women with a less firm labour market attachment is more often to a job of lower prestige than one of higher prestige. Hence, the labour market outcome for women after divorce is to some extent conditioned by their labour market attachment at the time of divorce. Men, on the other hand, in most cases seem to suffer occupationally from divorce. For separated men the risk of negative changes in occupational prestige is greater than for cohabiting men. Formal On-the-job Training. A Gender-Typed Experience and Wage- Related Advantage? Formal on-the-job training (FOJT) can have a positive impact on wages and on promotion opportunities. According to theory and earlier research, a two-step model of gender inequality in FOJT is predicted: First, women are less likely than men to take part in FOJT and, second, once women do get the more remunerative training, they are not rewarded for their new skills to the same extent as men are. Pooled cross-sectional data from the Swedish Survey of Living Conditions (ULF) in the mid-nineties were used. Results show that women are significantly less likely than men to take part in FOJT. Among those who do receive training, women are more likely to take part in industry-specific training, whereas men are more likely to participate in general training and training that increases promotion opportunities. The two latter forms of training significantly raise a man’s annual earnings but not a woman’s. Hence, the theoretical model is supported and it is argued that this gender inequality is partly due to employers’ discriminatory practices.

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There is very strong evidence that ordinary matter in the Universe is outweighed by almost ten times as much so-called dark matter. Dark matter does neither emit nor absorb light and we do not know what it is. One of the theoretically favoured candidates is a so-called neutralino from the supersymmetric extension of the Standard Model of particle physics. A theoretical calculation of the expected cosmic neutralino density must include the so-called coannihilations. Coannihilations are particle processes in the early Universe with any two supersymmetric particles in the initial state and any two Standard Model particles in the final state. In this thesis we discuss the importance of these processes for the calculation of the relic density. We will go through some details in the calculation of coannihilations with one or two so-called sfermions in the initial state. This includes a discussion of Feynman diagrams with clashing arrows, a calculation of colour factors and a discussion of ghosts in non-Abelian field theory. Supersymmetric models contain a large number of free parameters on which the masses and couplings depend. The requirement, that the predicted density of cosmic neutralinos must agree with the density observed for the unknown dark matter, will constrain the parameters. Other constraints come from experiments which are not related to cosmology. For instance, the supersymmetric loop contribution to the rare b -> sγ decay should agree with the measured branching fraction. The principles of the calculation of the rare decay are discussed in this thesis. Also on-going and planned searches for cosmic neutralinos can constrain the parameters. In one of the accompanying papers in the thesis we compare the detection prospects for several current and future searches for neutralino dark matter.

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Zusammmenfassung:Um Phasenseparation in binären Polymermischungen zuuntersuchen, werden zwei dynamische Erweiterungen der selbstkonsistenten Feldtheorie (SCFT)entwickelt. Die erste Methode benutzt eine zeitliche Entwicklung der Dichten und wird dynamische selbstkonsistente Feldtheorie (DSCFT) genannt, während die zweite Methode die zeitliche Propagation der effektiven äußeren Felder der SCFT ausnutzt. Diese Methode wird mit External Potential Dynamics (EPD) bezeichnet. Für DSCFT werden kinetische Koeffizienten verwendet, die entweder die lokale Dynamik von Punktteilchen oder die nichtlokale Dynamik von Rouse'schen Polymeren nachbilden. Die EPD-Methode erzeugt mit einem konstanten kinetischen Koeffizienten die Dynamik von Rouse'schen Ketten und benötigt weniger Rechenzeit als DSCFT. Diese Methoden werden für verschiedene Systeme angewendet.Zuerst wird spinodale Entmischung im Volumen untersucht,wobei der Unterschied zwischen lokaler und nichtlokalerDynamik im Mittelpunkt steht. Um die Gültigkeit derErgebnisse zu überprüfen, werden Monte-Carlo-Simulationen durchgeführt. In Polymermischungen, die von zwei Wänden, die beide die gleiche Sorte Polymere bevorzugen, eingeschränkt werden, wird die Bildung von Anreicherungsschichten an den Wänden untersucht. Für dünne Polymerfilme zwischen antisymmetrischen Wänden, d.h. jede Wand bevorzugt eine andere Polymerspezies, wird die Spannung einer parallel zu den Wänden gebildeten Grenzfläche analysiert und der Phasenübergang von einer anfänglich homogenen Mischung zur lokalisierten Phase betrachtet. Des Weiteren wird die Dynamik von Kapillarwellenmoden untersucht.

