Neurophysiologie du langage : apports de la neuro-imagerie et état des connaissances

International audience

Development of procedures for the triazole fungicides determination in fruits and liquid samples using microextraction techniques and chromatographic separation

Agricultural crops can be damaged by funguses, insects, worms and other organisms that cause diseases and decrease the yield of production. The effect of these damaging agents can be reduced using pesticides. Among them, triazole compounds are effective substances against fungus; for example, Oidium. Nevertheless, it has been detected that the residues of these fungicides in foods as well as in derivate products can affect the health of the consumers. Therefore, the European Union has established several regulations fixing the maximum residue of pesticide levels in a wide range of foods trying to assure the consumer safety. Hence, it is very important to develop adequate methods to determine these pesticide compounds. In most cases, gas or liquid chromatographic (GC, LC) separations are used in the analysis of the samples. But firstly, it is necessary to use proper sample treatments in order to preconcentrate and isolate the target analytes. To reach this aim, microextraction techniques are very effective tools; because allow to do both preconcentration and extraction of the analytes in one simple step that considerably reduces the source of errors. With these objectives, two remarkable techniques have been widely used during the last years: solid phase microextraction (SPME) and liquid phase microextraction (LPME) with its different options. Both techniques that avoid the use or reduce the amount of toxic solvents are convenient coupled to chromatographic equipments providing good quantitative results in a wide number of matrices and compounds. In this work simple and reliable methods have been developed using SPME and ultrasound assisted emulsification microextraction (USAEME) coupled to GC or LC for triazole fungicides determination. The proposed methods allow confidently determine triazole concentrations of μg L‐1 order in different fruit samples. Chemometric tools have been used to accomplish successful determinations. Firstly, in the selection and optimization of the variables involved in the microextraction processes; and secondly, to overcome the problems related to the overlapping peaks. Different fractional factorial designs have been used for the screening of the experimental variables; and central composite designs have been carried out to get the best experimental conditions. Trying to solve the overlapping peak problems multivariate calibration methods have been used. Parallel Factor Analysis 2 (PARAFAC2), Multivariate Curve Resolution (MCR) and Parallel Factor Analysis with Linear Dependencies (PARALIND) have been proposed, the adequate algorithms have been used according to data characteristics, and the results have been compared. Because its occurrence in Basque Country and its relevance in the production of cider and txakoli regional wines the grape and apple samples were selected. These crops are often treated with triazole compounds trying to solve the problems caused by the funguses. The peel and pulp from grape and apple, their juices and some commercial products such as musts, juice and cider have been analysed showing the adequacy of the developed methods for the triazole determination in this kind of fruit samples.

On Experiencers and Minimality

This dissertation is concerned with experiencer arguments, and what they tell us about the grammar. There are two main types of experiencers I discuss: experiencers of psychological verbs and experiencers of raising constructions. I question the notion of ‘experiencers’ itself; and explore some possible accounts for the ‘psych-effects’. I argue that the ‘experiencer theta role’ is conceptually unnecessary and unsustained by syntactic evidence. ‘Experiencers’ can be reduced to different types of arguments. Taking Brazilian Portuguese as my main case study, I claim that languages may grammaticalize psychological predicates and their arguments in different ways. These verb classes exist in languages independently, and the psych-verbs behavior can be explained by the argument structure of the verbal class they belong to. I further discuss experiencers in raising structures, and the defective intervention effects triggered by different types of experiencers (e.g., DPs, PPs, clitics, traces) in a variety of languages. I show that defective intervention is mostly predictable across languages, and there’s not much variation regarding its effects. Moreover, I argue that defective intervention can be captured by a notion of minimality that requires interveners to be syntactic objects and not syntactic occurrences (a chain, and not a copy/trace). The main observation is that once a chain is no longer in the c-command domain of a probe, defective intervention is obviated, i.e., it doesn’t apply. I propose a revised version of the Minimal Link Condition (1995), in which only syntactic objects may intervene in syntactic relations, and not copies. This view of minimality can explain the core cases of defective intervention crosslinguistically.

