999 resultados para IR emission
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稀土离子掺杂的氧氟玻璃是一种新型上转换发光材料。制备了Tm^3/Yb^3+单掺、共掺的摩尔分数为n(SiO2)-0.30,n(PbF2)-0.50,n=(Al2O3)=0.15,n(AlF3)=(0.049-x),n(TmF3)=y,n(YbF3)=x(x=0,0.001,0.010,0.015,0.020,y=0,0.001)系统氧氟玻璃,研究了其上转换发光特性、分析了其上转换发光机理。研究发现,在970nm抽运光源激发下,Tm^3+单掺时没有可见光上转换发射;而加入Yb^3+后产生了强的蓝光(452n
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设计了组成为0.70TeO2-(0.20-x)ZnO-xGeO2—0.05La2O3-0.025K2O-0.025Na2O-0.01Yb2O3(摩尔分数x=0,0.05,0.10,0.15和0.20)的碲酸盐激光玻璃,测试了热学性质、吸收光谱、荧光光谱和荧光寿命。计算了Yb^3+离子的吸收截面、受激发射截面、荧光有效线宽等参数。结果表明,组成为0.70TeO2-0.20GeO2-0.05La2O3-0.025K2O-0.025Na2O的玻璃具有优于著名的碲锌钠(TZN)玻璃的热稳定性,高的受激发射截面(1
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研究了摩尔组分为70TeO2-(20-x)ZnO-xPbO-5La2O3-2.5K2O-2.5Na2O(x=0,5,10,15,20)的新型多元铅锌镧碲酸盐激光玻璃,外掺Yb2O3为玻璃摩尔组分的1%,测试了试样的物理性质及吸收光谱、荧光光谱和荧光寿命,计算了Yb^3+的吸收截面、受激发射截面、荧光有效线宽等光谱参数,结果表明:该系列玻璃都具有良好的热学稳定性((Tx-Tg)>195℃,高于TZN玻璃(118℃));当X=15时,样品具有较好的光谱性质:高的受激发射截面(1.25pm^2)、长的荧光寿命(
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Ce3+ ions were introduced into the Er3+/Yb3+ -codoped TeO2-WO3-ZnO glasses, and the effect of Ce3+ on the emission properties at 1.5 mu m band and the upconversion luminescence of Er3+ in the glasses was investigated. With the increasing of Ce3+ concentration, the emission intensity of Er3+ at 1.5 mu m band increases firstly, and then decreases. The optimal doping concentration of Ce3+ is about 2.07 x 10(20)/cm(3). As for the Er3+ emission at 1.5-mu m band, the fluorescence lifetime decreases a little from 3.4ms to 3.0ms, while the full width at half maximum (FWHM) hardly changes with the increase of Cc 3+ concentration. Due to the effective cross relaxation between Ce3+ and Er3+ : Er3+ (I-4(11/2)) + Ce3+ (F-2(5/2)) -> Er3+ (I-4(13/2)) + Ce3+ (F-2(7/2)), the upconversion emission intensity of Er3+ is reduced greatly. But when Ce3+ -doping concentration is too high, the other cross relaxation between Ce3+ and Er3+ : Er3+ (4I(13/2)) + Ce3+ (F-2(5/2)) -> Er3+ (I-4(15/2)) + Ce3+ (F-2(7/2)) happens, which depopulates the I-4(13/2) level of Er3+ and results in the decrease of the emission intensity and fluorescence lifetime of Er3+ at 1.5 mu m band.
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研究了掺铒氟(卤)磷碲酸盐玻璃的吸收光谱和上转换荧光光谱,探讨了Er^2+在氟(卤)磷碲酸盐玻璃中的上转换发光机理.在975nm激光二极管抽运下产生强烈的上转换红光及绿光。且红光的发光强度要远远大于绿光.以PbCl2取代PbF2后,红光的发光强度下降,而绿光却没有明显变化;以ZnCl2取代ZnF2达5mol%时,红光和绿光的发光强度均明显增大.
