Synchronous scanning phosphorimetry for the selective determination of chrysene: a metrological study

Room-temperature phosphorimetry was used to quantify trace levels of chrysene in sugar-cane spirits and in fish bile. A selective phosphorescence enhancer (AgNO3) and synchronous scanning allowed the detection of ng amounts of chrysene. Accuracy (113 ± 17%) and selectivity was evaluated using the CRM-NIST-1647d - Priority Pollutant Polycyclic Aromatic Hydrocarbons in acetonitrile. Analysis of sugar-cane spirit samples enabled recovery of 108 ± 18% which agreed with the one achieved using HPLC. Method's uncertainty was equivalent to 3.4 ng of the analyte, however, the analyte pre-concentration (SPE) improved sensibility and minimized the relative uncertainty. Characterization and homogeneity studies in fish bile were also performed.

Keskijänniteverkon käyttövarmuuden parantaminen verkostoautomaatiolla

Tässä työssä tutkitaan maastokatkaisijoiden ja kauko-ohjattavien erottimien kannattavia sijoituskohteita keskijänniteverkkoon. Kannattavuutta lasketaan kannattavuuslaskennalla, jonka lopputuloksena saadaan automaatiolaitteiden aiheuttama keskeytyskustannussäästö. Saaduille keskeytyskustannussäästöille lasketaan investoinnin takaisinmaksuaika, joka määrää kohteiden tärkeysjärjestyksen. Lisäksi tarkastellaan verkostomuutosten vaikutusta automaatiolaitteiden kannattavuuteen. Kannattavuuslaskentaa varten keskijänniteverkko jaetaan vyöhykkeisiin. Vyöhykkeiden avulla huomioidaan olemassa olevien kauko-ohjattavien erottimien ja varasyöttöjen vaikutukset. Laskentaparametrit määritetään yhtiön tilastoista. Tutkimuksessa on esitetty automaatiolaitteiden kannattavuuslaskentaa esimerkkikohteiden avulla, jotka on valittu keskijänniteverkon rakenteen perusteella. Maastokatkaisijoille ja kauko-ohjattaville erottimille löytyi paljon kannattavia sijoituskohteita. Maastokatkaisijalle havaittu lisäominaisuus parantaa sen kannattavuutta entisestään. Automaatiolaitteiden aiheuttamat keskeytyskustannussäästöt riippuvat siirrettävästä tehosta, vikataajuuksista ja keskeytyskustannusten arvoista, joiden vaikutusta on kuvattu herkkyystarkasteluilla.

Ekonomien ammatillisen kehittymisen tarpeet

Tämä pro gradu -tutkielma käsittelee ekonomien ammatillisen kehittymisen tarpeita muuttuvassa maailmassa, jossa ammatillinen erityisosaaminen vanhenee nopeasti. Tutkimuksessa tarkastellaan ekonomikunnassa koettuja ammatillisen kehittymisen tarpeita substanssin ja oppimistapojen näkökulmasta. Tutkimuksen tavoitteena on selvittää, millaisia ammatillisen kehittymisen tarpeita ekonomeilla on ja miten näihin tarpeisiin voisi vastata. Tutkimuksen pyrkimyksenä on selvittää myös, miten Suomen Ekonomiliitto SEFE voisi auttaa jäseniään kehittymään edelleen ammatillisesti. Aikuisoppimis- ja motivaatioteorioita on olemassa lukuisia. Pro gradun teoriaosassa selvitetään, miten aikuisten oppiminen tapahtuu, mitä se pitää sisällään ja mikä motivoi oppimaan. Lisäksi tutkimuksessa tarkastellaan työelämän ekonomeille asettamia vaatimuksia tänään ja tulevaisuudessa. Pro graduni tutkimusmenetelmänä käytettiin sähköistä kyselyä, ja otoksena oli 2000 SEFEn jäsenrekisteristä poimittua ekonomia. Tutkimustulokset osoittavat, että heterogeenisen ekonomikunnan näkemykset ammatillisen kehittymisen tarpeista ja varsinkin juuri itselle sopivista koulutusmuodoista eroavat melko paljon. Tärkeimmiksi ekonomiosaamisen osa-alueiksi nousivat seikat, joista on hyötyä muuttuvan maailman mukana pysymisessä, kuten valmius omaksua uusia asioita ja ongelmanratkaisutaito. Seuraavaksi tärkeimmäksi osaamisalueeksi nimettiin yleinen talouden tuntemus. Kehittää tulisi paitsi näitä osa-alueita, myös erilaisia johtamistaitoja. Tulosten mukaan suurin este ammatilliselle lisäkoulutukselle on ajan puute. Kyselyn vastauksissa painotettiin koulutuksesta saatavaa hyötyä suhteessa siihen laitettuihin panostuksiin. Kiireessä priorisoidaan työssä oppimista ja lyhyitä täsmäkoulutuksia.

