Miscibility, crystallization and mechanical properties of PPC/PBS blends

In this paper, melt blends of poly(propylene carbonate) (PPC) with poly(butylene succinate) (PBS) were characterized by dynamic mechanical analysis (DMA), differential scanning calorimetry (DSC), tensile testing, wide-angle X-ray diffraction (WAXD), polarized optical microscopy and thermogravimetric analysis (TGA). The results indicated that the glass transition temperature of PPC in the 90/10 PPC/PBS blend was decreased by about 11 K comparing with that of pure PPC. The presence of 10% PBS was partially miscible with PPC. The 90/10 PPC/PBS blend had better impact and tensile strength than those of the other PPC/PBS blends. The glass transition temperature of PPC in the 80/20, 70/30, and 60/40 PPC/PBS blends was improved by about 4.9 K, 4.2 K, and 13 K comparing with that of pure PPC, respectively; which indicated the immiscibility between PPC and PBS. The DSC results indicated that the crystallization of PBS became more difficult when the PPC content increased. The matrix of PPC hindered the crystallization process of PBS. While the content of PBS was above 20%, significant crystallization-induced phase separation was observed by polarized optical microscopy. It was found from the WAXD analysis that the crystal structure of PBS did not change, and the degree of crystallinity increased with increasing PBS content in the PPC/PBS blends.

Crystallization and melting behaviors of PPC-BS/PVA blends

The isothermal crystallization and melting behaviors of poly(propylene carbonate) end-capped with benzenesulfonyl/poly (vinyl alcohol) (PPC-BS/PVA) blends over rich PVA composition range were first investigated by differential scanning calorimetry (DSC). PPS-BS/PVA interaction parameter, chi(12), calculated from equilibrium melting temperature depression was -0.44, revealing miscibility of PPC-BS with PVA in the melt and favorable interactions. The temperature dependence of crystallization rate constant at initial crystallization stage was analyzed using the modified Lauritzen-Hoffman expression. The chain width, a(0), the thickness of a monomolecular layer, b(0), the fold and lateral surface-free energies, sigma(e) and sigma, and the work of chain folding, q, for neat PVA were first reckoned to be 4.50 Angstrom, 4.78 Angstrom, 76.0 erg.cm(-2), and 4.70 kcal.mol(-1), respectively. The values of sigma(e) and q for PVA in PPC-BS/PVA blends exhibited a maximum in the neighborhood of 10/90 PPC-BS/PV, respectively.

Taxa de câmbio real e co-integração: testes sobre PPC em sua versão absoluta do Brasil de 1980 a 2007

O objetivo central desta dissertação consiste em avaliar as possibilidades para a validação da hipótese de paridade de poder de compra em sua versão absoluta no Brasil, no período que se estende desde 1980 a 2007. Este período se caracterizou por diversas alterações de política econômica bem como das condições macroeconômicas da economia brasileira, que acabam por gerar séries mais suscetíveis a quebras estruturais. Para a verificação da existência da hipótese da paridade de poder de compra, foram aplicados testes de raiz unitária e análises de co-integração para séries distintas de taxa de câmbio real. Os resultados obtidos mostram que tanto os testes de raiz unitária quanto a análise de co-integração não suportam a validade da hipótese da Paridade de Poder de Compra em sua versão absoluta.

Localizando o pretérito perfecto compuesto na linha do tempo: o estágio da gramaticalização do PPC nas variedades diatópicas argentinas

The aim of this study was to observe Argentine diatopic varieties and to identify in which stage of the evolution of the pretérito perfecto compuesto (PPC) the use of compound tense fits into these variations. Therefore, we assume as assumptions (I) some authors` description of the evolutionary stages of this verb tense in Spanish, (II) the description of the values assigned to the perfecto compuesto in the dialect regions of Argentina and (III) the contributions of studies on grammaticalization for the verb tenses analysis.

TESTANDO A TEORIA DA PARIDADE DE PODER DE COMPRA (PPC) NO PERÍODO DE 1995 A 2010

O objetivo deste trabalho é testar a teoria da Paridade de Poder de Compra em sua versão absoluta e relativa para o Brasil no período de 1995 a 2010, utilizando procedimentos da econometria visando estabelecer através de testes de hipóteses a validação ou rejeição da teoria da Paridade do Poder de Compra. Para a verificação serão utilizados os testes de Dickey-Fuller (DF), Dickey-Fuller Ampliado (ADF) e testes de Cointegração de Engle e Granger e Joahansen. Adotamos para o estudo os países EUA e Brasil, tendo em vista o fluxo de comércio entre estes países e sua importância na economia mundial. Através dos índices de preço IPA e PPI analisarse- á a validação da teoria da Paridade de Poder de Compra em sua versão relativa e absoluta, chegando-se a conclusão de aceitação de sua versão relativa e rejeição de sua versão absoluta.

