Zeolite Encapsulated Complexes Of Fe,Co,Ni,Cu And Pd:Synthesis , Characterization And Catalysis-2003

This thesis deals with the synthesis, characterization and catalysis activity studies of some zeolite encapsulated complexes. Encapsulation inside the zeolite cages makes the catalysts more stable. Further, the framework prevents the complexes from dimerising. Catalysis by metal complexes encapsulated in the cavities of zeolites and other molecular sieves has many features of homogeneous, heterogenous and enzymatic catalysis. Serious attempts has been made to gain product selectivity in catalysis .The catalytic activity shown by the encapsulated complexes can be correlated to the structure of the active site inside the zeolite pore. It deals with the studies on the partial oxidation of benzyl alcohol to benzaldehyde. The oxidatio was carried out using hydrogen peroxide as oxidant in presence of PdYDMG and CuYSPP as catalysts. The product (benzaldehyde) was detected using TLC and confirmed using GC.The catalytic activity of the complexes was tested for oxidation under various conditions. The operating conditions like the amount of the catalyst, reaction time, oxidant to substrate ratio, reaction temprature, and solvents have been optimized. No further oxidation products were obtained on continuing the reaction for four hours beyond the optimum time. Maximum conversion was obtained at room temperature and the percentage conversion decreased with increase in temperature. Activity was found to be dependent on the solvent used. With increasing awareness about the dangers of environmental degradation, research in chemistry is getting increasing geared to the development of “green chemistry,” by designing environmentally friendly products and processes that bring down the generation and use of hazardous substances.

Farm Programmes of Electronic Media: A Comparative Study of Audience Perception in Kerala

