Theoretical and computational approaches on heterogeneous nucleation

Nucleation is the first step of a first order phase transition. A new phase is always sprung up in nucleation phenomena. The two main categories of nucleation are homogeneous nucleation, where the new phase is formed in a uniform substance, and heterogeneous nucleation, when nucleation occurs on a pre-existing surface. In this thesis the main attention is paid on heterogeneous nucleation. This thesis wields the nucleation phenomena from two theoretical perspectives: the classical nucleation theory and the statistical mechanical approach. The formulation of the classical nucleation theory relies on equilibrium thermodynamics and use of macroscopically determined quantities to describe the properties of small nuclei, sometimes consisting of just a few molecules. The statistical mechanical approach is based on interactions between single molecules, and does not bear the same assumptions as the classical theory. This work gathers up the present theoretical knowledge of heterogeneous nucleation and utilizes it in computational model studies. A new exact molecular approach on heterogeneous nucleation was introduced and tested by Monte Carlo simulations. The results obtained from the molecular simulations were interpreted by means of the concepts of the classical nucleation theory. Numerical calculations were carried out for a variety of substances nucleating on different substances. The classical theory of heterogeneous nucleation was employed in calculations of one-component nucleation of water on newsprint paper, Teflon and cellulose film, and binary nucleation of water-n-propanol and water-sulphuric acid mixtures on silver nanoparticles. The results were compared with experimental results. The molecular simulation studies involved homogeneous nucleation of argon and heterogeneous nucleation of argon on a planar platinum surface. It was found out that the use of a microscopical contact angle as a fitting parameter in calculations based on the classical theory of heterogeneous nucleation leads to a fair agreement between the theoretical predictions and experimental results. In the presented cases the microscopical angle was found to be always smaller than the contact angle obtained from macroscopical measurements. Furthermore, molecular Monte Carlo simulations revealed that the concept of the geometrical contact parameter in heterogeneous nucleation calculations can work surprisingly well even for very small clusters.

Toimijaroolit ja roolien välinen dynamiikka Vihreän liiton periaateohjelmassa 2006

