9 resultados para Optical films

em Doria (National Library of Finland DSpace Services) - National Library of Finland, Finland


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The structure and optical properties of thin films based on C60 materials are studied. Reproducible vacuum method of thin fullerene films production with Cd impurity on Si, glass and mica surfaces is developed. Surface morphology of the films are investigated by AFM and SEM methods. The ab initio quantum - chemical calculations of the geometry, total energy and excited energy states of complex fullerene- cadmium telluride supramolecules are performed. Photoluminescence spectra of composite thin films based on C60 before and after X-ray irradiation were measured. The intensity of additional peaks is defined as the charge composition due to the type of substrate. These results are interpreted as an appearance of the dipole-allowed transitions in the fullerene excited singlet states spectrum cause of an interference with cadmium telluride. X-ray irradiated films were investigated, and additional peaks in photoluminescence spectra were detected. These peaks appear as a result of molecular complexes formation from C60CdTe mixture and dimerization of the films. Density functional B3LYP quantum-chemical calculations for C60CdTe, molecular complexes, (C60)2 and C120O dimers were performed to elucidate some experimental results.

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Bacteriorhodopsin (BR) is a light-sensitive protein, which is a promising material for various technical applications, such as photosensors. The quality of dry thick BR photosensors depends on few performance characteristics. Uniformity of parameters, which have the impact on such characteristics, should be maintained during the preparation or otherwise compensated afterwards. In this thesis, uniformity examination techniques were studied. Experimental setups, which operate, based on studied techniques, were designed. Experiments, which were conducted on constructed setups, revealed a list of dependencies between BR properties and allowed to evaluate properties of sensors.

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In this thesis, bacteriorhodopsin (BR) photosensor’s optical and electrical properties were studied. The BR sensor consisted of a dry film with BR in polyvinyl alcohol and covered with transparent conductors. In the experiments the BR photocycle was started with two lasers. The characteristics of the BR sensor were measured in two ways. The first approach was theoretical and it required knowing the laser parameters. The second way required assembling a measurement setup for the optical response measurements. However, no measurable results were obtained due to low laser power. The photoelectric response was measured in the experiments with two laser systems and the amplifier was tested. In the experiment with a Cavitar laser, the photoelectric response was obtained. In the experiment with FemtoFiber Pro laser, the photoelectric response was not measured. The expected amplitude of the response was obtained. The experimental data was analyzed and possible solutions for reducing the interference were given.

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Abstract: Readin films through political classics

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Selostus: Syötävien gluteenikalvojen valmistus, ominaisuudt ja eräät käyttösovellukset