Farm communication and extension programs are vital part of the farm development attempts. Electronic media plays a major role in farm extension activities. Kerala, the consumer state, which was a complete agricultural state in pre-independence period, is the sprouting land of agricultural extension and publication activities in print media. Later AIR (All India Radio) farm programs and farm broadcasting of Doordarshan enriched the role of electronic media in farm extension activities. The media saturated southern state of India received this new electronic media farm communication revolution whole heartedly. However, after 1990, Kerala witnessed a flood of private T V channels and currently there are 24 channels in this regional language, named Malayalam. All major news and entertainment channels are broadcasting farm programs. Farm programs of AIR and Doordarshan, broadcasted in Malayalam language, have been well accepted to the farmers‘ in Kerala. However, post-independence period, witnessed the formation of Kerala state in Indian Union and the first ballot-elected communist Government started its administration. After the land reform bills, the state witnessed a gradual decrease in agricultural production. Even if it is not reflected much in the attitude and practices of farm community and farm broadcast of traditional electronic broadcasting, a change is observable after the post-liberalization era of India. Private Television channels, which were focused on entertainment value of programs, started broadcasting farm programs and the parameters of program production went through certain changes. In this situation, there is ample relevance for a study about the farm programs of electronic media in terms of a comparative study of audience perception. The study is limited in the state of Kerala as it is the most media saturated state in India. The study analyzes the rate, nature and scope of adoption of farming methods transmitted through electronic media (T.V. and Radio) in Malayalam language.All kinds of Farm programs including comprehensive program serials, success stories, seasonal cropping methods, experts opinion, been analyzed on the basis of the following objectives.  To find whether propagating new farm methods through farm programs in electronic media or the availability of adequate infrastructure and economic factors make a farmer to adopt a new farming method.  To find which electronic media has more influence on farmers to adopt agricultural programs.  To find which form of electronic media gets better feedback from farmers  To find out whether the programs of T.V. or Radio is more acceptable to farmers than the print media.  To find whether farmers gets the message through their preferred medium for the message. The researcher recorded opinions from a panel of agricultural officers, farm Information officers, agro extension researchers and experts. According to their opinions and guidelines, a pilot study is designed and conducted in Kanjikuzhy Panchayath, in Alappuzha district, Kerala. The Panchayath is selected by considering its ideal nature of being the sample for a social Science research. Besides, the nature of farming in the Panchayath, which devoid of the cultivation of cash crops also supported its sample value. As per the observations from the pilot study, researcher confirmed the Triangulation method as the methodology of research. The questionnaire survey, being the primary part contained 42 Questions with 6 independent and 32 dependent variables. The survey is conducted among 400 respondents in Idukki, Alappuzha and Pathanamthitta districts considering geographical differences and distribution of different types of crops. The response from a total of 360 respondents, 120 from each district, finally selected for tabulation and data analysis.The data analysis, based on percentage analysis, along with the results from focus group discussion among a selected group of 20 farmers, together produced the results as follows. Farmers, who are the audience of farm programs, have a very serious approach towards the medium. They are maintaining a critical point of view towards the content of the programs. Farmers are reasonably aware about the financial side of the programs and the monitory aspirations of both private and Government owned Television channels. Even though, the farmers are not aware on the technical terminology and jargons, they have ideas about success stories, program serials and they are even informed about channels are not maintaining an audience research section like AIR. Though the farmers accept Doordarshan as the credential source of farm information and methods, they are inclined to the entertainment value of programs too. They prefer to have more entertainment value for the programs of Doordarshan. Surprisingly, they have very solid suggestions on even about the shots which add entertainment value to the farm broadcasting methods of Doordarshan. Farmers are very much aware about the fact that media is just an instrument for inspiration and persuasion. They strongly believe that the source of information and new methods is agricultural research and an effective change happens only when there are adequate infrastructure and marketing facilities, along with the proper support from Government agricultural guideline and support systems like Krishi Bhavans. They strongly believe that media alone cannot create any magic in increasing agricultural production. Farmers are pointing out the lack of response to the feedback and queries of farmers on farming methods, as an evidence for the difference in levels of commitment of Government and private owned Television channels.Farmers are still perceiving AIR farm programs are far more committed to farmers and farming than any other electronic medium. However, they are seriously lacking Radio receivers with medium wave reception facility. Farmers perceive that the farming methods on new crops are more adoptable than the farming methods of traditional crops in both private and Government owned Television channels. There are multiple factors behind this observation from farmers. Farmers changed in terms of viewing habits and they prefer success stories, which are totally irrelevant and they even think that such stories encourage people to go for farming and they opined that such stories are good sources of inspiration. However, they are all very much sure about the importance and particular about the presence of entertainment factor even in farm programs. Farmers expect direct interaction of any expert of the new farming method to implement the method in their agriculture practices. Though introduction of a new idea in the T.V. is acceptable, farmers need the direct instruction of expert on field to start implementing the new farming practices Farmers still have an affinity towards print media reports and agricultural pages and they have complaints to print media on the removal of agricultural information pages from news papers. They prefer the reports in print media as it facilitates them to collect and refer articles when they need it. Farmers are having an eye of doubt about the credibility of farm programs by private T.V. channels. Even if they prefer private Television channels for listening and adopting new farming methods and other farm information, they scrutinize programs to know whether they are sponsored programs by agrochemical or agro-fertilizer manufacturer.

Studies on certain exploted marine finfish resource of India

This thesis Entitled Studies on certain exploited marine Finfish Resources of india.Marine fish catch forecasting is short term or long term basis for purposes of explation and management. Among the short term forecasts, two approaches need serious consideration in India: 1. to improve the methods of understanding the influence of environmental characteristics on the abundance or availability of fish in different areas in different periods and to make the forecasts of the same, 2. to make analysis of time series catch data (ARIMA models) to make forecasts of catch in the next year or in a particular period during next year. There is some evidence of suitability of these approaches to Indian marine fisheries but attempts aiming at comprehensive studies should be made. In the area of long term forecasts, considerable work is done in India on single species assessments but in the context of multi species, multigear nature of Indian marine fisheries, assessments of all species together in a mixed fishery are urgently required for effective managements of fisheries.