Pro gradu -tutkielmassani tarkastelen toimijarooleja poliittisen puolueen periaateohjelmassa. Aineistonani on Vihreän liiton vuonna 2006 voimaan tullut periaateohjelma. Periaateohjelma on puolueen yhteisen keskustelun tuloksena syntyvä, kantaaottava ja voimakkaan ideologinen teksti, johon valikoidaan mukaan puolueen tärkeäksi katsomat asiat. Ohjelma on tekstinä preskriptiivinen ja sisältää runsaasti toimintavaatimuksia ja -ohjeita, mikä korostaa toimijuuden keskeisyyttä tutkimuskohteena juuri tässä tekstilajissa. Tekstilajikysymykset ja periaateohjelman kirjoituksen konventiot vaikuttavat myös aineistossani leimalliseen aktiivisesti toimivan subjektin häivyttämisen. Pyrin erittelemään ja analysoimaan Vihreän liiton ohjelmaa tapausesimerkkinä siitä, miten toimijaroolien kautta rakennetaan ohjelmatekstin maailmaa ja toimijoiden suhteita siinä. Välineenä analyysissani käytän A.J. Greimasin kehittelemää aktanttimallia (katso Greimas 1979). Semanttinen malli jäsentää tekstin maailman toimijoita rooleihin niiden suorittamien funktioiden perusteella. Keskeisimmät tarkasteltavat roolit ovat aktiivisen toimijan kategoria, statiivisen vaikuttajan kategoria ja toiminnan kohteiden kategoriat. Aineistonani olevan tekstin tunnusomaisen polarisaation tähden jaan kunkin näistä kategorioista edelleen puolueen kannan mukaiseen eli hyväksi esitettyyn ja kannan vastaiseen eli pahaksi esitettyyn. Analyysin tuloksena muodostuu käsitys periaateohjelman prototyyppisille toimijarooleille annetuista ominaisuuksista. Tärkeimpiä erottelevia ominaisuuksia ovat statiivisuus/dynaamisuus, agentiivisuus/sen puute sekä abstraktisuus/konkreettisuus. Statiivisuuden ja abstraktiuden totean koko tekstille leimallisiksi piirteiksi, erityisesti periaateohjelman pahalle. Tyypillinen paha on epäinhimillinen voima kuten ilmastonmuutos tai globalisaatio. Puolueen kannan puolella olevissa rooleissa ominaisuuksien hajonta on suurempaa. Puolueviitteiset toimijat sekä puoluetulkintainen me-pronomini ovat lähinnä kielen prototyyppistä agentiivista toimijaa. Ne ovat subjektiasemissa kommunikaatiotoiminnalle ja evidentiaalisuuden lähteenä asenteita ilmaistessa. Kommunikaatio itsessään hahmottuu keskeisenä toimintana ohjelmassa. Ihmisviitteisyys on lähinnä uhrin tai hyötyjän roolien piirre. Erityisen mielenkiintoinen seikka on kansalainen-sanaan ja sen lähimerkityksisiin vastineisiin kohdistuva ristiriita ohjelman metatekstin kansan aktiivista toimintaa ihannoivassa kielenkäytössä ja samanaikaisessa kansalaisten kielentämisessä tekstissä toiminnan kohteiksi. Ihmiset ovat periaateohjelmassa uhreja tai hyötyjiä, kun taas toimintavelvoitteet kohdennetaan tyypillisesti valtioille ja yhteiskunnan rakenteille. Poimin myös tarkasteltavaksi sellaisia kielen keinoja ja ilmiöitä kuin modaalisuus, kausaatiot, vaihtoehtoisten maailmojen käyttö ja nominalisaatio, sikäli kuin ne valottavat tarkasteltavana olevia toimijarooleja. Modaalisuus ja kausaatiot ovat tekstin merkityssuhteiden ilmiöitä. Kausaatio on ohjelmassa merkittävän vähäkäyttöinen, kun taas runsaslukuiset nesessiivirakenteet edustuvat ilman niille odotuksenmukaisia argumentteja. Modaalisuuden lähde ja kohde jätetään usein kielentämättä. Molemmat edellä mainitut seikat korostavat nykyhetkeä ja tulevaa toimintaa tekstin keskiössä. Toiminnan suorittajaa häivytetään tekstistä eri keinoin. Näin on erityisesti, kun puhutaan sävyltään negatiivisesta toiminnasta tai dynaamisesta toiminnasta. Dynaamista toimintaa kuvaavat verbit sijoittuvat tyypillisesti infinitiivisiin lausekkeihin, jotka on upotettu argumenttirakenteeseen tai sijoitettu ehtolauseella tai tulevaisuudesta puhuttaessa mahdollisiin maailmoihin. Näin toiminta ei reaalistu rakenteessa tässä ja nyt, vaan potentiaalisena toimintana tulevaisuudessa. Samalla syntyy myös potentiaalisen sankarin rooli, joka tässä ja nyt olevasta sankarista poiketen on ohjelmassa yleinen. Tätä roolia tarjotaan niin puolueen potentiaalisille tukijoille kuin pahoille voimillekin, kunhan ne määritellään uudelleen puolueen aatteille alisteisena sijoittamalla niiden yhteyteen puolueen diskurssin kiinteästi liittyviä attribuutteja kuten vihreä tai ekologinen.

Kouluvalinta vai koulun valinta? : Oppilaiden valikoituminen yläkouluihin Espoossa keväällä 2006

Changes in governance in the public sector made it possible to give the power to the level of service production. In Finland schools were diversified. They wanted to be as attractive as possible. In her dissertation (2006) Piia Seppänen studied parental choice and schools choice policies in Espoo, in Kuopio, in Lahti, inTurku and in some levels in Helsinki too. After her study was done there has been some changes in school choise policy in Espoo. The catchments areas changed radically; earlier every school did have its own catchment area. But now three or even five school has the same catchment area. On the base of the Seppänen’s dissertation I wondered who’s choice it really were? Is the choice maker customer or producer of the service? In my study I tried to understand those processes where pupils were selected for the 7th grade in lower secondary schools in the spring in 2006. To make the picture clear, I have to study the history of pupil selection and the changes of it in the 21st century. I also have to study the geography of the town which is quite special in comparison with the normal cities with one central area. This has its own effects on the pupil selection system as well as in the whole study. In my study I try to present what kind of process the pupil selection is in Espoo and how it was done actually in the spring of 2006. The empirical data of my study were statistical data, documents of different kind, conversations with principals, local authorities and politicians. I also interviewed one politician and observed a few information meetings about the pupil selection process. Based on this large variety of data I tried to draw a picture of the way of speaking (writing) about the ability of the choice. Furthermore, how this pupil selection is done in reality. The ability to apply to special instruction in f. e. music, graphic arts or maths and sciences or to language based instruction (bilingual and immersion teaching) depends on the district you live. Because there is one catchment area which has no special or language based instruction available. Also the poor public transport system might have some effects on the parental choice. According to my study, 20 % of the 7th grade pupils were selected with criteria of different kind to special classes. Because the ability to get special or language based instruction depends on your district, there is a big risk for a selection based on the pupils' socio-economic background.

