La movilidad residencial de los hogares con bajos ingresos y jefatura femenina en el área

En este artículo se analizan algunos aspectos de la movilidad residencial de los hogares con bajos ingresos y jefatura femenina en el área metropolitana de Bogotá. Para ello, se examinan los datos producidos por la encuesta de movilidad 2009 y una serie de entrevistas realizadas en el Proyecto “Metrópolis de América Latina en la globalización: reconfiguraciones territoriales, movilidad espacial, acción pública”, Metal. Se presenta un contexto a partir de algunos indicadores censales y, en seguida, algunos resultados de la encuesta: en primer lugar, características de las jefas de hogar como edad, estado conyugal, ocupación, grado educativo; posteriormente, sobre las zonas donde residen, en particular, su localización en el área metropolitana y la morfología del barrio. Por último, aspectos como la tenencia, el tipo de vivienda, la localización de las redes familiares y el ciclo vital del hogar.

Las operaciones para el mantenimiento de la paz en Haití (1991-2005)

La Misión de Estabilización de las Naciones Unidas en Haití -MINUSTAHes la primera intervención en la historia de las operaciones de paz en la cual la participación latinoamericana fue fruto de una concertación política de los gobiernos de la región. El desafío de la operación de paz es por un lado, la reconstrucción de un Estado, y por otro, demostrar la capacidad de los países latinoamericanos para manejar este tipo de conflictos.En el presente trabajo se analizan las operaciones para el mantenimiento de la paz de las Naciones Unidas en Haití,1 se evalúan las capacidades, los recursos y mecanismos políticos que disponen los organismos multilaterales y los gobiernos para manejar y responder a dicho conflicto en forma efectiva.Este trabajo no tiene la finalidad de investigar los eventos que han determinado la intervención de 2004, más bien la finalidad del presente trabajo es analizar las intervenciones de las operaciones para el mantenimiento de la paz de las Naciones Unidas en Haití, la Misión de las Naciones Unidas en Haití (UNMIH), de septiembre de 1993 a junio de 1996; la Misión de Apoyo de las Naciones Unidas en Haití (UNSMIH), de julio de 1996 a julio de 1997; la Misión de Transición de las Naciones Unidas en Haití (UNTMIH), de agosto a noviembre de 1997, y la Misión de Policía Civil de las Naciones Unidas en Haití (MIPONUH), de diciembre de 1997 a marzo de 2000; intervención de la Fuerza Interina Multinacional (FIM) entre marzo y junio de 2004, y particularmente la Misión de Estabilización de las Naciones Unidas en Haití (MINUSTAH) que reemplazó la anterior y que a la fecha continúa en Haití.-----The MINUSTAH mission is the first intervention in the history of peace operations where the Latin American involvement resulted from a political agreement among the region governments. The peace operation challenge is, on the one hand, the reconstruction of a State and, on the other hand, demonstrating the ability of Latin American countries for handling this type of conflicts.This paper analyzes UN peacekeeping operations in Haiti,2 evaluates the abilities, the resources, and the political mechanisms available to multilateral bodies and governments for handling and addressing such conflict on an effective way. The purpose of this paper is not investigating the events that determined the intervention in 2004. Rather, its purpose is to analyze the interventions of the UN peacekeeping operations in Haiti, –UN Mission in Haiti (UNMIH), from September 1993 to June 1996; UN Support Mission in Haiti (UNSMIH), from July 1996 to July 1997; UN Transition Mission in Haiti (UNTMIH), from August to November 1997; and UN Civilian Police Mission in Haiti (MIPONUH), from December 1997 to March 2000;– the intervention of the Multinational Force (MNF) between March and June 2004, and particularly the United Nations Stabilization Mission in Haiti (MINUSTAH) that replaced the latter and remains in Haiti.

La experiencia del proceso de desarrollo e internacionalización de las zonas francas industriales y comerciales colombianas

Entrar al análisis de los factores de liderazgo de las zonas francas de Colombia, República Dominicana y Taiwán, resulta básico abordar el tema del liderazgo empresarial, como la estructura principal del éxito en las organizaciones del mundo

La freqüentació dels parcs naturals a Catalunya

This article offers a series of reflections and proposals concerning the visitors usage of Catalonia's Natural Parks. The basis of these affirmations is the analysis of the parks which exist at the present in Catalonia, as well as the study of the current legislation in Catalonia and in Spain. Although the article deals exclusively with protected natural areas, it must be remembered that people's recreational activities affect the entire natural environment. It is therefore necessary to extend planning to the impact of such activities in all natural areas. The author proposes as a possible solution a hierarchy of leisure zones in natural spaces, divided into three different levels: Municipal Parks, Regional Parks as well as Natural and National Parks

