Biogenic opal and diatoms in surface sediments of the South Western Atlantic

Based on 66 surface sediment samples collected in the SW Atlantic Ocean between 27 and 50°S, this study presents an overview of the spatial distribution of biogenic opal and diatom concentrations, and diatom assemblages. Biogenic opal has highest values in the deepest, pelagic stations and decreases toward the slope. Diatoms closely follow the spatial trend of opal. Diatom assemblages reflect the present-day dominant hydrographical features. Antarctic diatoms are the main contributors to the preserved diatom community in core top sediments, with coastal planktonic and tropical/subtropical diatoms as secondary components. Dominance of Antarctic diatoms between 35 and 50°S in the pelagic realm mirrors the northward displacement of Antarctic-source water masses, characterized by high nutrient content and low salinity. Northward of ca. 35°S, the highest contribution of tropical/subtropical, pelagic diatoms, typical for nutrient-poor and high salinity waters, matches the main southward path of the Brazil Current. Mixing of Antarctic and tropical waters down up to 45°S is clearly illustrated by the diatom assemblage. Concentrations of biogenic opal and diatoms rather reflect the path of predominant water masses, but are less correlated with surface water productivity in the SW Atlantic.

Abundance of organic-walled dinoflagellate cysts of sediment core GeoB3603-2

Here, we reconstruct the varying influence of the Agulhas Current (AgC), the South Atlantic Current and the Antarctic Circumpolar Current on the Agulhas Retroflection (AgR) in the eastern South Atlantic Ocean for the last 160,000 years on the basis of the dinoflagellate cysts, pollen and spores present in a sediment core (GeoB 3603-2) from the southeastern Cape Basin offshore South Africa, where the Agulhas Current enters the Atlantic Ocean. Our analyses reveal strong orbital forcing on the heat exchange between the Indian Ocean and the South Atlantic Ocean during the Late Quaternary. Maxima in local productivity appear to be primarily related to a strengthening of the ocean circulation as a result of the high seasonal contrast during precession maxima. During precession minima, seasonal contrast was low and stratified, oligo- to mesotrophic conditions prevailed, notably when these minima coincided with the glacial terminations. The clear presence of periodicities on a sub-Milankovitch scale as well as modulations of the primary frequencies demonstrate that the Agulhas Retroflection furthermore is modulated substantially by complex interactions between the subtropical, 'precession-driven', climate and ocean circulation systems, and the southern, 'obliquity-driven', high latitudes.

The Appendicularia and Chaetognatha from the Great Meteor Bank, Northeast Atlantic

At a longtime station near the "Grosse Meteor Bank" in the North Atlantic 41 subsequent hauls were made in April 1967 with the Helgoland larva net with changing bucket device. In addition 9 hauls were made during July 1967. The catches from the depth ranges of 900-700 m, 700-500 m, 500-300 m, 300-200 m, 200-100 m, and 100-0 m were collected in separate buckets during each catch series. Contamination, though possible on principle, does not seem to be of much consequence in appendicularia. After some comments on certain species caught it is shown that at this station in the open ocean the density of appendicularia not only varies with the season, but that clouds of plankton may pass by it within a few hours, in which the density may vary at a ratio of ten or more to one. In the composition of species as many as four species may in turn be the most abundant. For one species the composition as to size and stage of maturity may change in the same way. Regarding the depth distribution there are no species restricted to deeper layers. Below 100 m the number falls to about 1 % of the uppermost layer. Oikopkura longicauda, O. cophocerca, O.parva and Althoffia tumida as well as Fritillaria species are found between 900 and 100 m in comparatively higher numbers than Stegosoma magnum, Oikopleura albicans and O. intermedia. The Chaetognaths were collected in the depth of 900-0 m in vertical hauls with the Helgoland larva net with changing bucket device; buckets had been changed in the depth of 700, 500, 300, 200,1 00 m. In the course of the investigation it appeared that for Chaetognaths the sampling method with changing bucket device is insufficient. Many specimens remained in the net and entered the bucket at a higher level than that in which they had lived, mostly during flushing the net (sample 100-0 m); this means considerable contamination. In spite of this difficulty deep layers of higher abundance could be traced for Sagitta lyra and some other species. For some species large local variations in the number of specimens within a short time were found. Moreover notes have been made of foodorganisms, parasits and anatornic metamorphoses during maturing.