Palladium Catalyzed Carbon-Carbon/Carbonheteroatom Bond Formation Reactions Utilizing Pentafulvene Derived Bicyclic Hydrazines

The reactions involving fulvenes and its derivatives have received a great deal of attention over the years in synthetic organic chemistry. Functionalizations of fulvenes provide versatile and powerful approaches to various polycyclic systems and natural products. They serve as versatile intermediates in the construction of various ring systems through inter- as well as intramolecular cycloadditions. Compared to the rich literature on the cycloaddition reactions of pentafulvenes, much less attention has been paid to the synthetic utilization of their cycloadducts. Tactical manipulations on the chosen adduct offer the prospects for designing a variety of useful molecular skeletons. Addition of heterodienophiles to fulvenes offers an efficient strategy towards the synthesis of azabicyclic olefins. However, there have been no serious attempts to study the synthetic utility of these substrates. In this context and with the intention of utilizing pentafulvenes towards synthetically important molecules, author decided to explore the reactivity of pentafulvene derived azabicyclic olefins. Our attention was focused on the synthetic potential associated with the ring opening of fulvene derived bicyclic hydrazines under palladium catalysis. It was envisioned that the desymmetrization of these adducts using various soft nucleophiles will provide a novel access to synthetically and biologically important alkylidene cyclopentenes. The investigations along this line form the focal theme of this thesis entitled “PALLADIUM CATALYZED CARBONCARBON/ CARBON-HETEROATOM BOND FORMATION REACTIONS UTILIZING PENTAFULVENE DERIVED BICYCLIC HYDRAZINES

“Stress Responses of Stinging Catfish Heteropneustes fassilis (Bloch) to Organophosphorus Insecticide Monocrotophos”

Poisoning by pesticides from agricultural fields is a serious water pollution problem and its environmental long-term effect may result in the incidence of poisoning of fish and other aquatic life forms (jyothi and Narayan, 1999). Fishes like Heteropneustesfbssilis and C/arius batrac/nus are especially prone to serious pesticide pollution as their habitat is mostly the agriculture area. Though only few studies are conducted in this area, it can be assessed from the local information that, population of such fish is on the verge of vulnerability due to extensive use of pesticides. The knowledge of sublethal effects of xenobiotic compounds on hematological parameters, enzyme activities and metabolite concentrations is very important to delineate the fish health status and provide a future understanding of ecological impacts. These pesticides act by causing inhibition of cholinesterase enzymes (ChE) by formation of enzyme inhibitor complex (O'Brien, 1976) and damaging the nervous system. These effects may result in metabolic disorders. Associated to cholinesterase activities, a study of other enzymes such as phosphatases and aminotransferases close to intermediary metabolite determination provides a wider view of metabolism. Interest in toxicological aspects has grown in recent years and research is now increasingly focused on mechanistic aspects of oxidative damage and cellular responses in biological system. The term ‘biomarker’ is generally used in a broad sense to include almost any measurement reflecting an interaction between a biological system and a potential hazard, which may be chemical, physical or biological (WHO, 1993). As biomarker stands for immediate responses, they are used as early warning signals of biological effects caused by environmental pollutants. The present work attempts to assess the toxicity of organophosphorus insecticide monocrotophos on the experimental organism selected for this study namely stinging catfish (Heteropneustesfossi/is) (Bloch), and to probe into the stress responses of the organism

Drinking water issues in Rural India: Need for stakeholders’ participation in Water resources management