La derecha creativa en el Perú: PPC Y ADEX

Hoy en día, se da un consenso relativamente general en torno a la claridad, contundencia y coherencia del Plan de Gobierno del Partido Popular Cristiano. Prácticamente, todas las tiendas del espectro político coinciden en esa apreciación, aunque puedan no coincidir con una sola de sus propuestas generales o específicas. El Programa del PPC, así como las Propuestas de ADEX, marcarían así el inicio de una tan ansiada nueva era en el Perú, dejando de lado la improvisación, las ideas vagas, la incoherencia y las frases bonitas. Se terminaría con esto la centuria poética de la política para entrar en una nueva, apoyada cada vez más en la seriedad y creatividad de los técnicos, cuya primera plana estaría conformada necesariamente por economistas. Gran parte de la campaña del PPC giró en torno a esta temática y del aspecto económico, con lo que se pretendió contraponer la concreción, el tecnicismo y la factibilidad de los planteamientos del PPC con la vaguedad, la demagogia y el irrealismo, tanto de Acción Popular como del Partido Aprista Peruano. Este artículo se ocupa únicamente de un aspecto, muy puntual, de toda esta vasta problemática, a saber: ¿Cuál es el origen, la motivación, las fuentes y la justificación de este súbito resurgimiento de un pensamiento coherente de la Derecha en el Perú? ¿Cómo explicar su condensación concentrada en torno al PPC y ADEX?

Implementation of a driving diary intervention to reduce aberrant driving behaviours

Crash data involving taxis indicates that such drivers are over represented in crashes and are one to two times more likely to be involved in a fatality crash. This study reports on the pre intervention survey to provide a baseline measure of the self-reported attitudes and corresponding driving behaviours of a sample of taxi drivers. Results indicate that some taxi drivers willingly admit to engaging in unsafe driving practices. In addition, preliminary results of a post intervention survey revealed that taxi drivers’ safety perceptions, attitude and behaviours improved after completing a Driving Diary intervention.

Identifying influences of driving behaviour : could the Australian work driving setting be unique?

Work-related driving safety is an emerging concern for Australian and overseas organisations. An in depth investigation was undertaken into a group of fleet drivers’ attitudes regarding what personal and environment factors have the greatest impact upon driving behaviours. A number of new and unique factors not previously identified were found including: vehicle features, vehicle ownership, road conditions, weather, etc. The major findings of the study are discussed in regards to practical solutions to improve fleet safety.

A high voltage power converter with a frequency and voltage controller

A high voltage power converter is presented in this paper and is based on a Capacitor-Diode Voltage Multiplier (CDVM) supplied through an inverter. This power converter has the capabilities of generating variable high DC voltage with improved transient response. The simulation results which are presented in this paper verify that due to its fast transient response, this converter can be used as a high DC voltage source in many applications.

Using a current source to improve efficiency of a plasma system

This paper presents the possibility of utilizing a current source topology instead of a voltage source as an efficient, flexible and reliable power supply for plasma applications. A buck-boost converter with a current controller has been used to transfer energy from an inductor to a plasma system. A control strategy has also been designed to satisfy all the desired purposes. The main concept behind this topology is to provide high dv/dt regardless of the switching speed of a power switch and to control the current level to properly transfer adequate energy to various plasma applications.

Technological innovation and operational effectiveness : their role in achieving performance improvements

The purpose of this article is to examine the role of the alignment between technological innovation effectiveness and operational effectiveness after the implementation of enterprise information systems, and the impact of this alignment on the improvement in operational performance. Confirmatory factor analysis was used to examine structural relationships between the set of observed variables and the set of continuous latent variables. The findings from this research suggest that the dimensions stemming from technological innovation effectiveness such as system quality, information quality, service quality, user satisfaction and the performance objectives stemming from operational effectiveness such as cost, quality, reliability, flexibility and speed are important and significantly well-correlated factors. These factors promote the alignment between technological innovation effectiveness and operational effectiveness and should be the focus for managers in achieving effective implementation of technological innovations. In addition, there is a significant and direct influence of this alignment on the improvement of operational performance. The principal limitation of this study is that the findings are based on investigation of small sample size.