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Diese Arbeit beschäftigt sich mit Strukturbildung im schlechten Lösungsmittel bei ein- und zweikomponentigen Polymerbürsten, bei denen Polymerketten durch Pfropfung am Substrat verankert sind. Solche Systeme zeigen laterale Strukturbildungen, aus denen sich interessante Anwendungen ergeben. Die Bewegung der Polymere erfolgt durch Monte Carlo-Simulationen im Kontinuum, die auf CBMC-Algorithmen sowie lokalen Monomerverschiebungen basieren. Eine neu entwickelte Variante des CBMC-Algorithmus erlaubt die Bewegung innerer Kettenteile, da der bisherige Algorithmus die Monomere in Nähe des Pfropfmonomers nicht gut relaxiert. Zur Untersuchung des Phasenverhaltens werden mehrere Analysemethoden entwickelt und angepasst: Dazu gehören die Minkowski-Maße zur Strukturuntersuchung binären Bürsten und die Pfropfkorrelationen zur Untersuchung des Einflusses von Pfropfmustern. Bei einkomponentigen Bürsten tritt die Strukturbildung nur beim schwach gepfropften System auf, dichte Pfropfungen führen zu geschlossenen Bürsten ohne laterale Struktur. Für den graduellen Übergang zwischen geschlossener und aufgerissener Bürste wird ein Temperaturbereich bestimmt, in dem der Übergang stattfindet. Der Einfluss des Pfropfmusters (Störung der Ausbildung einer langreichweitigen Ordnung) auf die Bürstenkonfiguration wird mit den Pfropfkorrelationen ausgewertet. Bei unregelmäßiger Pfropfung sind die gebildeten Strukturen größer als bei regelmäßiger Pfropfung und auch stabiler gegen höhere Temperaturen. Bei binären Systemen bilden sich Strukturen auch bei dichter Pfropfung aus. Zu den Parametern Temperatur, Pfropfdichte und Pfropfmuster kommt die Zusammensetzung der beiden Komponenten hinzu. So sind weitere Strukturen möglich, bei gleicher Häufigkeit der beiden Komponenten bilden sich streifenförmige, lamellare Muster, bei ungleicher Häufigkeit formt die Minoritätskomponente Cluster, die in der Majoritätskomponente eingebettet sind. Selbst bei gleichmäßig gepfropften Systemen bildet sich keine langreichweitige Ordnung aus. Auch bei binären Bürsten hat das Pfropfmuster großen Einfluss auf die Strukturbildung. Unregelmäßige Pfropfmuster führen schon bei höheren Temperaturen zur Trennung der Komponenten, die gebildeten Strukturen sind aber ungleichmäßiger und etwas größer als bei gleichmäßig gepfropften Systemen. Im Gegensatz zur self consistent field-Theorie berücksichtigen die Simulationen Fluktuationen in der Pfropfung und zeigen daher bessere Übereinstimmungen mit dem Experiment.