Ésteres de cloropropanóis e de glicidol em alimentos

Chloropropanols are a well-known group of food processing contaminants. They are formed through the reaction between lipids and chlorides when submitted to thermal treatment, and can be found in free and bound form. Although free chloropropanols were identified around 30 years ago, the occurrence of bound forms, especially 3-MCPD, and glycidyl fatty acid esters, has only recently been reported in several food products. Dietary exposure to these ester-bound compounds has been considered a priority food safety issue since free forms can be potentially released through the action of gut lipases, representing a major toxicological concern.

Química Sem Fronteiras: o desafio da energia

Coal, natural gas and petroleum-based liquid fuels are still the most widely used energy sources in modern society. The current scenario contrasts with the foreseen shortage of petroleum that was spread out in the beginning of the XXI century, when the concept of "energy security" emerged as an urgent agenda to ensure a good balance between energy supply and demand. Much beyond protecting refineries and oil ducts from terrorist attacks, these issues soon developed to a portfolio of measures related to process sustainability, involving at least three fundamental dimensions: (a) the need for technological breakthroughs to improve energy production worldwide; (b) the improvement of energy efficiency in all sectors of modern society; and (c) the increase of the social perception that education is a key-word towards a better use of our energy resources. Together with these technological, economic or social issues, "energy security" is also strongly influenced by environmental issues involving greenhouse gas emissions, loss of biodiversity in environmentally sensitive areas, pollution and poor solid waste management. For these and other reasons, the implementation of more sustainable practices in our currently available industrial facilities and the search for alternative energy sources that could partly replace the fossil fuels became a major priority throughout the world. Regarding fossil fuels, the main technological bottlenecks are related to the exploitation of less accessible petroleum resources such as those in the pre-salt layer, ranging from the proper characterization of these deep-water oil reservoirs, the development of lighter and more efficient equipment for both exploration and exploitation, the optimization of the drilling techniques, the achievement of further improvements in production yields and the establishment of specialized training programs for the technical staff. The production of natural gas from shale is also emerging in several countries but its production in large scale has several problems ranging from the unavoidable environmental impact of shale mining as well as to the bad consequences of its large scale exploitation in the past. The large scale use of coal has similar environmental problems, which are aggravated by difficulties in its proper characterization. Also, the mitigation of harmful gases and particulate matter that are released as a result of combustion is still depending on the development of new gas cleaning technologies including more efficient catalysts to improve its emission profile. On the other hand, biofuels are still struggling to fulfill their role in reducing our high dependence on fossil fuels. Fatty acid alkyl esters (biodiesel) from vegetable oils and ethanol from cane sucrose and corn starch are mature technologies whose market share is partially limited by the availability of their raw materials. For this reason, there has been a great effort to develop "second-generation" technologies to produce methanol, ethanol, butanol, biodiesel, biogas (methane), bio-oils, syngas and synthetic fuels from lower grade renewable feedstocks such as lignocellulosic materials whose consumption would not interfere with the rather sensitive issues of food security. Advanced fermentation processes are envisaged as "third generation" technologies and these are primarily linked to the use of algae feedstocks as well as other organisms that could produce biofuels or simply provide microbial biomass for the processes listed above. Due to the complexity and cost of their production chain, "third generation" technologies usually aim at high value added biofuels such as biojet fuel, biohydrogen and hydrocarbons with a fuel performance similar to diesel or gasoline, situations in which the use of genetically modified organisms is usually required. In general, the main challenges in this field could be summarized as follows: (a) the need for prospecting alternative sources of biomass that are not linked to the food chain; (b) the intensive use of green chemistry principles in our current industrial activities; (c) the development of mature technologies for the production of second and third generation biofuels; (d) the development of safe bioprocesses that are based on environmentally benign microorganisms; (e) the scale-up of potential technologies to a suitable demonstration scale; and (f) the full understanding of the technological and environmental implications of the food vs. fuel debate. On the basis of these, the main objective of this article is to stimulate the discussion and help the decision making regarding "energy security" issues and their challenges for modern society, in such a way to encourage the participation of the Brazilian Chemistry community in the design of a road map for a safer, sustainable and prosper future for our nation.

