Instances of combinatorial optimization problems: complexity and generation

138 p.

Optical properties of nickel(II)-azo complexes thin films for potential application as high-density recordable optical recording media

Smooth thin films of three kinds of nickel(II)-azo complexes were prepared by the spin-coating method. Absorption spectra of the thin films on K9 glass substrate in the 300-600 nn wavelength region were measured. Optical constants (complex refractive index N = n + ik) and thickness of the thin films prepared on single-crystal silicon substrate in the 300-600 nm wavelength region were investigated on rotating analyzer-polarizer type of scanning ellipsometer, and dielectric constants epsilon (epsilon = epsilon(1) + i epsilon(2)), absorption coefficients a as well as reflectance R of thin films were then calculated at 405 nm. In addition, in order to examine the possible use of nickel(II)-azo complex thin film as an optical recording medium, one of the nickel(II)-azo complex thin film prepared on K9 glass substrate with an Ag reflective layer was also studied by atomic force microscopy and static optical recording. The results show that the nickel(II)-azo complex thin film is smooth and has a root mean square surface roughness of 2.25 nm, and the recording marks on the nickel(II)-azo complex thin film are very clear and circular, and their size can reach 200 nn or less. (c) 2006 Elsevier Ltd. All rights reserved.

Temperature dependence of thermal properties of Ag8In14Sb55Te23 phase-change memory materials

The dependence of thermal properties of Ag8In14Sb55Te23 phase-change memory materials in crystalline and amorphous states on temperature was measured and analyzed. The results show that in the crystalline state, the thermal properties monotonically decrease with the temperature and present obvious crystalline semiconductor characteristics. The heat capacity, thermal diffusivity, and thermal conductivity decrease from 0.35 J/g K, 1.85 mm(2)/s, and 4.0 W/m K at 300 K to 0.025 J/g K, 1.475 mm(2)/s, and 0.25 W/m K at 600 K, respectively. In the amorphous state, while the dependence of thermal properties on temperature does not present significant changes, the materials retain the glass-like thermal characteristics. Within the temperature range from 320 K to 440 K, the heat capacity fluctuates between 0.27 J/g K and 0.075 J/g K, the thermal diffusivity basically maintains at 0.525 mm(2)/s, and the thermal conductivity decreases from 1.02 W/m K at 320 K to 0.2 W/m K at 440 K. Whether in the crystalline or amorphous state, Ag8In14Sb55Te23 are more thermally active than Ge2Sb2Te5, that is, the Ag8In14Sb55Te23 composites bear stronger thermal conduction and diffusion than the Ge2Sb2Te5 phase-change memory materials.

超大功率二维半导体激光列阵并路自适应稳模技术

半导体列阵量子效率高,输出波长范围涵盖570～1600nm,工作寿命可达数百万小时,叠层列阵可提供超高功率激光输出,在工业、医学等很多领域具有非常广阔的应用前景。但列阵在自由运行时,各发光单元发出的光是不相干的,输出质量差,采用1/4Talbot外腔镜耦合技术,列阵实现了空间锁相最高阶超模,然而唯有基超模远场分布是中心单瓣结构,输出接近衍射极限。为得到最小谱宽、最小发散角、最大功率密度输出,必须将外腔镜倾斜β=λ/2d(λ为工作波长,d为列阵周期),这使得仅有基超模光能成像于发光单元内而被允许振荡。应用此

Influence of synthetic method on the properties of La0.5Ba0.5FeO3 SOFC cathode

Power Point presentado en The Energy and Materials Research Conference - EMR2015 celebrado en Madrid (España) entre el 25-27 de febrero de 2015

2W Yb-doped double-clad fiber superfluorescent source with 42 nm 3 dB bandwidth

The output spectrum of Yb-doped double-clad fiber superfluorescent source (SFS) is tailored by placing a broadband dichroic mirror in the pump end of conventional single-pass forward configuration, which constitutes double-pass forward configuration. The 3 dB bandwidth is increased from I I to 42 nm. A maximum output SFS power of 2.12 W and a slope efficiency of 43.2% are obtained. The double-clad fiber is 25 in and the pump power is adequate to saturate the fiber as far as the feedback-induced lasing appears. (c) 2004 Elsevier Ltd. All rights reserved.