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应用Judd-Oflet理论计算了新型掺铒高硅氧玻璃中铒离子的强度参量Ωt(t=2,4,6),Ω2=8.15×10^-20,Ω4=1.43×10^-20,Ω6=1.22×10^-20,相比于其他氧化物玻璃,表现出较大的Ω2,6值,反映了铒离子周围的近邻结构不对称性和Er-O键的离子键成分较高.利用McCumber理论计算得到了能级4I13/2→4I15/2跃迁的受激发射截面为σc=O.51pm^2.这种高硅氧玻璃掺铒离子浓度尽管高于石英光纤的掺杂浓度10倍左右,其荧光寿命和量子效率仍达到6.0ms和66.
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制备了四种不同铒离子掺杂浓度的碲酸盐玻璃,通过测定吸收光谱计算了吸收谱线的振子强度,根据Judd-Ofelt理论计算了不同浓度下Er^3+离子发光光谱的强度参数Ω(i=2,4,6),计算了自发辐射电偶和磁偶跃迁概率、辐射寿命、荧光分支比等参数,讨论了Er^3+离子浓度变化对以上这些参数的影响。测试了Er^3+:^4I13/2→^4I15/2跃迁对应的荧光光谱和Er^3+:^4I13/2能级荧光寿命。最后应用McCumber理论计算了玻璃中Er^3+:^4I13/2→^4I15/2跃迁对应的受激发射截面大小
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制备了用于离子交换法制备光波导器件的掺铒碲-钨-钠玻璃基质。应用扎得-奥菲而特(Judd—Ofelt)理论计算了玻璃样品的三个强度参量,由强度参量计算了Er^3+离子的自发跃迁几率、荧光分支比等光谱参量;应用麦克库玻(McCumber)理论,计算了Er^3+离子在1.5μm的受激发射截面,荧光测试发现Er^3+离子的荧光半峰全宽可达65nm。比较了Er^3+离子在不同玻璃基质中的光谱特性。结果表明,Er^3+离子在碲-钨-钠玻璃中具有较高的受激发射截面和较宽的荧光半峰全宽,可以用于宽带光波导器件的制备。
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The integrated absorption cross section Sigma(abs), I peak emission cross section sigma(cmi), Judd-Ofeld intensity parameters Omega(iota) ( t = 2,4,6), and spontaneous emission probability A(R) of Er3+ ions were determined for Erbium doped alkali and alkaline earth phosphate glasses. It is found the compositional dependence of sigma(emi) 5 almost similar to that of Sigma(abs), which is determined by the sum, of Omega(1) (3 Omega(2) + 10 Omega(4) + 21 Omega(6)). In addition, the compositional dependence of Omega(1) was studied in these glass systems. As a result, compared with. Omega(4) and Omega(6) the Omega(2) has a stronger compositional dependence on the ionic radius and content of modifers. The covalency of Er-O bonds in phosphate glass is weaker than that in silicate glass, germanate glass, aluminate glass, and tellurate glass, since Omega(6) of phosphate glass is relatively large. A(R) is affected by the covalency of the Er3+ ion sites and corresponds to the Omega(6) value.
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Optical spectroscopic properties of Er3+-doped alkaline-earth metal modified fluoropho sphate glasses have been investigated experimentally for developing broadband fiber and planar amplifiers. The results show a strong correlation between the alkaline-earth metal content and the spectroscopic parameters such as absorption and emission cross sections, full widths at half-maximum and Judd-Ofelt intensity parameters. It is found that strontium ions could have more influences on the Judd-Ofelt intensity parameters and the absorption and emission cross sections than other alkaline-earth metal ions such as Mg2+, Ca2+, Ba2+. The sample containing 23 mol% strontium fluoride exhibits the maximum emission cross section of 7.58 x 10(-21) cm(2), the broadest full width at half-maximum of 65 nm and the longer lifetime of 8.6 ms among the alkaline-earth metal modified fluorophosphates glasses studied. The Judd-Ofelt intensity parameter Omega(6)s, the emission cross sections and the full widths at half-maximum in the Er3+-doped fluorophosphate glasses studied are larger than in the silicate and phosphate glasses.