Water is the very essential livelihood for mankind. The United Nations suggest that each person needs 20-50 litres of water a day to ensure basic needs of drinking, cooking and cleaning. It was also endorsed by the Indian National Water Policy 2002, with the provision that adequate safe drinking water facilities should be provided to the entire population both in urban and in rural areas. About 1.42 million rural habitations in India are affected by chemical contamination. The provision of clean drinking water has been given priority in the Constitution of India, in Article 47 conferring the duty of providing clean drinking water and improving public health standards to the State. Excessive dependence of ground water results in depletion of ground water, water contamination and water borne diseases. Thus, access to safe and reliable water supply is one of the serious concerns in rural water supply programme. Though government takes certain serious steps in addressing the drinking water issues in rural areas, still there is a huge gap between demand and supply. The Draft National Water Policy 2012 also states that Water quality and quantity are interlinked and need to be managed in an integrated manner and with Stakeholder participation. Water Resources Management aims at optimizing the available natural water flows, including surface water and groundwater, to satisfy competing needs. The World Bank also emphasizes on managing water resources, strengthening institutions, identifying and implementing measures of improving water governance and increasing the efficiency of water use. Therefore stakeholders’ participation is viewed important in managing water resources at different levels and range. This paper attempts to reflect up on portray the drinking water issues in rural India, and highlights the significance of Integrated Water Resource Management as the significant part of Millennium Development Goals, and Stakeholders’ participation in water resources management.

La despenalización del aborto en una sociedad liberal : el caso colombiano

El presente artículo pretende exponer un debate de filosofía política sobre un problema moral álgido: el aborto. Partiendo de la base de que en todas las democracias occidentales una cuestión central en esta discusión tiene que ver con quién es, en último término, el que debe o puede decidir sobre la legalidad del mismo, lo que aquí se analiza es el problema de diseño y legitimidad constitucional con que se responde en una democracia liberal a esta controversia. Reconociendo que no son pocas las ocasiones en que este controvertido debate moral ha dividido profundamente a la sociedad, el presente artículo tiene como objetivo específico explicar brevemente cuál fue el mecanismo utilizado para lograr la “despenalización” del aborto en Colombia, para luego analizar la justicia del procedimiento, las pretensiones de quienes promovieron la acción de constitucionalidad y, así mismo, la decisión de la Corte Constitucional a la luz del modelo de justicia de John Rawls, especialmente a la luz del concepto de consenso traslapado. Lo anterior, con el propósito de defender la postura de que, al menos en el modelo jurídico-político colombiano, existen serios reparos frente a quienes consideran que la Corte Constitucional es el órgano democráticamente competente para cerrar el debate respecto al aborto.

El entorno empresarial y las condicionantes tributarias y fiscales en América Latina

La primera parte de este estudio versa sobre los temas del crecimiento y el desarrollo y sobre la caracterización de las políticas económicas. La segunda sección se dedica a una caracterización de las condicionantes fiscales con base en las cuales desempeñan sus funciones los Gobiernos de América Latina y el Caribe. En la primera sección se discuten las principales características de las políticas fiscales, monetarias y cambiarias, y con fundamento en ellas se exponen los conceptos centrales relacionados con el desarrollo humano. El principal argumento a sostener aquí es que, en general, los países de menor desarrollo relativo, los que tienen que enfrentar los desafíos sociales más significativos, son también los que poseen condiciones fiscales más débiles o vulnerables. Los intentos de alcanzar mayores niveles de desarrollo implican la necesidad de realizar cambios efectivos en las condiciones fiscales de varios países latinoamericanos.

El problema de conceptualización del terrorismo dentro de la disciplina de las Relaciones Internacionales: Un análisis desde la perspectiva histórico conceptual

Los hechos ocurridos durante el 11 de septiembre de 2001 se constituyeron como un momento fundamental en los intentos de conceptualización del terrorismo internacional dentro de la disciplina de las Relaciones Internacionales. A raíz del 9/11 tuvo lugar la resemantización del concepto de terrorismo internacional en función del terrorismo religioso y del fundamentalismo islámico. Lo anterior, marco una ruptura en el campo de experiencia y en el horizonte de expectativas del concepto mismo, pues este último adquirió un nuevo uso discursivo, y por ende, político. Por eso, ante la necesidad de emprender un análisis discursivo de los usos del concepto de terrorismo internacional, se evidencia cómo al estar inmersos en determinados juegos del lenguaje, el uso discursivo de este concepto termina por convertirse en una herramienta de acción política que promueve una forma de vida.

