n-GaAs和p-GaN晶片的直接键合

采用直接键合的方法成功实现了n-GaAs和p-GaN晶片的高质量键合.扫描电子显微镜观测结果表明,键合界面没有空洞.键合前后光致发光谱测试表明,键合工艺对材料质量影响不大.室温下界面的电流-电压特性表明,键合得到的n-GaAs/p-GaN异质结为肖特基二极管并且理想因子为1.08.n-GaAs和p-GaN材料直接键合的成功对于集成GaAs和GaN材料制备光电集成器件有重要意义.

非晶/微晶过渡区域硅薄膜的微区喇曼散射研究

通过改变氢气对硅烷气体的稀释程度，并保持其他的沉积参量不变，用等离子体增强化学气相沉积（PECVD）方法成功地制备出非晶/微晶相变过渡区域的硅薄膜样品。测量了样品的室温光电导和暗电导，样品的光电性能优越，在50 mW·cm~（-2）的白光照射下，光电导和暗电导的比值达到10~6。在室温下用微区喇曼谱研究了薄膜的微结构特性，用高斯函数对喇曼谱进行了拟合分析。结果表明，在我们的样品制备条件下，当H_2和SiH_4的流量比R较小时，样品表现出典型的非晶硅薄膜 的结构特性；随流量比R的增大，薄膜表现出两相结构，其中的微晶成分随氢稀释比的增大逐渐增多；用量子尺寸效应估算了两个高氢稀释样品（R > 50）中微晶粒子的平均尺寸大小为2.4 nm左右；样品的中程有序度随氢稀释程度的增加而增大。

PROJECTILE FRAGMENTATION OF Ar-36,Ar-40 INDUCED REACTIONS

Fragment yields for Z >= 5 from projectile fragmentation using primary beams of Ar-36,Ar-40 at 50 MeV/nucleon on Ni-64 target have been measured in RIBLL fragment separator. We compare the fragment cross sections with the predictions of the empirical EPAX parametrization of fragmentation cross-sections and Statistical Abration-Ablation model (SAA) by considering the RIBLL separator transmission rate. Isotope yield ratios between these two reactions were calculated and isoscaling parameters alpha and beta are extracted, their dependences on fragment atomic number Z and neutron number N were presented.

感染糠虾的三种病原体的形态观察

感染糠虾的三种病原体的形态观察＊国际翔王丽霞李文清刘丹（中国科学院沈阳应用生态所，沈阳１１００１５）糠虾属软甲亚纲（Ｍａｌａｃｏｓｔｒａｃａ），糠虾目（Ｍｙｓｉｄｃｅａ）。在我国北部黄渤海沿岸糠虾的产量很大，年产量几十万斤。不仅可供食用，也是人工养殖...

空间直观景观模型在呼中林区土壤侵蚀预测研究中的初步应用

土壤通用流失方程 (USLE)已被广泛应用于大尺度的土壤侵蚀预测 .在以往的土壤侵蚀研究中 ,由于只能获得静态的植被图 ,土壤通用流失方程只能用于土壤侵蚀的静态估算 .空间直观景观模型能在大尺度上模拟植被动态 ,为土壤通用流失方程提供动态的植被因子 ,从而使土壤侵蚀的动态模拟成为可能 .本研究结合空间直观景观模型LANDIS和土壤通用流失修正方程 ,以大兴安岭呼中林区为研究区 ,动态地模拟未来 6 5 0年内有采伐和无采伐预案下的土壤侵蚀量 ;同时以无火无采伐预案下的土壤侵蚀为对比值 .结果表明 ,土壤侵蚀量随时间变化呈周期性的波动 ,其波动程度在无火无采伐预案下最小 ,而在有火无采伐预案下最大 ;采伐对土壤侵蚀的影响没有火对土壤侵蚀的影响在空间上表现得明显 ,但是其累积效果则比火的影响强 ;降低采伐所产生的裸露土能有效降低年平均土壤侵蚀量 ,但是对土壤侵蚀动态变化的影响不明显 ;虽然采伐增加使平均土壤侵蚀量增加 ,但是也同时使土壤侵蚀的年际变化更趋于平稳 .

The investigation of exfoliation process of organic modified montmorillonite in thermoplastic polyurethane with different molecular weights

Cloisite 30B (30B) was melt-mixed with two kinds of thermoplastic polyurethane (TPU) with different molecular weights to discern the roles of molecular diffusion and shear in the exfoliation process. The higher level of exfoliation was achieved in TPU matrix with higher molecular weight due to the appropriate viscosity. In order to have an insight into the mechanism of exfoliation, the degree of dispersion and exfoliation of 30B was characterized by wide angle X-ray diffraction and transmission electron microscopy. The layers of 30B were exfoliated via a slippage process, which was also observed in polyamide 12 nanocomposites recently.

Direct electrochemistry and electrocatalysis of horseradish peroxidase immobilized in sol-gel-derived ceramic-carbon nanotube nanocomposite film

The sol-gel-derived ceramic-carbon nanotube (SGCCN) nanocomposite film fabricated by doping multiwall carbon nanotubes (MWNTs) into a silicate get matrix was used to immobilize protein. The SGCCN film can provide a favorable microenvironment for horseradish peroxidase (HRP) to perform direct electron transfer (DET) at glassy carbon electrode. The HRP immobilized in the SGCCN film shows a pair of well-defined redox waves and retains its bioelectrocatalytic activity to the reduction of O-2 and H2O2, which is superior to that immobilized in silica sol-gel film.

Compatibility and specific interactions in poly(beta-hydroxybutyrate) and poly(p-vinylphenol) blends

The miscibility and specific interactions in poly (beta-hydroxybutyrate) (PHB)/poly(p-vinylphenol) (PVPh) blends were studied by differential scanning calorimetry(DSC) , fourier transform infrared(FTIR) spectrometer and high resolution solid state C-13 NMR, A single composition-dependent glass transition temperatures were obtained by DSC which indicate the blends of PHB/PVPh were miscible in the melt state, The experimental glass transition temperatures were fitted quite well with those obtained from Couchman-Karasz equation. The FTIR study shows that the strong intermolecular hydrogen bonding exists in blends of PHB with strong proton acceptor and PVPh with strong proton donor and is the origin of its compatibility. The CPMAS C-13 NMR spectra also show that the strong hydrogen bonding exists in PHB/PVPh blends. From the T-1 rho(H) relaxation time it follows that the blends of PHB/PVPh(40/60, 20/80) studied are completely homogeneous on the scale of about 3.2 nm.

PHB／PVPh共混体系的相容性及分子间的特殊相互作用

ＰＨＢ／ＰＶＰｈ共混体系的相容性及分子间的特殊相互作用邢佩祥，董丽松，冯汉桥，安玉贤，庄宇钢，冯之榴（中国科学院长春应用化学研究所高分子物理开放实验室，长春，１３００２２；中国科学院武汉物理研究所波谱与原子分子实验室）关键词氢键，相容性，聚（β－羟基...