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Three Er3+-doped tellurite glasses with compositions of 70TeO(2)-30ZnO, 70TeO(2)-20ZnO-10Nb(2)O(5) and 70TeO(2)-20ZnO-5BaO-5Nb(2)O(5) have been investigated for developing fiber and planar broadband amplifiers and lasers. The optical spectroscopic properties and thermal stability of Er3+-doped tellurite glasses have been discussed. The results show that the incorporation of Nb2O5 increases the thermal stability of Er3+-doped tellurite glasses significantly, Er3+-doped niobium tellurite glasses 70TeO(2)-20ZnO-10Nb(2)O(5) and 70TeO(2)-20ZnO-5BaO-5Nb(2)O(5) exhibit the good thermal stability (DeltaT > 150degreesC), the large emission cross-section (>10 x 10(-21) cm(2)) and broad full width at half maximum (similar to65 nm), will be preferable for broadband Er3+-doped fiber amplifiers. (C) 2004 Elsevier B.V. All rights reserved.
Resumo:
测量了不同掺杂浓度下Er^3+离子在碲酸盐玻璃中的吸收光谱、发射光谱和Er^3+离子的荧光寿命,计算了Er^3+离子的发射截面σc,分析了Er^3+离子掺杂浓度对其发光强度和荧光寿命的影响.结果表明,Er^3+离子掺杂浓度较低时,对其荧光强度和荧光寿命没有显著的影响;掺杂浓度高时,出现了浓度猝灭效应,使Er^3+离子荧光光强度降低,荧光寿命下降.实验确定了掺杂浓度最优值,同时对浓度猝灭机制进行了分析.
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分析了掺Er^3+碲酸盐玻璃的热力学稳定性能,研究了掺Er^3+碲酸盐玻璃的吸收和荧光光谱性质;应用Judd-Ofelt理论计算了碲酸盐玻璃中Er^3+离子的强度参数Ω(Ω2=4.79×10^-20cm^2,Ω4=1.52×10^-20cm^2,Ω6=0.66×10^-20cm^2),计算了离子的自发跃迁几率,荧光分支比;应用McCumber理论计算了Er^3+的受激发射截面(σe=10.40×10^-21cm^2)、Er^3+离子^4I13/2→^4I15/2发射谱的荧光半高宽(FWHM=65.5nm)
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研制了一种用于宽带波导放大器的掺铒碲钨酸盐激光玻璃材料,对玻璃热稳定性、光谱性质进行了表征,并在其上采用离子交换法制作了平面光波导.掺铒碲钨酸盐玻璃的转变温度Tg和析品开始温度Tx分别为377.1和488.5℃;荧光半高宽为52nm;应用McCumber理论,计算得出Er^3+离子4I13/2→^4I15/2跃迁在峰值波长1532nm的受激发射截面为0.91×10^-20cm^2.不同条件下制作了在632.8nm处多模的平面光波导,通过拟合得到Ag^+离子在300℃的有效扩散系数De为2.82×10^-1
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研究了掺铒TeO2-ZnO-PbCl2碲酸盐基氧卤玻璃在977nm激光二极管抽运下的发光和上转换发光特性,结果发现除红外1.53μm^4I13.2→^4I15/2发光外(荧光半高宽高达69nm),该玻璃还存在很强的^2H11/2→^4I15/2(527nm),^4S3/2→^4I15/2(549nm)和^4R9/2→^4I15/2(666nm)可见上转换发光.应用Judd-Ofelt理论计算得到玻璃强度参数Ω1(t=2,4,6)分别为Ω2=5.87×10^20cm^2,Ω4=2.08×10^2-cm^2,