The project of land restitution in Colombia: an illustration of the civilizing force of hypocrisy?

This article offers a theoretical interpretation of the dispositions on land restitution contained in the famous “Victims’ Bill”, which was debated in the Colombian Congress during the year 2008. The bill included specific mechanisms aimed at guaranteeing the restitution of land to victims of the Colombian armed conflict. At the time, the bill was endorsed by all the main political actors in the country –notably the government and the elites that support it, on the one hand, and victims’ and human rights organizations and other opposition groups, on the other–. The fact that the restitution of land to victims of the Colombian armed conflict was being considered as a serious possibility by all political actors in the country seemed to indicate the existence of a consensus among actors whose positions are ordinarily opposed, on an issue that has traditionally led to high levels of polarization. This consensus is quite puzzling, because it seems to be at odds with the interests and/or the conceptions of justice advocated by these political actors, and because the restitution of land faces enormous difficulties both from a factual and a normative point of view, which indicates that it may not necessarily be the best alternative for dealing with the issue of land distribution in Colombia. This article offers an interpretation of said consensus, arguing that it is only an apparent consensus in which the actors are actually misrepresenting their interests and conceptions of justice, while at the same time adopting divergent strategies of implementation aimed at fulfilling their true interests. Nevertheless, the article concludes that the common adherence by all actors to the principle of restorative justice might bring about its actual realization, and thus produce an outcome that, in spite (and perhaps even because) of being unintended, might substantively contribute to solving the problem of unequal land distribution in Colombia. Even though the article focuses in some detail on the specificities of the 2008 Bill, it attempts to make a general argument about the state of the discussion on how to deal with the issue of land distribution in the country. Consequently, it may still be relevant today, especially considering that a new Bill on land restitution is currently being discussed in Congress, which includes the same restitution goals as the Victims’ Bill and many of its procedural and substantive details, and which therefore seems to reflect a similar consensus to the one analyzed in the article.

Proyectos de integración en América Latina durante el siglo xx: el Mercosur y el sueño que continúa vigente