Koherentziazko diskurtso erlazioen detekzio automatikoa patroien bidez, XMLko erlazio-egiturak oinarri hartuta

[EU]Hizkuntzaren prozesamenduan testu koherenteetan kausa taldeko erlazioak (KAUSA, ONDORIOA eta HELBURUA) automatikoki hautematea eta bereiztea erabilgarria da galdera-erantzun automatikoko sistemak eraikitzerako orduan. Horretarako Egitura Erretorikoaren Teoria (Rhetorical Structure Theory, aurrerantzean RST) eta bere erlazioak erabiliko ditugu, corpus bezala RST Treebank -a (Iruskieta et al., 2013) hartuta, zientziako laburpen-testuz osatutako corpusa, hain zuzen ere. Corpus hori XML formatuan deskargatu eta hortik XPATH tresnaren bidez informazio garrantzitsuena eskuratzen dugu. Lan honek 3 helburu nagusi ditu: lehendabizi, kausa taldeko erlazioak elkarren artean bereiztea, bigarrenez, kausa taldeko erlazio hauek beste erlazio guztiekin bereiztea, eta azkenik, EBALUAZIOA eta INTERPRETAZIOA erlazioak bereiztea sentimendu analisian aplikatu ahal izateko. Ataza horiek egiteko, RhetDB tresnarekin eskuratu diren patroi ensaguratsuenak erabili eta bi aplikazio garatu ditugu. Alde batetik, bilatu nahi ditugun patroiak adierazi eta erlazio-egitura duen edonolako testuetan bilaketak egiten dituen bilatzailea, eta bestetik, patroi esanguratsuenak emanda erlazioak etiketatzen dituen etiketatzailea. Bi aplikazio hauek gainera, ahalik eta modu parametrizagarrienean erabiltzeko garatu ditugu, kodea aldatu gabe edonork erabili ahal izateko antzeko atazak egiteko. Etiketatzaileak ebaluatu ondoren, identifikatzeko erlaziorik errazena HELBURUA erlazioa dela ikusi dugu eta KAUSA eta ONDORIOA bereizteko arazo gehiago dauzkagula ere ondorioztatu dugu. Modu berean, EBALUAZIOA eta INTERPRETAZIOA ere elkarren artean bereiz dezakegula ikusi dugu.

Testu arteko koherentziazko erlazio-egitura: lehen urratsak euskaraz

[EU]Testu bat koherente egiten duten arrazoiak ulertzea oso baliagarria da testuaren beraren ulermenerako, koherentzia eta koherentzia-erlazioak testu bat edo gehiago koherente diren ondorioztatzen laguntzen baitigu. Lan honetan gai bera duten testu ezberdinen arteko koherentziazko 3 Cross Document Structure Theory edo CST (Radev, 2000) erlazio aztertu eta sailkatu dira. Hori egin ahal izateko, euskaraz idatziriko gai berari buruzko testuak segmentatzeko eta beraien arteko erlazioak etiketatzeko gidalerroak proposatzen dira. 10 testuz osaturiko corpusa etiketatu da; horietako 3 cluster bi etiketatzailek aztertu dute. Etiketatzaileen arteko adostasunaren berri ematen dugu. Koherentzia-erlazioak garatzea oso garrantzitsua da Hizkuntzaren Prozesamenduko hainbat sistementzat, hala nola, informazioa erauzteko sistementzat, itzulpen automatikoarentzat, galde-erantzun sistementzat eta laburpen automatikoarentzat. Etorkizunean CSTko erlazio guztiak corpus esanguratsuan aztertuko balira, testuen arteko koherentzia- erlazioak euskarazko testuen prozesaketa automatikoa bideratzeko lehenengo pausua litzateke hemen egindakoa.

Creación de neologismos en euskera: Análisis descriptivo de la terminología de la odontología en lengua vasca y propuestas para la formación de términos en los ámbitos de especialidad.

450 p.

Barrenetik mintzora: euskararen erabilera sustatzeko proposamena haur hezkuntzan

100 p. -- E-mail del autor: unaiballesteros@gmail.com

Análise de correlação canónica : extensões e aplicações

Neste trabalho apresentamos a teoria da análise de correlação canónica, uma técnica de análise estatística multivariada para o estudo da relação, simultânea, entre dois, três ou mais grupos de variáveis. Descrevemos a natureza da correlação canónica com três ou mais variáveis, com modelos matemáticos, fazendo uma síntese dos métodos de generalização de correlação canónica nomeadamente o método Ssqcor, método Sumcor, método Ecart, método Maxvar, método Minvar, e o método de Carroll. Apresentamos uma aplicação utilizando dados provenientes do cálculo do Índice de Preços no Consumidor IPC, produzido pelo INE - STP (Instituto Nacional de Estatística de São Tomé e Príncipe), referente ao período 2010 a 2014. Estamos interessados em conhecer as correlações canónicas entre grupos de variáveis relacionadas com o cabaz de produtos pré-estabelecido para o cálculo do índice de preços no consumidor, concretamente os produtos alimentares (PA), produtos para bebidas (PB) e produtos não alimentares (PNA), constituindo assim os três grandes grupos de variáveis da nossa pesquisa.

