含微裂纹的95%Al_2O_3陶瓷的力学性能

本文采用三种不同加载方式(单轴拉伸,三点弯曲以及圆盘压缩)研究含微裂纹Al_2O_3的陶瓷的弹性性能及其抗拉强度.微裂纹是通过对材料瞬时突变加热和冷却(简称热冲击)形成的.试验结果表明:1)三点弯曲试验得到的力学性能参数较其它两种加载方式所得到的结果要稳定和集中.单轴拉伸试验结果分散性最大.2)热冲击温度越高,材料的等效弹性模量?和等效泊松比?以及各种加载方式下试件的抗拉强度??都有不同程度的下降.电镜观察证实了力学性能参数下降主要与材料内部微裂纹密度增加有关.3)Budiansky-O'Connell方法被用来估计不同热冲击处理后的圆盘试件在断裂过程中的微裂纹密度变化,结果表明实际材料的微裂纹密度较理想材料的微裂纹密度都有一定的偏差.

Influences of Al doping concentration on structural, electrical and optical properties of Zn0.95Ni0.05O powders

Nanocrystalline Zn0.95 - xNi0.05AlxO (x = 0.01, 0.02, 0.05 and 0.10) diluted magnetic semiconductors have been synthesized by an auto-combustion method. X-ray diffraction measurements indicate that all Al-doped Zn0.95Ni0.05O samples have the pure wurtzite structure. Transmission electron microscope analyses show that the as-synthesized powders are of the size 40 - 45 nm. High-resolution transmission electron microscope, energy dispersive spectrometer and X-ray photoemission spectroscope analyses indicate that Ni2+ and Al3+ uniformly substitute Zn2+ in the wurtzite structure without forming any secondary phases. The Al doping concentration dependences of cell parameters (a and c), resistance and the ratio of green emission to UV emission have the similar trends. (c) 2007 Elsevier B.V. All rights reserved.

低C/N对湿地中硝化反硝化作用的影响

通过监测几种形态氮的变化,研究了人工湿地小试系统在不同浓度和低C/N条件下的除氮效果和反硝化途径.结果发现,湿地对浓度为5.5～50.5mg/L的NH4+-N有很好的去除效果,去除率可达95%以上.在此浓度范围内,NH4+-N的进、出水浓度呈线性关系,R2值为0.9971.当进水含氮量低于16.4mg/L时,湿地的除氮效率随进水浓度的增加而明显增加.进水含氮量为16.4～51.4mg/L时,湿地的除氮效率为85%以上,且浓度对去除率无显著影响.当C/N<1时,湿地系统对总氮的去除率为86.3%,而碳源充足

光通信用1.55微米InGaAsP/InP DH激光器中的0.95微米发光和俄歇复合

Submitted by zhangdi (zhangdi@red.semi.ac.cn) on 2009-04-13T11:45:31Z

1.55μm InGaAsP/InP DH激光器中的0.95μm发光带与Auger复合

于2010-11-23批量导入

High-spin level structure in Mo-94,Mo-95

High-spin level structures of 94,95Mo have been reinvestigated via the 16O(82Se, xnγ)94,95Mo(x = 4, 3) reactions at E(82Se) = 460 MeV. The previously reported level schemes of these two nuclei have been largely modified up to ∼11 MeV in excitation energy due to identifications of some important linking transitions. Shellmodel calculations have been made in the model space of π(p1/2, g9/2, d5/2)4 and ν(d5/2, s1/2, d3/2, g7/2, h11/2)2(3) and compared with the modified level schemes. The structures of the newly assigned high-spin states in 94,95Mo have been discussed.

Structural stability of C-60 films under the bombardment of 1.95 GeV Kr ions

The structural stability of C-60 films under the bombardment of 1.95 GeV Kr ions is investigated. The irradiated C-60 films were analyzed by Fourier Transform Infrared (FTIR) spectroscopy and Raman scattering technique. The analytical results indicate that the irradiation induced a decrease of icosahedral symmetry of C-60 molecule and damage of C-60 films; different vibration modes of C-60 molecule have different irradiation sensitivities; the mean efficient damage radius obtained from experimental data is about 1.47 nm, which is in good agreement with thermal spike model prediction.

An unusual organic-inorganic chain-like hybrid complex [(CuCl)(2)(o-phen)](infinity) (o-phen=o-phenanthroline)

A novel organic-inorganic hybrid complex [(CuCl)(2) (o-phen)](infinity) 1 (o-phen = o-phenanthroline) has been hydrothermally synthesized and structurally characterized by elemental analyses, XPS spectrum, TG analysis, and single-crystal X-ray diffraction. Compound I crystallizes in the monoclinic system, space group P2(1)/n, a = 3.7285(7) Angstrom, b = 19.603(4) Angstrom, c = 16.757(3) Angstrom, beta = 95.83(3)degrees, V = 1218.4(4) Angstrom(3), Z = 4, lambda(MoKalpha) = 0.71073 Angstrom (R(F) = 0.0643 for 2559 reflections). Data were collected on an R-axis RAPID diffractometer at 293 K in the range of 1.60 < θ < 27.48degrees. The title compound exhibits a one-dimensional chain-like scaffolding constructed by the unusual [Cu3Cl3] hexagon motifs by, sharing opposite edges. Only Cu(1) sites of the [Cu3Cl3] hexagon are coordinated with N donors of o-phen groups. Furthermore, the three-dimensional supermolecular architecture is formed by C-H...Cl hydrogen bonds between o-phen groups and CuCl chains.