Desde el siglo xix, con la formación de los Estados nacionales en Latinoamérica, se han promovido proyectos integracionistas aún no concluidos. Actualmente se resalta la necesidad de la integración entre países en distintos aspectos: económico, político, militar, diplomático.El primer propósito es analizar históricamente los proyectos de integración en América Latina y dar una mirada al concepto de “panamericanismo”, que surgió en 1890 tras la Conferencia Internacional Americana: examinando el “panamericanismo” como concepto y como política que estuvo estrechamente ligada al surgimiento de Estados Unidos como potencia mundial, y el “panamericanismo”, desde la posición latinoamericana, entendido como el esfuerzo por parte del gobierno norteamericano por controlar política y militarmente a las distintas naciones del continente para favorecer en última instancia su expansión económica (Bobbio, Matteucci y Pasquino, 2002).El propósito final es destacar los intentos de integración en el siglo xx, especialmente desde los proyectos aparecidos en la década del sesenta hasta la formación del Mercado Común del Sur (Mercosur) en 1994; asimismo, observar las dificultades que ha tenido históricamente la comunidad regional, y analizar la experiencia del Mercosur como el más serio proceso de integración latinoamericano –vigente en los comienzos del siglo xxi– en el ámbito económico e, incluso, político.---Integration projects in Latin America during the 20th century: the ‘Mercosur’ and the dream that continues effectiveFrom the nineteenth century, with the formation of the national states in Latin America, have promoted an integrationist projects unfinished. Nowadays, the need of the integration is highlighted between countries in different aspects: economic, political, military man, diplomat.The first intention is to analyze historically the projects of integration in Latin America, and to give a look to the concept “Pan Americanism”, which arose in 1890 after the International American Conference: examining the “Pan Americanism” as concept and as politics that was closely linked to the emergence of The United States as world power, and the “Pan Americanism”, from the Latin-American position, understood as the effort on the part of the North American government for controlling politics and militarily to the different nations of the continent to promote its eventual economic expansion (Bobbio, Matteucci and Pasquino, 2002).The final intention is to emphasize the attempts of integration in the twentieth century, specially, from the projects appeared in the decade of sixty up to the formation of the Common Market of the South (Mercosur) in 1994. Likewise, to observe the difficulties that the regional community has had historically, and to analyze the experience of the Mercosur as the most serious Latin-American process of integration –in force in the beginning of the twenty-first century– in the economic area and, enclosedly, political.Key words: Latin America, pan americanism, integration, Mercosur, twentieth century---Projetos de interrogação na América Latina durante o século xx: O Mercosul e o sonho que continua vigenteDesde o século XIX, com a formação dos Estados nacionais na Latino-América, se têm promovido projetos integracionistas ainda não concluídos. Atualmente se ressalta a necessidade da integração entre países em distintos aspectos: econômico, político, militar, diplomático.O primeiro propósito é analisar historicamente os projetos de interrogação na América Latina e dar uma olhada ao conceito de “pan-americanismo”, que surgiu em 1890 depois da Conferencia Internacional Americana: examinado o “panamericanismo” como conceito e como política que esteve estreitamente ligada ao surgimento de Estados Unidos como potencia mundial, e o “pan-americanismo”, desde a posição latino-americana, entendido como o esforço por parte do governo norte-americano por controlar política e militarmente às distintas nações do continente para favorecer em última instância sua expansão econômica (Bobbio, Matteucci e Pasquino, 2002).O propósito final é destacar as tentativas de interrogação no século XX, especialmente desde os projetos aparecidos na década do sessenta até a formação do Mercado Comum do Sul – Mercosul (Mercado Común del Sur – Mercosur) em 1994; assim mesmo, observar as dificuldades que tem tido historicamente a comunidade regional, e analisar a experiência do Mercosul como mais importante processo de integração latino-americano –vigente a princípios do século XXI- no âmbito econômico e, inclusive, político.Palavras chave: Latino-américa, pan-americanismo, integração, Mercosul, século XX

Apoyo social e ideación suicida en pacientes con cáncer

El diagnóstico de cáncer ha sido asociado con un alto riesgo de presentar ideación suicida en comparación con la población no oncológica, sin embargo se ha considerado al apoyo social como un factor protector para la ocurrencia de esta conducta. La presente investigación tuvo como objetivo identificar la relación entre el apoyo social percibido y la ideación suicida en 90 pacientes oncológicos adultos en Bogotá, bajo la hipótesis de que a mayor apoyo social percibido, menor presencia de ideación suicida. Se midió la variable de apoyo social a través del cuestionario Duke UNC y la ideación suicida a través de cuatro instrumentos: Escala de Ideación Suicida (SSI), Escala de Desesperanza de Beck (BHS), el ítem 9 del Inventario de Depresión de Beck (BDI-IA) y una entrevista semiestructurada. Los resultados mostraron que no existe relación entre el apoyo social percibido y la ideación suicida. Por otro lado se identificó una prevalencia de suicidio entre 5,6% y 22,77%, confirmando que el paciente con cáncer considera el suicidio y es fundamental evaluar esta variable en esta población. Se considera importante continuar con la realización de investigaciones que permitan generalizar los resultados a la población oncológica colombiana.

Serious Games para el desarrollo de las competencias del siglo XXI

Resumen basado en el de la publicaci??n

Desarrollo de las competencias de colaboraci??n con el uso del Serious Game MetaVals

Resumen basado en el de la publicaci??n