(Table 2) Age model and sedimentation rate of sediment core GeoB5559-2

The Canary Basin lies in a region of strong interaction between the atmospheric and ocean circulation systems: Trade winds drive seasonal coastal upwelling and dust storm outbreaks from the neighbouring Sahara desert are the major source of terrigenous sediment. To investigate the forcing mechanisms for dust input and wind strength in the North Canary Basin, the temporal pattern of variability of sedimentological and geochemical proxy records has been analysed in two sediment cores between latitudes 30°30'N and 31°40'N. Spectral analysis of the dust proxy records indicates that insolation changes related to eccentricity and precession are the main periods of temporal variation in the record. Si/Al and grain-size of the terrigenous fraction show an increase in glacial-interglacial transitions while Al concentration and Fe/Al ratio are both in phase with minima in the precessional index. Hence, the results obtained show that the wind strength was intensified at Terminations. At times of maxima of Northern Hemisphere seasonal insolation, when the African monsoon was enhanced, the North Canary Basin also received higher dust input. This result suggests that the moisture brought by the monsoon may have increased the availability of dust in the source region.

Sediment and ice characteristics at a buried ice-wedge system at Barrow

Barrow, the northernmost point in Alaska, is one of the most intensively studied areas in the Arctic. However, paleoenvironmental evidence is limited for northern Alaska for the Lateglacial-Holocene transition. For a regional paleoenvironmental reconstruction, we investigated a permafrost ice-wedge tunnel near Barrow, Alaska. The studied site was first excavated in the early 1960s and intercepts a buried ice-wedge system at 3-6 m depth below the surface. A multi-methodological approach was applied to this buried ice-wedge system and the enclosing sediments, which in their combination, give new insight into the Late Quaternary environmental and climate history. Results of geochronological, sedimentological, cryolithological, paleoecological, isotope geochemical and microbiological studies reflect different stages of mid to late Wisconsin (MW to LW), Allerod (AD), Younger Dryas (YD), Preboreal (PB), and Late Holocene paleoenvironmental evolution. The LW age of the site is indicated by AMS dates in the surrounding sediments of 21.7 kyr BP at the lateral contact of the ice-wedge system as well as 39.5 kyr BP below the ice-wedge system. It is only recently that in this region, stable isotope techniques have been employed, i.e. to characterize different types of ground ice. The stable isotope record (oxygen: d18O; hydrogen: dD) of two intersecting ice wedges suggests different phases of the northern Alaskan climate history from AD to PB, with radiocarbon dates from 12.4 to 9.9 kyr BP (ranging from 14.8 to 10.6 kyr cal BP). Stable isotope geochemistry of ice wedges reveals winter temperature variations of the Lateglacial-Holocene transition including a prominent YD cold period, clearly separated from the warmer AD and PB phases. YD is only weakly developed in summer temperature indicators (such as pollen) for the northern Alaska area, and by consequence, the YD cold stadial was here especially related to the winter season. This highlights that the combination of winter and summer indicators comprehensively describes the seasonality of climate-relevant processes in discrete time intervals. The stable isotope record for the Barrow buried ice-wedge system documents for the first time winter climate change at the Lateglacial-Holocene transition continuously and at relatively high (likely centennial) resolution.