La violencia contra la pareja o expareja mujer: un estudio de la variable de la nacionalidad en la base de datos de la Guardia Municipal de Donostia/San Sebastian

[ES]Este Trabajo de Fin de Grado (TFG) está relacionado con las prácticas efectuadas en la Guardia Municipal de San Sebastián (País Vasco) y pretende analizar las órdenes de protección concedidas a víctimas de violencia de género inmigrantes y nacionales para comprobar si existe alguna diferencia en cuanto a su aplicación. Asimismo, se pretende analizar el procedimiento efectuado por este cuerpo policial y servicios sociales en estos casos, así como el perfil de la víctima y el agresor. Por otra parte, se procura analizar aspectos controvertidos de la Ley Orgánica 1/2004 de Medidas de Protección Integral de la Violencia de Género. Para ello, se utilizara una metodología mixta. Por una parte de corte cualitativo realizando cuatro entrevistas (a dos víctimas, una agente de policía y una trabajadora social) para ahondar más respecto a este tema. En segundo lugar, desde una perspectiva cuantitativa se explorará la base de datos de la Guardia Municipal en materia de violencia de género para realizar un análisis estadístico. Finalmente, se abordaran las conclusiones a las que se ha llegado con este trabajo y se propondrán mejoras de cara a futuras investigaciones y a la operatividad de la Guardia Municipal.

Development of new analytical procedures of isotope geochemistry by mass spectrometry. Application to the study of high-pressure metamorphic rocks from the Iberian Massif

319 p.

Synthesis of waterborne polyurethane-urea dispersions with chain extension step in homogeneous and heterogeneous media

Hypothesis: The possibility of tailoring the final properties of environmentally friendly waterborne polyurethane and polyurethane-urea dispersions and the films they produce makes them attractive for a wide range of applications. Both the reagents content and the synthesis route contribute to the observed final properties. Experiments: A series of polyurethane-urea and polyurethane aqueous dispersions were synthesized using 1,2-ethanediamine and/or 1,4-butanediol as chain extenders. The diamine content was varied from 0 to 4.5 wt%. Its addition was carried out either by the classical heterogeneous reaction medium (after phase inversion step), or else by the alternative homogeneous medium (prior to dispersion formation). Dispersions as well as films prepared from dispersions have been later extensively characterized. Findings: 1,2-Ethanediamine addition in heterogeneous medium leads to dispersions with high particle sizes and broad distributions whereas in homogeneous medium, lower particle sizes and narrow distributions were observed, thus leading to higher uniformity and cohesiveness among particles during film formation. Thereby, stress transfer is favored adding the diamine in a homogeneous medium; and thus the obtained films presented quite higher stress and modulus values. Furthermore, the higher uniformity of films tends to hinder water molecules transport through the film, resulting, in general, in a lower water absorption capacity.

Os limites da gentrificação na vila planalto

Dissertação (mestrado)—Universidade de Brasília, Faculdade de Arquitetura e Urbanismo, Programa de Pós-Graduação em Arquitetura e Urbanismo, 2015.

A forma do privilégio: renda, acessibilidade e densidade em Natal-RN

The aim of this work is to understand the morphological expression of ground occupation by the higher income population, by focusing on population distribution in accordance with income layers and demographical density, as well as topological accessibility (HILLIER and HANSON, 1984) resulting from the urban grid structure. It endeavors to identify a functional organizing principle regarding the intra-urban space of Natal capital city of the state of Rio Grande do Norte, the research focus. In order to achieve this, census data as well as syntactic data were utilized for mapping and spatial analysis of income patterns, topological accessibility and demographical density using Geographical Information System GIS. The organizing principle was named as the Form of Privilege, a pattern that concentrates or tends to concentrate wealth, topological accessibility and low demographical density. Attempting to assess its extent, beyond Natal, this principle was applied to other Brazilian northeastern capitals such as: Fortaleza, CE; Teresina, PI; Aracaju, SE; Recife, PE; and João Pessoa, PB. Findings point out that although the urban structures of these cities are not immune to the Form of Privilege, Natal is emblematic of this phenomenon, a fact that demonstrates the perverse character of its spatial process, which historically creates privileged areas within the city, by means of the appropriation of accessibility as well as of the many urban benesses that are related to it by higher income groups at the expense of the major part of the population, which though being the people mostly in need of the benefits originating from the urban form are excluded from them

Euskarazko egitura sintaktiko konplexuen analisirako eta testuen sinplifikazio automatikorako proposamena

301 p.(eus); 217 (eng)

Hábitos de compra de las hortalizas en el País Vasco

Título del monográfico: Usos y costumbres en la alimentación. Recoge los contenidos presentados a las Jornadas de Antropología de la Alimentación, Nutrición y Salud (3. 2006. Bilbao). Coord. por Esther Rebato Ochoa