Avioliiton teologia Englannin kirkossa ja Suomen evankelis-luterilaisessa kirkossa vuosina 1963-2006

The theology of marriage in the Church of England(CofE) and in the Evangelical Lutheran Church of Finland(ELCF)1963–2006 The method of the study is a systematic analysis of the sources. In the CofE marriage stems from creation, but it is also sacramental, grounded in the theology of love and redemption. Man and woman have a connection between them that is a mystical union in character because of the one between Christ and the Church; therefore every marriage is sacramental. The purposes of marriage have been expressed in a different order than earlier. A caring relationship and sexuality are set before childbirth as the causes of marriage. The remedial cause of marriage is also moved to the background and it cannot be found in the recent wedding formulas. A personal relationship and marriage as a school of faith and love have a central place in the theology of marriage. The theology of love unites the love of God and marriage. In the CofE the understanding of divorce and co-habiting has changed, too. Co-habiting can now be understood as a stage towards marriage. Divorce has been understood as a phenomenon that must be taken as a fact after an irretrievable breakdown of marriage. Thus the church must concentrate on pastoral care after divorce. Similarly, the ELCF also maintains that the order of creation is the origin of marriage as a lifelong institution. This is also an argument for the solemnization of marriage in the church. Faith and grace are not needed for real marriage because marriage is the culmination of reason and natural law. The society defines marriage and the church gives its blessing to the married couples if so requested. Luther’s view of marriage is different from this because he saw marriage as a school of love and faith, similar to CofE. He saw faith as essential to enable the fullfillment of natural law. Marriage in the ELCF is mostly a matter of natural ethics. An ideal form of life is sought through the Golden Rule. This interpretation of marriage means that it does not presuppose Christian education for children to follow. The doctrine of the two kingdoms is definitely essential as background. It has been impugned by scholars, however, as a permanent foundation of marriage. There is a difference between the marriage formulas and the other sources concerning the purposes of marriage in the ELCF. The formulas do not include sexuality, childbirth or children and their education as purposes of marriage. The formulas include less theological vocabulary than in the CofE. The liturgy indicates the doctrine in CofE. In the Lutheran churches there is not any need to express the doctrine in the wedding formulas. This has resulted in less theology of marriage in the formulas. The theology of Luther is no longer any ruling principle in the theology of marriage. The process of continuing change in society refines the terms for marriage more than the theological arguments do.

Siperiaa sanoiksi - uralilaisuutta teoiksi : Kai Donner poliittisena organisaattorina sekä tiedemiehenä antropologian näkökulmasta

The doctoral dissertation, entitled Siperiaa sanoiksi - uralilaisuutta teoiksi. Kai Donner poliittisena organisaattorina sekä tiedemiehenä antropologian näkökulmasta clarifies the early history of anthropological fieldwork and research in Siberia. The object of research is Kai Donner (1888-1935), fieldworker, explorer and researcher of Finno-Ugric languages, who made two expeditions to Siberia during 1911-1913 and 1914. Donner studied in Cambridge in 1909 under the guidance of James Frazer, A. C. Haddon and W. H. R. Rivers - and with Bronislaw Malinowski. After finishing his expeditions, Donner organized the enlistment of Finnish university students to receive military training in Germany. He was exiled and participated in the struggle for Finnish independence. After that, he organized military offensives in Russia and participated in domestic politics and policy in cooperation with C. G. E. Mannerheim. He also wrote four ethnographic descriptions on Siberia and worked with the Scandinavian Arctic areas researchers and Polar explorers. The results of this analysis can be sum up as follows: In the history of ethnographic research in Finland, it is possible to find two types of fieldwork tradition. The first tradition started from M. A. Castrén's explorations and research and the second one from August Ahlqvist's. Donner can be included in the first group with Castrén and Sakari Pälsi, unlike other contemporary philologists, or cultural researcher colleagues, which used the method of August Ahlqvist. Donner's holistic, lively and participant-observation based way of work is articulated in his writings two years before Malinowski published his thesis about modern fieldwork. Unfortunately, Donner didn't get the change to continue his researche because of the civil war in Finland, and due to the dogmatic position of E. N. Setälä. Donner's main work - the ethnohistorical Siberia - encloses his political and anthropological visions about a common and threatened Uralic nation under the pressure of Russian. The important items of his expeditions can be found in the area of cultural ecology, nutritional anthropology and fieldwork methods. It is also possible to prove that in his short stories from Siberia, there can be found some psychological factors that correlate his early life history.