Geochemical investigations of sediment profiles in the Norwegian-Greenland Sea

High-, i.e. 15-140-yr-resolution climate records from sediment cores 23071, 23074, and PS2644 from the Nordic Seas were used to recon:;truct changes in the surface and deep water circulation during marine isotope stages 1-5.1, i.e. the last 82 000 yr. From this the causal links between the paleoceanographic signals and the Dansgaard-Oeschger events 1-21 revealed in 0180-ice-core records from Greenland were determined. The stratigraphy of the cores is based on the planktic 0180 curves, the minima of which were directly correlated with the GISP2-0180 record, numerous AMS 14C ages, and some ash layers. The planktic d18O and dl3C curves of all three cores reveal numerous meltwater events, the most pronounced of which were assigned to the Heinrich events 1-6. The meltwater events, among other things also accompanied by cold sea surface temperatures and high IRD concentration, correlate with the stadial phases of the Dansgaard-Oeschger cycles and in the western Iceland Sea also to colder periods or abrupt drops in 0180 within a few longer interstadials. Besides being more numerous, the meltwater events also show isotope values lighter in the Iceland Sea than in the central Norwegian Sea, especially if compared to core 23071. This implies a continuous inflow of relative warm Atlantic water into the Norwegian Sea and a cyclonic circulation regime.

Nucleonic intensities investigated during the Atlantic Expedition IQSY 1965 of RV "Meteor" (Appendix)

The nucleonic component of the cosmic rays has been measured by the German research vessel "Meteor" during the Atlantic Expedition IQSY 1965. The pressure corrected intensities fit well the rigidity calculations of Kondo and Kodamo. In this way we confirm the earth's magnetic field model used by these authors. Two positions of the cosmic ray equator have been determined at 29,7 °W (6,5 ± 1) °N and at 19 °W (7 ± 1) °N. These positions agree with the calculated values of Kondo and Kodamo. The total latitude effect of the nucleonic component amounts to 1.74 and 1.76. The measurements were carried out at solar minima activity. Using the values of latitude measurements at maxima solar activity the degree of modulation of the primary cosmic rays was determined in the rigidity range 2 - 13 GV. For rigidity values above 6 GV the modulation remains constant to 20 %.

Análise comparativa e teste empírico da validade dos modelos CAPM tradicional e condicional: o caso das ações da Petrobrás

ALVES, Janaína da Silva. Análise comparativa e teste empírico da validade dos modelos CAPM tradicional e condicional: o caso das ações da Petrobrás. Revista Ciências Administrativas, Fotaleza, v. 13, n. 1, p.147-157, ago. 2007.

Idrossiapatite biologica e di sintesi: analisi attraverso spettroscopia Raman

Le tradizionali tecniche usate per l’analisi della struttura e della composizione comprendono, tra le altre, microscopia ottica, microscopia elettronica, diffrazione a raggi X e analisi chimica. In generale però, la maggior parte di questi metodi richiede una procedura di preparazione che può modificare la struttura o la composizione del campione. È necessario infatti che il campione non subisca alterazioni particolari durante la fase di preparazioni in modo tale che le condizioni fisiologiche rimangano il più possibile simili a quelle che si hanno in situ. Una tecnica che ultimamente sta diventando sempre più significativa in ambito biomedico è la spettroscopia Raman. Innanzitutto con l’analisi Raman la quantità di materiale da studiare per ottenere buoni risultati è minima, visto che possono essere studiati campioni che vanno dai micro ai nanogrammi; inoltre, possono essere analizzati campioni umidi e a pressione atmosferica, condizioni che rispecchiano verosimilmente quelle fisiologiche. Questo tipo di analisi è inoltre vantaggiosa dato che riesce a identificare diversi composti chimici, ha un’elevata risoluzione spaziale (0.6-1µm), riuscendo quindi ad analizzare campioni molto piccoli, ha tempi di misura brevi e può essere utilizzato più volte sullo stesso campione senza che quest’ultimo venga danneggiato. Nel seguente elaborato si sono riportati i risultati di diversi studi condotti sull’idrossiapatite naturale/biologica e sintetica ottenuti mediante questa tecnica spettroscopica. In particolare, ci si è soffermati sulla diversa concentrazione di OH- presente nell’apatite stechiometrica rispetto a quella biologica e di come tale concentrazione sia influenzata dalla presenza o meno dello ione carbonato. Si riportano inoltre le analisi condotte su campioni sintetici e biologici per comprendere se le molecole di acqua si trovino all’interno della struttura del minerale (acqua di bulk) o se siano solamente assorbite in superficie.

