Reduction vs acetalisation of some carbonyl-compounds by means of methylselenol and lewis-acids


Autoria(s): Cravador, A.; Krief, A.; Hevesi, L.
Data(s)

15/06/2015

15/06/2015

1980

Identificador

0022-4936

AUT: ACR00659;

http://hdl.handle.net/10400.1/6145

https://dx.doi.org/10.1039/c39800000451

Idioma(s)

eng

Publicador

Royal Society Chemistry

Relação

P-008-R6Q

Direitos

restrictedAccess

Tipo

article

Resumo

Aliphatic ketones and aromatic carbonyl compounds on reaction with methylselenol :and a Lewis acid, are shown to undergo acetalisation and/or reduction to methyl selenide, the unexpected reduction reaction being predominant in most cases.