Y_(1.95-x)Gd_xSiO_5:Eu_(0.05)的真空紫外光谱

利用高温固相法合成了 Ｙ１．９５－ｘＧｄｘＳｉＯ５：Ｅｕ０．０５（ｘ＝０．６ｍｏｌ％）荧光体。结构测定表明所合成的荧光体为单斜晶系的Ｘ２型Ｙ２ＳｉＯ５相，空间群为Ｂ２／ｂ。真空紫外光谱表明：随着Ｇｄ３＋含量的增加，在１９２ｕｍ附近，出现了Ｇｄ＋的激发峰，且此峰的强度随着Ｇｄ３＋含量的增加而增大；同时位于１５０～１８５ｎｍ之间的基质吸收带的强度也增大；而位于２００～３００ｎｍ之间的Ｅｕ的电行迁移带的强度却随着Ｇｄ３＋含量的增加而降低。

La_(0.95)Pb_(0.05)F_(2.95)气敏性质的研究

本文研究了“Bi(BiF_3~-)/La_(0.95)Pb_(0.05)F_(2.95)/Pt”元件的气敏性质。元件的电动势与氧分压对数呈线性关系,温度升高,响应时间变短。20℃,在所测的范围内,电动势与空气中氢分压呈对数关系:E=E_0-961gPH_2(mV);敏感电极反应归结为局域电流或称作混合电势机理。元件对空气中1000Pa 氢气的90%响应时间仅用15S。元件对 CO 也有一定的敏感性能,但对甲烷、丁烷、乙炔等不具敏感性能。

Ce_(0.95)Ca_(0.05)F_(3-x)固体电解质氧传感器的研究

本文研究了Ce_(0.95)Ca_(0.05)F_(3-x)固体电解质及其氧传感器的制备和性质。在150℃时,Po_2在10~(-2)～10~(-1)MPa范围内传感器件的电位变化正比于Po_2的对数值。同时研究了不同参比电极和敏感电极对传感性能的影响。以Bi+BiF_3为参比电极时,EMF值稳定较快;当Pd作为敏感电极时,传感元件的响应较快;以RuO_2作敏感电极时,传感器件较灵敏。文章还讨论了敏感机理。

Cys-92, Cys-95, and the C-terminal 12 residues of the Vibrio harveyi ferric uptake regulator (Fur) are functionally inessential

Ferric uptake regulator (Fur) is a global regulator involved in multiple aspects of bacterial life. The gene encoding the Vibrio harveyi Fur (Fur(vh)) was cloned from a pathogenic V. harveyi strain isolated from diseased fish. Furvh shares 77% overall sequence identity with the Escherichia coli Fur (Fur(Ec)) and could complement a mutant of Fur(Ec). Like Fur(Ec), Fur(Vh), possesses two cysteine residues at positions 92 and 95, yet unlike Fur(Ec), in which these cysteine residues constitute part of the metal ion coordination site and hence are vital to the repressor activity, C92 and C95 of Fur(Vh) proved to be functionally inessential. Further study identified a Vibrio Fur signature sequence, which is preserved in all the ten Vibrio Fur proteins that have been discovered to date but in none of the non-vibrio Fur proteins. Site-directed and random mutation analyses of the signature residues, the cysteine residues, and seven highly charged amino acid residues indicated that D9, H32, C137, and K138 of Fur(vh) are functionally important but D9, C137, and K138 can be replaced by more than one functional substitutes. Systematic deletion analysis demonstrated that the C-terminal 12 residues of Fur(Vh) are functionally inessential. These results (i) indicated that the activation mechanism, or certain aspects of which, of Fur(Vh) is possibly different from that of Fur(Ec); and (ii) suggested that it is not very likely that the C-terminal 12 residues play any significant role in the activation or stability of Fur(Vh); and (iii) provided insights into the potential function of the local structure involving C137 and K138.

95-2重穗型小麦品系生长动态分析

对重穗型小麦品系95－2生长动态分析结果表明，95－2较一般概念上的栽培品系株型粗壮、高大．在整个生育期保持较高的有效光合面积，形成较高的生物学产量，根系发达，形成大穗大粒，体现了源大、库大的特点，茎拜系统也具良好的输导性能。在下一步超高产、稳产品种培育中，植株叶型及其合理配置是一个着重要考虑和解决的问题。