Double-cladding Yb3+ fiber for free-space optical communication

The experiment result of Nd:YVO4 laser pumped by laser diode that was amplified by double-cladding Yb3+ fiber is reported. Stable mode-locking pulses are obtained at repetition rate of 320 MHz and the output power is 15 mW. When laser power is amplified by Yb3+- doped double-cladding fiber amplifier, its power can get to 600 mW. Based on these, experiment of double-frequency is carried out, and green laser with power of 4 mW is obtained. (c) 2007 Wiley Periodicals, Inc.

A mulher como representação do bem e do mal n A Demanda do Santo Graal e n A Divina Comédia

Esta dissertação tem como objetivo trabalhar com a forte significação que o feminino apresenta nas narrativas medievais, em especial nA Demanda do Santo Graal e nA Divina Comédia, dois dos mais importantes textos medievais. Pode-se observar um padrão na caracterização dessas mulheres, pois elas são modelos do Bem ou do Mal. Pode-se perceber esse modelo em ambas as obras citadas. NA Demanda do Santo Graal, encontram-se mulheres que desviam o caminho do homem rumo ao Graal que representa o máximo da ascese espiritual. São as mulheres pecadoras, filhas de Eva, que trouxe a morte ao mundo. Também, na Demanda, encontram-se mulheres santas e plenas de virtude que se equiparam à mãe de todas as santas da literatura medieval: Beatriz, dA Divina Comédia. Beatriz é um guia espiritual e não um obstáculo a ser ultrapassado. Daí vai a comparação com as mulheres plenas de virtude da Demanda. Aqui as mulheres santas das duas obras se equiparam. São todas elas símbolos de crescimento na vida dos personagens masculinos. No entanto, tentaremos comprovar que Beatriz é a maior de todas e será utilizada neste trabalho porque na Demanda não podemos encontrar o modelo de mulher perfeita. Chega-se então ao principal objetivo desse trabalho que é observar, na literatura medieval, os vários tipos de mulheres existentes, e as semelhanças e diferenças entre elas, especialmente nA Divina Comédia e nA Demanda do Santo Graal. Tenta-se com isso traçar um elo entre essas duas importantes literaturas (portuguesa e italiana) através de dois textos que apresentam o misterioso papel das mulheres na literatura

Reprodução de peixes de riachos: uma abordagem comparativa entre as estratégias r e K

