模拟酸雨条件下树木氨基酸变化与害虫的发生关系

本文通过人工模拟酸雨试验小区置木招引的研究方法,对马尾松次期性害虫进行了招引试验,并对样木中16种氨基酸含量进行了分析。结果表明,马尾松样木在人工模拟酸雨条件下比对照都易招次期性害虫的入侵,样木中氨基酸含量也比对照高。但在强酸(pH=2)条件下其氨基酸含量比对照低,其原因还有待进一步探讨。

长期定位施肥对黑垆土剖面养分分布特征的影响

对黄土高原旱地 1 5年连续施肥后土壤剖面养分分布的研究发现 ,施化肥对土壤剖面有机质、全N、全P含量的影响深达 1 0 0cm以下 ,所有施肥处理有机质、全N、全P、NO3- N、有效P含量在耕层 (0～ 2 0cm)都有不同程度增加 ;40～ 60、60～ 80cm土层有机质、全N、全P都低于长年不施肥处理 ,造成土壤下层养分的亏缺。长期大量施用氮肥造成N素养分下淋累积 ;长期大量施用磷肥土壤耕层有效P显著提高 ,而 2 0cm以下土层变化不大。

中国地形起伏度的提取及在水土流失定量评价中的应用

基于全国 1:10 0万的栅格数字高程模型 ( DEM)数据 ,在 ARC/ INFO的 GRID模块支持下 ,利用窗口分析方法 ,经过采样统计 ,确定中国水土流失地形起伏度的最佳分析窗口大小为 5 km× 5 km;基于 5 km× 5 km的分析窗口 ,提取了中国水土流失地形起伏度 ,完成了中国水土流失地形起伏度制图 ;最后对中国水土流失地形起伏度进行了适用性分析 ,并将其初步应用于中国潜在水土流失评价

基于DEA模型的我国自然灾害区域脆弱性评价

应用数据包络分析(Data Envelopment Analysis,DEA)模型对我国自然灾害的区域脆弱性水平进行研究,在区域灾害系统理论的组织框架下,从区域自然灾害危险性、区域承灾体暴露性和区域自然灾害损失度三个方面构建了区域自然灾害系统的DEA投入产出模型,并利用模型得出的区域自然灾害成灾效率对区域自然灾害的脆弱性进行模拟反映,对我国自然灾害脆弱性的区域分异特征进行分析。研究发现:我国自然灾害脆弱性的整体水平较高,地域格局为西部>中部>东部,且脆弱性水平与地区经济水平具有明显的负相关关系,经济发达地区的脆弱性相对较低。

21世纪初中国生态退耕的空间格局及黄土高原典型区退耕的生态位适宜性分析(英文)

自1999年我国开始试行以"退耕还林"工程为主的生态退耕以来,到目前已历时十年。特别是进入21世纪,工程实施强度较大,因此从国家尺度上进行宏观生态退耕格局的分析对于评估生态退耕政策和确定未来政策导向具有重要意义。本研究以TM遥感监测的土地利用变化数据库为基础分析2000-2005年生态退耕的时空格局。在此基础上,以黄土高原典型地区陕西中北部为研究区,采用生态位适宜度评价模型探讨了生态退耕工程实施的合理性。研究结果表明:(1)2000-2005年间,生态退耕主要集中在中国中部地区,尤其是在黄河和长江的中上游地区,生态退耕面积与建设占用面积基本持平。在各生态类型区中,黄土高原土壤侵蚀区生态退耕面积最大,达到了1162.50km~2,主要用于还林;(2)整体看来,研究区内生态退耕的空间格局是合理的,即适宜性越差的耕地退耕比例越大。从退耕区域的适宜性水平来看,有77.35%的地区属于勉强适宜区,其中退为林地的面积为603.32km~2,退为草地的面积为528.94km~2。整个研究区内前者大于后者。然而,退耕地中仍有19.38%属于中度适宜区,原因可能来自于退耕指标分配等管理因素,另外,当地农民外出务工从而将中等适宜度的耕地退耕。结果表明,当前仍有大面积不适宜和勉强适宜的耕地存在,在未来工程实施过程区应该首先考虑该类地区。

Novel White Electroluminescent Single Polymer Derived from Fluorene and Quinacridone

A novel series of white light emitting single polymers are prepared by incorporating low contents of quinacridone into the main chain of polyfluorene. This is the first report of quinacridone-containing conjugated polymer. Single layer devices (ITO/PEDOT:PSS/polymer/Ca/Al) are fabricated with these polymers. Energy transfer from fluorene segments to quinacridone unit is observed. Moreover, in the EL process, quinacridone unit can trap electrons and cannot trap holes from fluorene segments.