Integração do elemento vegetal no edificado

Esta dissertação é muito mais do que um trabalho sobre ajardinamento de edifícios, pois pretende-se que seja uma ferramenta de ajuda em benefício da transformação de milhares de metros quadrados, das coberturas e das fachadas, muitas vezes negligenciados, em espaços verdes públicos beneficiando, não somente, os promotores imobiliários mas, acima de tudo os seus ocupantes e usufrutuários, que desta forma podem tirar partido de novos espaços de estar, ao ar livre. Enquanto a cidade, ao nível térreo, apresenta um aumento de tráfego rodoviário, com inegável poluição e confusão, é possível, desta forma, usufruir de um espaço aberto. Esta dissertação procura estudar os edifícios que já integram o elemento vegetal no seu conceito e que sejam um sucesso na forma como usam o elemento vegetal, de modo a divulgar as técnicas de construção, entender as decisões dos projectistas e o impacto nos utilizadores que habitam e usufruem dos espaços – Análise-Pós-Ocupação. Esta dissertação pretende demonstrar o quanto é importante que as cidades apresentem espaços verdes para uso da população. As zonas verdes existentes nas cidades são inequivocamente um importante indicador da qualidade ambiental existente nessas mesmas cidades. As coberturas e fachadas verdes arrefecem os edifícios, capturam e filtram as águas da chuva, proporcionam habitat à vida selvagem, reduzem o efeito de estufa das cidades, proporcionam uma preciosidade estética, uma experiência recreativa e por vezes comida, para os habitantes das cidades. Pretende-se assim, focar os benefícios humanos, sociais e naturais que se obtêm ao introduzir vegetação nas paredes, terraços, pátios e coberturas dos edifícios. Assim foi considerado útil usar uma metodologia para também analisar o tipo de espécies usadas nos estudos de caso, e determinar a necessidade de uma ferramenta para que a selecção vegetal respeite critérios de biodiversidade e melhor adaptabilidade aos ecossistemas locais, sabendo de antemão que não podem nem pretendem substituir os habitats naturais, que as cidades também podem e devem apresentar.

Una escritura en tránsito: apuntes sobre la narrativa de los 50 (Dossier: Narradores ecuatorianos de la década de 1950)

El autor analiza y comenta varias de las características atribuidas a la literatura de la llamada Generación de Transición en Ecuador, la cual constituye, a su criterio, el segundo esfuerzo por superar las coordenadas estéticas de la literatura de la década de 1930. Señala los vínculos y rasgos diferenciales de los narradores de los 50 respecto de los del 30, y remarca el rol de Pablo Palacio y Humberto Salvador –autores que realizaron el primer esfuerzo de distanciamiento de la literatura del 30. El análisis considera cuentos de cinco narradores de los 50, poniendo énfasis en la nueva actitud ante el lenguaje, entre otros aspectos. Los textos que analiza son: «Locura» de Alfonso Cuesta y Cuesta, «Vinatería del Pacífico» de César Dávila Andrade, «Una sombra protectora» de Arturo Montesinos Malo, «La manzana dañada» de Alejandro Carrión, y «Tangos» de Pedro Jorge Vera.

Paradojas e incertidumbres de las economías andinas (Coyuntura)

El artículo parte de señalar la contradicción entre un desempeño macroeconómico, generalmente calificado como favorable, de las economías andinas en lo que va del presente siglo, sustentado en mayores tasas de crecimiento del PIB Y en la reducción del ritmo inflacionario, con el significativo agravamiento de la inestabilidad política en la región, que se ha constituido en la zona más conflictiva del continente. Posteriormente, se examina detenidamente el comportamiento de las economías andinas, estableciendo sus limitaciones y sobre todo los elevados niveles de desempleo en todos los países andinos, como factores estructurales que unidos a la crisis de sus instituciones políticas configuran una situación paradójica y muy frágil. En este contexto, la apuesta al TLC que realizan tres de sus miembros, con diversos grados de decisión, significa una seria amenaza para la integración andina y abre serias dudas sobre el balance de costos y beneficios.

