Nanoelectrocatalyst based on high-density Au/Pt hybrid nanoparticles supported on a silica nanosphere


Autoria(s): Guo SJ; Zhai JF; Fang YX; Dong SJ; Wang E
Data(s)

2009

Resumo

A high-efficiency nanoelectrocatalyst based on high-density Au/Pt hybrid nanoparticles supported on a silica nanosphere (Au-Pt/SiO2) has been prepared by a facile wet chemical method. Scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy are employed to characterize the obtained Au-Pt/SiO2. It was found that each hybrid nanosphere is composed of high-density small Au/Pt hybrid nanoparticles with rough surfaces. These small Au/Pt hybrid nanoparticles interconnect and form a porous nanostructure, which provides highly accessible activity sites, as required for high electrocatalytic activity. We suggest that the particular morphology of the AuPt/SiO2 may be the reason for the high catalytic activity. Thus, this hybrid nanomaterial may find a potential application in fuel cells.

Identificador

http://ir.ciac.jl.cn/handle/322003/12541

http://www.irgrid.ac.cn/handle/1471x/148683

Idioma(s)

英语

Fonte

Guo SJ;Zhai JF;Fang YX;Dong SJ;Wang E.Nanoelectrocatalyst based on high-density Au/Pt hybrid nanoparticles supported on a silica nanosphere,CHEMISTRY-AN ASIAN JOURNAL ,2009,3(7):1156-1162

Palavras-Chave #METHANOL FUEL-CELL #OXYGEN-REDUCTION #CARBON NANOTUBES #HOLLOW NANOSPHERES #ALKALINE MEDIA #PT-CO #ELECTROCATALYSTS #ELECTROOXIDATION #ELECTRODES #ALLOY
Tipo

期刊论文