Cyclization of citronellal to p-menthane-3,8-diols in water and carbon dioxide

A clean process has been developed for the synthesis of p-menthane-3,8-diols from cyclization of citronellal in CO2-H2O medium without any additives. With the addition of CO2, the reaction rate could be enhanced about 6 times for the cyclization of citronellal in H2O, because CO2 dissolved into water and formed carbonic acid inducing an increase of the acidity. Although, the reaction conversion in CO2-H2O is slightly lower compared to that obtained with sulfuric acid as catalyst, CO2-H2O could replace the sulfuric acid at a relative higher reaction temperature. The reaction kinetics studies showed that the hydration of isopulegols to p-menthane-3,8-diols is a reversible reaction. The equilibrium constant and the maximum equilibrium yield obtained in CO2-H2O at a range of CO2 pressures are similar to that with sulfuric acid catalyst.

Nanoelectrocatalyst based on high-density Au/Pt hybrid nanoparticles supported on a silica nanosphere

A high-efficiency nanoelectrocatalyst based on high-density Au/Pt hybrid nanoparticles supported on a silica nanosphere (Au-Pt/SiO2) has been prepared by a facile wet chemical method. Scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy are employed to characterize the obtained Au-Pt/SiO2. It was found that each hybrid nanosphere is composed of high-density small Au/Pt hybrid nanoparticles with rough surfaces. These small Au/Pt hybrid nanoparticles interconnect and form a porous nanostructure, which provides highly accessible activity sites, as required for high electrocatalytic activity. We suggest that the particular morphology of the AuPt/SiO2 may be the reason for the high catalytic activity. Thus, this hybrid nanomaterial may find a potential application in fuel cells.

纳米AgBr/PMMA光致变色杂化材料制备与表征

采用本体聚合法制备了纳米AgBr/PMMA(聚甲基丙烯酸甲酯)光致变色杂化材料.XRD分析表明,纳米AgBr/PMMA杂化材料是无定形的.SEM分析表明,AgBr含量不同,杂化材料的断面形貌明显不同,随AgBr含量的增加,杂化材料由韧性断裂向脆性断裂转变.EDS面分析表明,Ag、Br元素在杂化材料中均匀分布.所制备的纳米AgBr/PMMA杂化材料具有一定的光致变色效应.

Nonisothermal crystallization behavior of poly (L-lactide)-poly(ethylene glycol) dibloick copolymer

The nonisothermal crystallization behavior of poly (L-lactide)-poly(ethylene glycol) ( PLLA-PEG) diblock copolymer was studied by means of real-time WAXD, DSC and POM, and Ozawa equation was used to analyze the kinetics of PLLA-PEG under nonisothermal crystallization conditions. During the crystallization of the high-T-m block (PLLA), the low-T-m block (PEG) acts as a noncrystalline diluent, and the crystallization behavior of PLLA obeys the Ozawa theory. When the PEG block begins to crystallize, the PLLA phase is always partially solidified and the presence of the spherulitic microstructure of PLLA profoundly restricts its crystallization behavior, which results in that the overall crystallization process does not obey the Ozawa equation. Furthermore, the study of the crystalline morphology of PLLA-PEG at different cooling rates indicates that when the cooling rate is from low to high, the crystalline morphology undergoes a transformation from the ring-banded spherulites to the typical Maltese cross spherulites, which experiences the mixed crystalline morphologies of ring-banded and typical Maltese cross spherulites, and the spherulitic size becomes smaller.

癸酸钕顺丁橡胶扩试胶样的性能

研究了癸酸钕催化聚合顺丁橡胶的扩试胶样的性能。结果表明 ,改变聚合条件不仅导致聚合物分子链结构变化 ,降低分子量及其分子量分布 ,而且也会影响生胶和硫化胶的性能。此批胶样拉伸强度虽不高 ,但耐磨、生热、抗湿滑等动态性能良好。