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Skalenargumente werden verwendet, um Rod-Coil Copolymere mit fester Zusammensetzung von steifen Stäbchen und flexiblen Ketten zu studieren. In einem selektiven Lösungsmittel, in dem sich nur die Ketten lösen, bildet ein Rod-Coil Multiblock zylinderförmige Micellen aus aggregierten Stäbchen verbunden durch Kettenstücke. Die Stäbchen aggregieren, um Energie zu gewinnen. Dieser Prozeß wird durch den Entropieverlust der flexiblen Ketten ausgeglichen. Das Adsorptionsverhalten von Aggregaten aus parallel aneinandergelagerten, einzelnen Rod-Coil Diblöcken in selektivem Lösungsmittel wird anhand von erweiterten Skalenbetrachtungen diskutiert. Wenn ein solches Aggregat mit den Stäbchen parallel zur Oberfläche adsorbiert, verschieben sich die Stäbchen gegeneinander. Zusätzlich werden die Stabilität der adsorbierten Aggregate und andere mögliche Konfigurationen untersucht. Um einen Rod-Coil Multiblock mit variabler Zusammensetzung zu studieren, wird eine Feldtheorie entwickelt. Jedes Segment kann entweder steif oder flexibel sein. Das System zeigt drei Phasenzustände, offene Kette, amorphe Globule und flüssig-kristalline Globule. Beim Übergang von amorpher zu flüssig-kristalliner Globule steigt der Anteil an steifen Segmenten rapide an. Dieser Übergang wird durch die isotrope Wechselwirkung zwischen den steifen Segmenten und die anisotrope Oberflächenenergie der Globule verursacht.

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The aim of this study was to develop a model capable to capture the different contributions which characterize the nonlinear behaviour of reinforced concrete structures. In particular, especially for non slender structures, the contribution to the nonlinear deformation due to bending may be not sufficient to determine the structural response. Two different models characterized by a fibre beam-column element are here proposed. These models can reproduce the flexure-shear interaction in the nonlinear range, with the purpose to improve the analysis in shear-critical structures. The first element discussed is based on flexibility formulation which is associated with the Modified Compression Field Theory as material constitutive law. The other model described in this thesis is based on a three-field variational formulation which is associated with a 3D generalized plastic-damage model as constitutive relationship. The first model proposed in this thesis was developed trying to combine a fibre beamcolumn element based on the flexibility formulation with the MCFT theory as constitutive relationship. The flexibility formulation, in fact, seems to be particularly effective for analysis in the nonlinear field. Just the coupling between the fibre element to model the structure and the shear panel to model the individual fibres allows to describe the nonlinear response associated to flexure and shear, and especially their interaction in the nonlinear field. The model was implemented in an original matlab® computer code, for describing the response of generic structures. The simulations carried out allowed to verify the field of working of the model. Comparisons with available experimental results related to reinforced concrete shears wall were performed in order to validate the model. These results are characterized by the peculiarity of distinguishing the different contributions due to flexure and shear separately. The presented simulations were carried out, in particular, for monotonic loading. The model was tested also through numerical comparisons with other computer programs. Finally it was applied for performing a numerical study on the influence of the nonlinear shear response for non slender reinforced concrete (RC) members. Another approach to the problem has been studied during a period of research at the University of California Berkeley. The beam formulation follows the assumptions of the Timoshenko shear beam theory for the displacement field, and uses a three-field variational formulation in the derivation of the element response. A generalized plasticity model is implemented for structural steel and a 3D plastic-damage model is used for the simulation of concrete. The transverse normal stress is used to satisfy the transverse equilibrium equations of at each control section, this criterion is also used for the condensation of degrees of freedom from the 3D constitutive material to a beam element. In this thesis is presented the beam formulation and the constitutive relationships, different analysis and comparisons are still carrying out between the two model presented.