No presente trabalho, objetivou-se caracterizar a estratégia reprodutiva, enfatizando o investimento energético, de duas espécies de peixe do rio Ubatiba, Maricá, Rio de Janeiro: Parotocinclus maculicauda (K-estrategista) e Astyanax hastatus (r-estrategista). Foram realizadas coletas bimestrais de Junho de 2010 a Abril de 2011 totalizando 236 exemplares amostrados de A. hastatus e 234 de P. maculicauda. Para cada exemplar foram registrados os dados de comprimento padrão (Cp, cm), peso total (Pt, g), peso gonadal (Pg, g), sexo e estádio de maturação. Através da estrutura de tamanho, observamos que as fêmeas atingem maior comprimento, em relação aos machos, para as duas espécies. A relação peso/ comprimento evidenciou para ambas as espécies, crescimento alométrico negativo (inferior a 3), demonstrando crescimento mais longelíneo. Para a proporção sexual, o teste χ2 foi aplicado e indicou que, para as duas espécies, há significativamente mais fêmeas. A distribuição sexual no ano mostrou que as fêmeas se mantêm em maioria durante todo o ano para P. maculicauda. Para A. hastatus este padrão também se mantém, porém com exceção do bimestre Novembro/Dezembro, quando o número de machos torna-se um pouco maior. O tamanho de primeira maturação mostrou-se o mesmo para ambas as espécies (2,5 a 3,0 cm). A variação temporal da freqüência de indivíduos reprodutivos e não reprodutivos juntamente com a distribuição temporal dos valores individuais de IGS mostrou que P. maculicauda se reproduz com maior intensidade nas estações chuvosas (Setembro a Abril), reduzindo sua atividade reprodutiva de maneira significativa nas estações secas (Maio a Agosto). Já A. hastatus demonstrou regular atividade reprodutiva durante todo o ano com pequeno pico no bimestre Novembro/ Dezembro. Desova do tipo total foi registrada para Astyanax, enquanto que para Parotocinclus registrou-se desova parcelada em três lotes. Em ambas as espécies foi observada relação inversa entre volume e a quantidade de ovócitos produzidos, com A. hastatus produzindo muitos ovócitos (fecundidade: 463 + 213 ovócitos/grama de peixe) de reduzido volume (diâmetro = 800 μm e volume = 0,26 mm3) e P. maculicauda produzindo número bem inferior (fecundidade: 47 + 13 ovócitos/grama de peixe), porém com volume superior (diâmetro = 1.600 μm e volume = 2,14 mm3). Com isso o valor energético relativo também se mostrou superior, com A. hastaus produzindo ovócitos vitelogênicos com 0,4+ 0,08 cal/unidade e P. maculicauda produzindo os mesmos ovócitos com 1,8+ 1,1 cal/unidade. Para a produção energética total investida na produção de gametas, foi considerado o tipo de desova de cada espécie, com Astyanax investindo 50,5 + 24 calorias/grama/grama de peixe e Parotocinclus investindo 88,4 + 72,46 cal/grama/grama de peixe, porém sem diferenças significativas (Mann-Whitney; U =235,0, p=0,08), indicando, portanto que independente da estratégia adotada (r ou K), o gasto energético na produção de ovócitos é a mesma.

Bismuth-doped zinc aluminosilicate glasses and glass-ceramics with ultra-broadband infrared luminescence

Broadband infrared luminescence covering the optical telecommunication wavelength region of 0, E and S bands was observed from bismuth-doped zinc aluminosilicate glasses and glass-ceramics. The spectroscopic properties of the glasses and glass-ceramics depend on the thermal-treatment history. With the appearance of gahnite (ZnAl2O4) crystalline phase, the fluorescent peak moves to longer wavelength, but the fluorescent intensity decreases. The similar to 1300 nm fluorescence with a FWHM larger than 250 nm and a lifetime longer than 600 mu s possesses these optical materials with potential applications in laser devices and broadband amplifiers. The broad infrared luminescence from the bismuth-doped zinc aluminosilicate glasses and glass-ceramics might be from BiO or bismuth clusters rather than from Bi5+ and Bi3+. (c) 2005 Elsevier B.V. All rights reserved.

一种宽带拉曼放大碲酸盐玻璃的拉曼散射特性

The flattening and broadening effects of Ga2O3, GeO2, P2O5 in TeO2-BaCO3-SrCO3- Nb2O5 (TBSN) glass system were studied. The results showed that P2O5 can broaden the vibration band in Raman spectra and Ga2O3, GeO2 can flatten the spectra compared with TBSN glass. And also, they can extend the main vibration band and decrease the vibration intensity of 730 cm^-1 and 780 cm^-1 nonbridging oxygen connected with Te. They also make for the decrease of flatness in 600-870 cm^-1 vibration band and GeO2 has larger effect than Ga2O3 in weakening the vibration of nonbridging oxygen.