Cycles saisonniers, reproduction et qualite des ovocytes chez Pecten maximus en rade de Brest

This work is part of the program, "recruitment determinism in scallops" initiated in 1992 by the "Contrat de Baie". The aim of this research was to explain interannual abundance fluctuations observed for Pecten maximus, in the Bay of Brest. To this end an analytical approach to the life cycle of the species was undertaken to determine its critical phases. A phase may be considered as "critical" if the mortality rate at its level varies from one year to the other. Using data from 1989 to 1994, a precise time-table of the "physiological year" of the scallop in the Bay of Brest was determined. Fecundity and gamete production kinetics were estimated from the annual variation in the weight indices of the gonad. In the laboratory, egg quality was estimated following stimulated spawning of newly caught individuals. The digestive activity was estimated by amylase activity measurements during a three year period. Spawning lasts 6 months in the Bay of Brest from March to October. Spawning, muscle and digestive gland growths, are intimately linked to phytoplancton blooms. Gonad production shows a maximum in April-May, and two relative minima in Match and November. These results, which provide detailed understanding of the adult's annual cycle in the Bay of Brest, will be used to interpret the relationship between the annual cycle and larval and post larval abundance and survival. Already, these results are being used to improve spat production in hatcheries.

Análise comparativa e teste empírico da validade dos modelos CAPM tradicional e condicional: o caso das ações da Petrobrás

ALVES, Janaína da Silva. Análise comparativa e teste empírico da validade dos modelos CAPM tradicional e condicional: o caso das ações da Petrobrás. Revista Ciências Administrativas, Fotaleza, v. 13, n. 1, p.147-157, ago. 2007.

Le peuplement littoral de Hon-Chong (Nhatrang)

On the area in relation with the very wave battered made, the associations to be noted are: 1) association with Bangia sp., which is seasonal and located at the level of Brachytrichia maculans. 2) Association with Chthamalus stellatus, which is very well developed over under the oysters’ level. 3) Association with Dermonema frappieri, which form a narrow band over the Chnoospora minima band. At the same level are located the associations with Ectocarpus braeviarticulatus, with Centroceras clavulatum, with Gymnogongrus Sereneii and with Chaetomorpha antennina. The infralittoral level does not present any conspicuous different.

O percurso poético-identitário de Aimée Bolaños nas vozes de Las Otras

Esta dissertação examina o livro Las Otras: Antología mínima del silencio (2004), de Aimée G. Bolaños, mais especificamente, dez dos poemas, os quais foram organizados em quatro grupos para traçar o percurso diaspórico da escritora, desde sua saída de Cuba, até seu domiciliamento no Brasil, na cidade do Rio Grande, no sul do Estado do Rio Grande do Sul. Para tanto, são abordadas a questão da mulher e da subalternidade, por se tratar de uma antologia composta por vozes femininas, e ainda são feitas reflexões sobre multivocalidade e construção identitária.

Nuevo método de identificación usando la respuesta escalón para sistemas de fase no mínima de segundo orden

Este artículo presenta un nuevo método de identificación para sistemas de fase no mínima basado en la respuesta escalón. El enfoque propuesto provee un modelo aproximado de segundo orden evitando diseños experimentales complejos. El método propuesto es un algoritmo de identificación cerrado basado en puntos característicos de la respuesta escalón de sistemas de fase no mínima de segundo orden. Él es validado usando diferentes modelos lineales. Ellos tienen respuesta inversa entre 3,5% y 38% de la respuesta en régimen permanente. En simulaciones, ha sido demostrado que resultados satisfactorios pueden ser obtenidos usando el procedimiento de identificación propuesto, donde los parámetros identificados presentan errores relativos medios, menores que los obtenidos mediante el método de Balaguer.

