987 resultados para Tappan, Lewis, 1788-1873.


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The first examples of ionic liquids based on borenium cations, [BCl2L](+), are reported. These compounds form highly Lewis acidic liquids under solvent-free conditions. Their acidity was quantified by determining the Gutmann acceptor number (AN). Extremely high ANs were recorded (up to AN=182, delta(31P)=120 ppm), demonstrating that these borenium ionic liquids are the strongest Lewis superacids reported to date, with the acidity enhanced by the ionic liquid environment.

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Aliphatic ketones and aromatic carbonyl compounds on reaction with methylselenol :and a Lewis acid, are shown to undergo acetalisation and/or reduction to methyl selenide, the unexpected reduction reaction being predominant in most cases.

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Tese apresentada para cumprimento dos requisitos necessários à obtenção do grau de Doutor em História, especialidade em História Contemporânea

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1 kartta : käsinpiirros, vär. ; 90,5 x 91 cm, lehti 94 x 94 cm. Kankaalle liimattu.

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Variante(s) de titre : Bulletin de la Société de Saint-Jean