Irtokappaleiden hallinnan nykytila ja kehittäminen Loviisan voimalaitoksella

Ydinvoimateollisuudessa irtokappaleella tarkoitetaan prosessiin kuulumatonta materiaalia, joka ei luonnostaan kuulu prosessiin ja jolla prosessiin jäädessään voi olla haitallinen vaikutus sen toimintaan, komponentteihin tai kemiaan. Irtokappaleet voivat aiheuttaa monenlaisia haittoja ydinvoimalaitoksen turvalliselle ja taloudelliselle käytölle. Vaikka ydinvoimalaitoksen käytössä turvallisuus on aina etusijalla, negatiiviset vaikutukset turvallisuuteen heijastuvat usein myös talouteen. Diplomityössä arvioitiin erilaisia irtokappaleiden aiheuttamia riskejä ydinvoimalan toiminnalle käyttötapahtumia analysoimalla. Erilaisiin tapahtumiin, niiden aiheuttajiin ja vaikutusmekanismeihin tutustumisen jälkeen tutkittiin Loviisan voimalaitoksen käyttämiä toimintatapoja irtokappaleiden hallitsemiseksi. Irtokappaleiden hallintaan pyritään sekä hallinnollisilla että käytännön menetelmillä. Hallinnollisia menetelmiä ovat esimerkiksi ohjeistojärjestelmä ja johtaminen, käytännön menettelytapoja esimerkiksi työtavat ja koulutus. Irtokappaleiden hallinnan menetelmiin tutustuttiin sekä tehoajolla että vuosihuollon aikana. Nykytilan arvioinnin perusteella esitettiin toimenpide-ehdotuksia irtokappaleiden hallinnan kehittämiseksi. Toimenpide-ehdotukset muodostettiin sekä korjaamaan havaittuja haavoittuvuuksia että kehittämään toimintaa kansainvälisesti hyviksi tunnistettujen käytäntöjen mukaisiksi.

Utilization of Incident Reporting in The Finnish Maritime Industry

Marine traffic is expected to increase rapidly in the future, both in the Baltic Sea and in the Gulf of Finland. As the number of vessels in the area increases, so does the risk of serious marine accidents. To help prevent such accidents in the future, the International Maritime Organization (IMO) has put forth the International Safety Management Code (the ISM Code), which aims to improve the safety of the vessels. The second work package of the Development of maritime safety culture (METKU) project investigates the effects of the ISM Code and potential areas of improvement in maritime safety. The first phase in the work package used a literature review to determine how maritime safety culture could be improved. Continuous improvement, management commitment and personnel empowerment and motivation were found to be essential. In the second phase, shipping companies and administrators were interviewed. It was discovered that especially incident reporting based on continuous improvement was felt to be lacking. This third phase aims to take a closer look at incident reporting and suggest improvements based on the findings. Both the IMO and national legislation encourage shipping companies in incident reporting, and on the national level a shared incident reporting system (ForeSea) is being pushed forward. The objective of this research project was to find out the IMO’s attitude towards incident reporting, to establish a theoretical framework of reference in incident reporting, and to observe how reporting is actually being employed on the seas. Existing incident reporting systems were also researched. The study was carried out using a literature review and the results previously gathered in interviews. The results of phase two were elaborated further for themes relating to incident reporting. According to the findings of this research, the theoretical background of incident reporting dates back to the early 20th century. Although some theories are widely accepted, some have also received criticism. The lack of a concise, shared terminology poses major difficulties in maritime incident reporting and in determining its efficiency. A central finding is the fact that existing incident reporting focuses mostly on information flow away from the ship, whereas the backward information flow is much less planned and monitored. In incident reporting, both nationally and internationally, stakeholders are plenty. The information produced by these parties is scattered, however, and thus not very usable. Based on this research, the centralizing of this information should be made a priority. Traditionally, the success of incident reporting has been determined statistically, from the number of reported incidents. Yet existing reporting systems have not been designed with such statistical analysis in mind, so different methodologies might yield a more comprehensive view. The previous findings of seafarers and management (including shipping companies and administration) having differing views on safety work and safety management were backed up by the results of this study. Seafarers find seamanship and storytelling important, while management wants a more systematic and broad approach on safety matters. The research project was carried out by the Centre for Maritime Studies of the University of Turku, in the Kotka unit (Maritime Logistics Research), with coordination by the Kotka Maritime Research Centre. The major financiers of the project were the European Union and the city of Kotka. The financing authority was the Regional Council of Päijät-Häme. Partners in the project were the shipping companies Finnlines Oyj, Kristina Cruises Oy, Meriaura Oy and VG-Shipping Oy, and the ports of Helsinki, Kotka and Hamina. The partners provided both funding for the project and information for the research.