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Die vorliegende Arbeit wurde durch die Erkenntnis motiviert, daß die Theorie der Intentionalität ohne eine Theorie der impliziten Intentionalität unvollständig ist. Die Anlage einer solchen Theorie gründet in der Annahme, daß die impliziten ("ergänzenden oder "mit-bewußten") Erfahrungsinhalte Inhalte intentional wirksam sind: daß sie zur "Konstitution" der intentionalen Objekte – im Sinne vom Husserl und Gurwitsch – beitragen. Die Bedingungen und Umstände dieser Wirksamkeit herauszuarbeiten, ist das Hauptziel der vorliegenden Untersuchungen. Dazu wurde (1) eine phänomenologische Theorie des impliziten Inhalts kritisch expliziert, und (2) diese anhand einiger aktueller Ansätze der analytischen Philosophie auf die Probe gestellt. Im phänomenologischen Teil der Arbeit wurden zuerst die methodologischen Voraussetzungen von Gurwitschs gestalttheoretischer Neuformulierung des Husserlschen Projekts unter Berücksichtigung der sogenannten Konstanzannahme kritisch untersucht. Weiterhin wurden Husserls Noema-Konzeption und seine Horizontlehre aus der Perspektive von Gurwitschs Feldtheorie des Bewußtseins expliziert, und in der Folge Gurwitschs dreifache Gliederung des Bewußtseinsfeldes – das Kopräsenz-Kohärenz-Relevanz-Schema – um die phänomenologischen Begriffe "Potentialität", "Typik" und "Motivation" erweitert. Die Beziehungen, die diesen Begriffen zugrunde liegen, erwiesen sich als "mehr denn bloß kontigent, aber als weniger denn logisch oder notwendig" (Mulligan). An Beispielen aus der analytischen Philosphie der Wahrnehmung (Dretske, Peacocke, Dennett, Kelly) und der Sprache (Sperber, Wilson, Searle) wurde das phänomenologische Konzept des impliziten Inhalts kritisch beurteilt und weiterentwickelt. Hierbei wurde(n) unter anderem (1) der Zusammenhang zwischen dem phänomenologischen Begriff "vorprädikativer Inhalt" und dem analytischen Begriff "nichtkonzeptueller Inhalt" aufgezeigt und (2) Kriterien für die Zuschreibung impliziter Überzeugungen in den typischen Fällen der prädikativen Intentionalität zusammengetragen und systematisiert.

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Il formalismo Mathai-Quillen (MQ) è un metodo per costruire la classe di Thom di un fibrato vettoriale attraverso una forma differenziale di profilo Gaussiano. Lo scopo di questa tesi è quello di formulare una nuova rappresentazione della classe di Thom usando aspetti geometrici della quantizzazione Batalin-Vilkovisky (BV). Nella prima parte del lavoro vengono riassunti i formalismi BV e MQ entrambi nel caso finito dimensionale. Infine sfrutteremo la trasformata di Fourier “odd" considerando la forma MQ come una funzione definita su un opportuno spazio graduato.

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This thesis reports a study on the seismic response of two-dimensional squat elements and their effect on the behavior of building structures. Part A is devoted to the study of unreinforced masonry infills, while part B is focused on reinforced concrete sandwich walls. Part A begins with a comprehensive review of modelling techniques and code provisions for infilled frame structures. Then state-of-the practice techniques are applied for a real case to test the ability of actual modeling techniques to reproduce observed behaviors. The first developments towards a seismic-resistant masonry infill system are presented. Preliminary design recommendations for the seismic design of the seismic-resistant masonry infill are finally provided. Part B is focused on the seismic behavior of a specific reinforced concrete sandwich panel system. First, the results of in-plane psuudostatic cyclic tests are described. Refinements to the conventional modified compression field theory are introduced in order to better simulate the monotonic envelope of the cyclic response. The refinements deal with the constitutive model for the shotcrete in tension and the embedded bars. Then the hysteretic response of the panels is studied according to a continuum damage model. Damage state limits are identified. Design recommendations for the seismic design of the studied reinforced concrete sandwich walls are finally provided.