Consequences of N,C,N '- and C,N,N '-coordination modes on electronic and photophysical properties of cyclometalated aryl ruthenium(II) complexes

The effects of isoelectronic replacement of a neutral nitrogen donor atom by an anionic carbon atom in terpyridine ruthenium(II) complexes on the electronic and photophysical properties of the resulting N,C,N'- and C,N,N'-cyclometalated aryl ruthenium(II) complexes were investigated. To this end, a series of complexes was prepared either with ligands containing exclusively nitrogen donor atoms, that is, [Ru(R-1-tpy)(R-2-tpy)](2+) (R-1, R-2 = H, CO2Et), or bearing either one N,C,N'- or C,N,N'-cyclometalated ligand and one tpy ligand, that is, [Ru(R-1-(NCN)-C-Lambda-N-Lambda)(R-2-tpy)](+) and [Ru(R-1-(CNN)-N-Lambda-N-Lambda)(R-2-tpy)](+), respectively. Single-crystal X-ray structure determinations showed that cyclometalation does not significantly alter the overall geometry of the complexes but does change the bond lengths around the ruthenium(II) center, especially the nitrogen-to-ruthenium bond length trans to the carbanion. Substitution of either of the ligands with electron-withdrawing ester functionalities fine-tuned the electronic properties and resulted in the presence of an IR probe. Using trends obtained from redox potentials, emission energies, IR spectroelectrochemical responses, and the character of the lowest unoccupied molecular orbitals from DFT studies, it is shown that the first reduction process and luminescence are associated with the ester-substituted C,N,N'-cyclometalated ligand in [Ru(EtO2C-(CNN)-N-Lambda-N-Lambda)(tpy)](+). Cyclometalation in an N,C,N'-bonding motif changed the energetic order of the ruthenium d(zx), d(yz), and d(xy) orbitals. The red-shifted absorption in the N,C,N'-cyclometalated complexes is assigned to MLCT transitions to the tpy ligand. The red shift observed upon introduction of the ester moiety is associated with an increase in intensity of low-energy transitions, rather than a red shift of the main transition. Cyclometalation in the C,N,N'-binding motif also red-shifts the absorption, but the corresponding transition is associated with both ligand types. Luminescence of the cyclometalated complexes is relatively independent of the mode of cyclometalation, obeying the energy gap law within each individual series.

Adsorption and dissociation of benzene on bimetallic surfaces - the influence of surface geometry and electronic structure

This topical review discusses the influence of the surface geometry (e.g. lattice parameters and termination) and electronic structure of well-defined bimetallic surfaces on the adsorption and dissociation of benzene. The available data can be divided into two categories with combinations of non-transition metals and transition metals on the one side and combinations of two transition metals on the other. The main effect of non-transition metals in surface alloys is site blocking which can suppress chemisorption and dissociation of the molecules completely. When two transition metals are combined, the effects are less dramatic. They mainly affect the strength of the chemisorption bond and the degree of dissociation due to electronic and template effects.

Strong-segregation limit of the self-consistent field theory for diblock copolymer melts

The self-consistent field theory (SCFT) introduced by Helfand for diblock copolymer melts is expected to converge to the strong-segregation theory (SST) of Semenov in the asymptotic limit, $\chi N \rightarrow \infty$. However, past extrapolations of the lamellar/cylinder and cylinder/sphere phase boundaries, within the standard unit-cell approximation, have cast some doubts on whether or not this is actually true. Here we push the comparison further by extending the SCFT calculations to $\chi N = 512,000$, by accounting for exclusion zones in the coronae of the cylindrical and spherical unit cells, and by examining finite-segregation corrections to SST. In doing so, we provide the first compelling evidence that SCFT does indeed reduce to SST.

An introduction to the Chinese Evaluation Standard for the indoor thermal environment

Designing for indoor thermal environmental conditions is one of the key elements in the energy efficient building design process. This paper introduces a development of the Chinese national Evaluation Standard for indoor thermal environments (Evaluation Standard). International standards including the ASHRAE55, ISO7730, DIN EN, and CIBSE Guide-A have been reviewed and referenced for the development of the Evaluation Standard. In addition, over 28,000 subjects participated in the field study from different climate zones in China and over 500 subjects have been involved in laboratory studies. The research findings reveal that there is a need to update the Chinese thermal comfort standard based on local climates and people's habitats. This paper introduces in detail the requirements for the thermal environment for heated and cooled buildings and free-running buildings in China.

Electrocatalytic reduction of carbon dioxide with a manganese(I)tricarbonyl complex containing a nonaromatic α‑diimine ligand

The 2e reduced anion [Mn(CO)3(iPr-DAB)]− (DAB = 1,4- diazabuta-1,3-diene, iPr = isopropyl) was shown to convert in the presence of CO2 and a small amount of water to the unstable complex [Mn(CO)3(iPr-DAB)(η1-OCO2H)] (OCO2H− = unidentate bicarbonate) that was further reductively transformed to give a stable catalytic intermediate denoted as X2, showing νs(OCO) 1672 and 1646 (sh) cm−1. The subsequent cathodic shift by ca. 650 mV in comparison to the single 2e cathodic wave of the parent [Mn(CO)3(iPr-DAB)Br] triggers the reduction of intermediate X2 and catalytic activity converting CO2 to CO. Infrared spectroelectrochemistry has revealed that the high excess of CO generated at the cathode leads to the conversion of [Mn(CO)3(iPr-DAB)]− to inactive [Mn(CO)5]−. In contrast, the five-coordinate anion [Mn(CO)3(pTol-DAB)]−(pTol = 4-tolyl) is completely inert toward both CO2 and H2O (solvolysis). This detailed spectroelectrochemical study is a further contribution to the development of sustainable electro- and photoelectrocatalysts of CO2 reduction based on abundant first-row transition metals, in particular manganese.