Radiogenic isotopes in the Mediterranean Sea: water mass exchange and precessional variability during the Messinian

During the late Miocene, exchange between the Mediterranean Sea and Atlantic Ocean changed dramatically, culminating in the Messinian Salinity Crisis (MSC). Understanding Mediterranean-Atlantic exchange at that time could answer the enigmatic question of how so much salt built up within the Mediterranean, while furthering the development of a framework for future studies attempting to understand how changes may have impacted global thermohaline circulation. Due to their association with specific water masses at different scales, radiogenic Sr, Pb, and Nd isotope records were generated from various archives contained within marine deposits to endeavour to understand better late Miocene Mediterranean-Atlantic exchange. The archives used include foraminiferal calcite (Sr), fish teeth and bone (Nd), dispersed authigenic ferromanganese oxyhydroxides (Nd, Pb), and a ferromanganese crust (Pb). The primary focus is on sediments preserved at one end of the Betic corridor, a gateway that once connected the Mediterranean to the Atlantic through southern Spain, although other locations are investigated. The Betic gateway terminated within several marginal sub-basins before entering the Western Mediterranean; one of these is the Sorbas Basin, a well-studied location whose sediments have been astronomically tuned at high temporal resolution, providing the necessary age control for sub-precessional resolution records. Since the climatic history of the Mediterranean is strongly controlled by precessional changes in regional climate, the aim was to produce records at high (sub-precessional) temporal resolution, to be able to observe clearly any precessional cyclicity driven by regional climate which could be superimposed over longer trends. This goal was achieved for all records except the ferromanganese crust record. The 87Sr/86Sr isotope record (Ch. 3) shows precessional frequency excursions away from the global seawater curve. As precessional frequency oscillations are unexpected for this setting, a numerical box model was used to determine the mechanisms causing the excursions. To enable parameterisation of model variables, regional Sr characteristics, data from general circulation model HadCM3L, and new benthic foraminiferal assemblage data are employed. The model results imply that the Sorbas Basin likely had a positive hydrologic budget in the late Miocene, very different to that of today. Moreover, the model indicates that the mechanism controlling the Sr isotope ratio of Sorbas Basin seawater was not restriction, but a lack of density-driven exchange with the Mediterranean. Beyond improving our understanding of how marginal Mediterranean sub-basins may evolve different isotope signatures, these results have implications for astronomical tuning and stratigraphy in the region, findings which are crucial considering the geological and climatic history of the late Miocene Mediterranean is based entirely on marginal deposits. An improved estimate for the Nd isotope signature of late Miocene Mediterranean Outflow (MO) was determined by comparing Nd isotope signatures preserved in the deeper Alborán Sea at ODP Site 978 with literature data as well as the signature preserved in the Sorbas Basin (Ch. 4; -9.34 to -9.92 ± 0.37 εNd(t)). It was also inferred that it is unlikely that Nd isotopes can be used reliably to track changes in circulation within the shallow settings characteristic of the Mediterranean-Atlantic connections; this is significant in light of a recent publication documenting corridor closure using Nd isotopes. Both conclusions will prove useful for future studies attempting to understand changes in Mediterranean-Atlantic exchange. Excursions to high values, with precessional frequency, are also observed in the radiogenic Pb isotope record for the Sorbas Basin (Ch. 5). Widening the scope to include locations further away from the gateways, records were produced for late Miocene sections on Sicily and Northern Italy, and similar precessional frequency cyclicity was observed in the Pb isotope records for these sites as well. Comparing these records to proxies for Saharan dust and available whole rock data indicates that, while further analysis is necessary to draw strong conclusions, enhanced dust production during insolation minima may be driving the observed signal. These records also have implications for astronomical tuning; peaks in Pb isotope records driven by Saharan dust may be easier to connect directly to the insolation cycle, providing improved astronomical tuning points. Finally, a Pb isotope record derived using in-situ laser ablation performed on ferromanganese crust 3514-6 from the Lion Seamount, located west of Gibraltar within the MO plume, has provided evidence that plume depth shifted during the Pliocene. The record also suggests that Pb isotopes may not be a suitable proxy for changes in late Miocene Mediterranean-Atlantic exchange, since the Pb isotope signatures of regional water masses are too similar. To develop this record, the first published instance of laser ablation derived 230Thexcess measurements are combined with 10Be dating.