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Der erste Teil der vorliegenden Dissertation befasst sich mit der Untersuchung der perturbativen Unitarität im Komplexe-Masse-Renormierungsschema (CMS). Zu diesem Zweck wird eine Methode zur Berechnung der Imaginärteile von Einschleifenintegralen mit komplexen Massenparametern vorgestellt, die im Grenzfall stabiler Teilchen auf die herkömmlichen Cutkosky-Formeln führt. Anhand einer Modell-Lagrangedichte für die Wechselwirkung eines schweren Vektorbosons mit einem leichten Fermion wird demonstriert, dass durch Anwendung des CMS die Unitarität der zugrunde liegenden S-Matrix im störungstheoretischen Sinne erfüllt bleibt, sofern die renormierte Kopplungskonstante reell gewählt wird. Der zweite Teil der Arbeit beschäftigt sich mit verschiedenen Anwendungen des CMS in chiraler effektiver Feldtheorie (EFT). Im Einzelnen werden Masse und Breite der Deltaresonanz, die elastischen elektromagnetischen Formfaktoren der Roperresonanz, die elektromagnetischen Formfaktoren des Übergangs vom Nukleon zur Roperresonanz sowie Pion-Nukleon-Streuung und Photo- und Elektropionproduktion für Schwerpunktsenergien im Bereich der Roperresonanz berechnet. Die Wahl passender Renormierungsbedingungen ermöglicht das Aufstellen eines konsistenten chiralen Zählschemas für EFT in Anwesenheit verschiedener resonanter Freiheitsgrade, so dass die aufgeführten Prozesse in Form einer systematischen Entwicklung nach kleinen Parametern untersucht werden können. Die hier erzielten Resultate können für Extrapolationen von entsprechenden Gitter-QCD-Simulationen zum physikalischen Wert der Pionmasse genutzt werden. Deshalb wird neben der Abhängigkeit der Formfaktoren vom quadrierten Impulsübertrag auch die Pionmassenabhängigkeit des magnetischen Moments und der elektromagnetischen Radien der Roperresonanz untersucht. Im Rahmen der Pion-Nukleon-Streuung und der Photo- und Elektropionproduktion werden eine Partialwellenanalyse und eine Multipolzerlegung durchgeführt, wobei die P11-Partialwelle sowie die Multipole M1- und S1- mittels nichtlinearer Regression an empirische Daten angepasst werden.

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Il collasso di diverse colonne, caratterizzate da danneggiamenti simili, quali ampie fessure fortemente inclinate ad entrambe le estremità dell’elemento, lo schiacciamento del calcestruzzo e l’instabilità dei ferri longitudinali, ha portato ad interrogarsi riguardo gli effetti dell’interazione tra lo sforzo normale, il taglio ed il momento flettente. Lo studio è iniziato con una ricerca bibliografica che ha evidenziato una sostanziale carenza nella trattazione dell’argomento. Il problema è stato approcciato attraverso una ricerca di formule della scienza delle costruzioni, allo scopo di mettere in relazione lo sforzo assiale, il taglio ed il momento; la ricerca si è principalmente concentrata sulla teoria di Mohr. In un primo momento è stata considerata l’interazione tra solo due componenti di sollecitazione: sforzo assiale e taglio. L’analisi ha condotto alla costruzione di un dominio elastico di taglio e sforzo assiale che, confrontato con il dominio della Modified Compression Field Theory, trovata tramite ricerca bibliografica, ha permesso di concludere che i risultati sono assolutamente paragonabili. L’analisi si è poi orientata verso l’interazione tra sforzo assiale, taglio e momento flettente. Imponendo due criteri di rottura, il raggiungimento della resistenza a trazione ed a compressione del calcestruzzo, inserendo le componenti di sollecitazione tramite le formule di Navier e Jourawsky, sono state definite due formule che mettono in relazione le tre azioni e che, implementate nel software Matlab, hanno permesso la costruzione di un dominio tridimensionale. In questo caso non è stato possibile confrontare i risultati, non avendo la ricerca bibliografica mostrato niente di paragonabile. Lo studio si è poi concentrato sullo sviluppo di una procedura che tenta di analizzare il comportamento di una sezione sottoposta a sforzo normale, taglio e momento: è stato sviluppato un modello a fibre della sezione nel tentativo di condurre un calcolo non lineare, corrispondente ad una sequenza di analisi lineari. La procedura è stata applicata a casi reali di crollo, confermando l’avvenimento dei collassi.

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This work is focused on axions and axion like particles (ALPs) and their possible relation with the 3.55 keV photon line detected, in recent years, from galaxy clusters and other astrophysical objects. We focus on axions that come from string compactification and we study the vacuum structure of the resulting low energy 4D N=1 supergravity effective field theory. We then provide a model which might explain the 3.55 keV line through the following processes. A 7.1 keV dark matter axion decays in two light axions, which, in turn, are transformed into photons thanks to the Primakoff effect and the existence of a kinetic mixing between two U(1)s gauge symmetries belonging respectively to the hidden and the visible sector. We present two models, the first one gives an outcome inconsistent with experimental data, while the second can yield the desired result.