Climate change projections and selected impacts for Vietnam

In September 2013, the 5th Assessment Report (5AR) of the International Panel on Climate Change (IPCC) has been released. Taking the 5AR cli-mate change scenarios into account, the World Bank published an earli-er report on climate change and its impacts on selected hot spot re-gions, including Southeast Asia. Currently, dynamical and statistical-dynamical downscaling efforts are underway to obtain higher resolution and more robust regional climate change projections for tropical South-east Asia, including Vietnam. Such initiatives are formalized under the World Meteorological Organization (WMO) Coordinated Regional Dynamic Downscaling Experiment (CORDEX) East Asia and Southeast Asia and also take place in climate change impact projects such as the joint Vietnam-ese-German project “Environmental and Water Protection Technologies of Coastal Zones in Vietnam (EWATEC-COAST)”. In this contribution, the lat-est assessments for changes in temperature, precipitation, sea level, and tropical cyclones (TCs) under the 5AR Representative Concentration Pathway (RCP) scenarios 4.5 and 8.5 are reviewed. Special emphasis is put on changes in extreme events like heat waves and/or heavy precipita-tion. A regional focus is Vietnam south of 16°N. A continued increase in mean near surface temperature is projected, reaching up to 5°C at the end of this century in northern Vietnam un-der the high greenhouse-gas forcing scenario RCP8.5. Overall, project-ed changes in annual precipitation are small, but there is a tendency of more rainfall in the boreal winter dry season. Unprecedented heat waves and an increase in extreme precipitation events are projected by both global and regional climate models. Globally, TCs are projected to decrease in number, but an increase in intensity of peak winds and rain-fall in the inner core region is estimated. Though an assessment of changes in land-falling frequency in Vietnam is uncertain due to difficul-ties in assessing changes in TC tracks, some work indicates a reduction in the number of land-falling TCs in Vietnam. Sea level may rise by 75-100 cm until the end of the century with the Vietnamese coastline experienc-ing 10-15% higher rise than on global average. Given the large rice and aquaculture production in the Mekong and Red River Deltas, that are both prone to TC-related storm surges and flooding, this poses a challenge to foodsecurity and protection of coastal population and assets.

Adaptive climate change governance for urban resilience

Climate change poses new challenges to cities and new flexible forms of governance are required that are able to take into account the uncertainty and abruptness of changes. The purpose of this paper is to discuss adaptive climate change governance for urban resilience. This paper identifies and reviews three traditions of literature on the idea of transitions and transformations, and assesses to what extent the transitions encompass elements of adaptive governance. This paper uses the open source Urban Transitions Project database to assess how urban experiments take into account principles of adaptive governance. The results show that: the experiments give no explicit information of ecological knowledge; the leadership of cities is primarily from local authorities; and evidence of partnerships and anticipatory or planned adaptation is limited or absent. The analysis shows that neither technological, political nor ecological solutions alone are sufficient to further our understanding of the analytical aspects of transition thinking in urban climate governance. In conclusion, the paper argues that the future research agenda for urban climate governance needs to explore further the links between the three traditions in order to better identify contradictions, complementarities or compatibilities, and what this means in practice for creating and assessing urban experiments.

Koncentrisk hämning och stimulans av bakterietillväxt i agarkulturer

The aim of this study is to elucidate factors that effect growth of Sarcina lutea and Bacillus subtilis, exposed to the growth inhibitor SDS (Sodiumdodecylsulfat). Agar diffusion experiments revealed repeated, concentric zones of inhibition and stimulation upon exposure to Sodiumdodecylsulphate or to Amoxicillin. Temperature, nutrient concentration and inhibitor concentration were controlled. Formation of successively repeated zones of inhibition, stimulation, inhibition and stimulation is discussed: •The extension of the primary inhibition zone is due to the concentration of applied Sodium dodecyl sulphate.•Immediately outside the primary inhibition zone the bacteria have access to diffusing nutrients that have not been consumed in the primary inhabitation zone.•In zones of dense bacterial growth the bacteria may produce inhibiting substances, affecting growth of bacteria in adjacent zones.•In zones of dense bacterial growth the nutrients will soon become depleted, thus affecting bacteria in adjacent zones.