Spectroscopic properties of Er3+-doped tellurite glass for 1.55 mu m optical amplifier

Er3+-doped TeO2-BaO (Li2O, Na2O)-La2O3 tellurite glass system was prepared and their density, characteristic temperatures and optical properties were determined and investigated. For the TeO2-BaO-La2O3-Er2O3 system, composition with 10 mol% BaO presented the highest thermal stability and good infrared transmittance. Intense and broad 1.53 mu m infrared fluorescence were observed under 977 nm diode laser excitation and the most full width at half-maximum (FWHM) is similar to 60nm. According to absorption spectrum, we calculated the optical parameters by means of Judd-Ofelt and McCumber theory such as the fluorescence lifetimes which are about 2.72-3.25 ms and the maximum emission cross-sections which are similar to 1.0pm(2) at 1.531 mu m. The sigma(e) x FWHM value of composition with 10 mol% BaO for gain bandwidth is similar to 600 exceeding those in silicon and phosphate glasses. Our results indicated this kind of tellurite glasses could be used as an ideal host glass for optical amplifier. (c) 2005 Elsevier B.V. All rights reserved.

Spectroscopic properties of Er3+ doped TeO2-BaO (Li2O, Na2O)-La2O3 glasses for 1.5-mu m optical amplifiers

This paper reports on the optical spectroscopic properties and thermal stability of Er3+-doped TeO2-BaO (Li2O,NaO)-La2O3 glasses for developing 1.5-mu m fiber amplifiers. Upon excitation at 977 nm laser diode, an intense 1.53-mu m infrared fluorescence has been observed with a broad full width at half maximum (FWHM) of about 60 nm for the Er3+-doped TeO2-BaO (Li2O, Na2O)-La2O3 glass with 10 mol% of BaO. The calculated fluorescence lifetime and the emission cross-sections of the 1.53-mu m transition are 2.91 ms and similar to 9.97 x 10(-21) cm(2), respectively. It is noted that the gain bandwidth, a, x FWHM, of the TeO2-BaO-La2O3Er2O3 glass is about 600, which is significantly higher than that in silicate and phosphate glasses. Meanwhile, it is interesting to note that the TeO2-BaO-La2O3-Er2O3 glass has shown a high glass thermal stability and good infrared transmittance. As a result, TeO2-BaO (Li2O, Na2O)-La2O3 glass with 10 mol% of BaO has been considered to be more useful as a host for broadband optical fiber amplifier. (c) 2005 Elsevier B.V. All rights reserved.

石英玻璃表面金属沉积层的界面研究

就石英玻璃的金属化进行了初步研究，综合考虑石英玻璃管和金属的特点，合理选择金属化膜层；采用磁控溅射工艺在石英玻璃表面镀制薄膜，利用俄歇电子能谱（AES）进行了界面分析。发现膜层在沉积过程中有轻微的扩散和界面还原反应现象，后期的热处理使这种现象变得更加显著。600℃时界面扩散变得明显，Ni膜中Mo的含量达到了20％；800℃时界面扩散已经很严重，表层Ni膜渗过Mo膜进入到Ti层。因此在后期处理时，温度应控制在700℃左右。对样品灯进行了检验，加速寿命及灯头耐压检验结果均通过初步考核。

Epitaxial growth of ZnO films on (100) and (001) gamma-LiAlO2 substrates by pulsed laser deposition

Structural and optical properties were investigated for ZnO films grown on (100) and (001) gamma-LiAlO2 (LAO) substrates by pulsed laser deposition method. According XRD results, it is intuitionistic that (100) LAO is suitable for fabricating high quality ZnO film, while (001) LAO is unsuitable. The FWHM of XRD, stress in film and FWHM of UV PL spectra for ZnO films on (100) LAO show a decreasing with increasing substrate temperature from 300 to 600 degrees C. ZnO film fabricated at 600 degrees C has the greatest grain size, the smallest stress (0.47 Gpa) and PL FWHM value (similar to 85 meV). This means that the substrate temperature of 600 degrees C is optimum for ZnO film deposited on (100) LAO. Moreover, it was found that the UV PL spectra intensity of ZnO film is not only related to the grain size and stoichiometric, but also depends on the stress in the film.