Tasehallinnan kehittäminen Suomen sähkömarkkinoilla

Tämän diplomityön tavoitteena oli tutkia tasehallinnan kehittämismahdollisuuksia Suomessa järjestelmävastaavan näkökulmasta. Sähköjärjestelmässä tulee vallita jatkuvasti tasapaino tuotannon ja kulutuksen välillä, tämän järjestelmävastaavan vastuulla olevan tasapainon ylläpitoa kutsutaan tehotasapainon hallinnaksi. Työssä pääasiasiallinen huomio oli markkinalähtöisessä tehotasapainon hallinnan kehittämisessä. Tuotantosuunnitelmat ovat ratkaisevassa osassa sähköjärjestelmän muutoksia ennustettaessa ja suunniteltaessa. Pääasiassa tutkimus kohdistuu tuotantosuunnitelmien tarkentamisen mahdollisuuksien analysointiin sekä tarkentamisesta aiheutuvien muutosten selvittämiseen. Työn yhteydessä toteutettiin sopivalla otannalla kyselytutkimus, jonka oli tarkoitus antaa tietoa Eurooppalaisista käytännöistä asian suhteen. Tutkimusten pohjalta päädyttiin malliin, jossa tuotantosuunnitelmien jaksonpituutta lyhennettäisiin nykyisestä 60 minuutista 15 minuuttiin. 15 minuutin jaksonpituus ulottuisi koko tuotantotaseen käsittelyyn, mukaan lukien säätösähkömarkkinat ja muut tehokaupat.

Inferential Rationality and Internalistic Scarecrows

Abstract In a recent paper, Manuel Pérez Otero attempted to turn the tables on Paul Boghossian's claim that content externalism is incompatible with the 'a priority of our logical abilities'. In reply, Boghossian argued that Pérez Otero's criticism misses the main point of his argument through concentrating on the semantics of singular (as opposed to general) terms. I elaborate on Boghossian's reply by showing that even taken on its own terms Pérez Otero's paper fails to engage with internalism through systematically misrepresenting what a truly internalistic account of the semantics of singular terms should be.

Regional innovation strategies and sustainability in selected EU countries

This study focuses on regional innovation strategy (RIS) and sustainability aspects in selected regions of European Union (EU) countries. It is known that RIS helps a region to innovate locally and to compete globally and it is considered as one of the main policy tools of the EU for innovation support at a regional level. This study is conducted to explore the existence and adoption of RIS in different regions of selected EU countries, and to highlight and compare regional RIS characteristics. The study is also aimed at identifying the factors that characterise the formulation and implementation of RIS as well as the problems associated thereof. In this study, six regions of EU countries are considered: Päijät-Häme Region (Finland); London Region (United Kingdom); Mid-West Region (Ireland); Veneto Region (Italy); Eastern Region (Poland); and West Region (Romania). Data and information are collected by sending questionnaires to the respective regional authorities of these selected regions. Based on the gathered information and analysis, RIS or equivalent strategy document serves as a blueprint for forwarding innovative programmes towards regional sustainability. The objectives of RIS in these regions are found to be dependent on the priority sectors and state of the region’s development. The current environmental sustainability aspects are focused on eco-design, eco-products, and eco-innovation, although each region also has its own specific aspects supported by RIS. Likewise, regional policies typically follow the RIS yet translated in various sectoral focus or priority areas. The main enhancing factors supporting RIS among selected regions have some similarities and variations; among others, some regions are strongly supported by EU while others have support from own regional agencies, organisations and professional networks. RIS implementation is not without challenges and despite the differences in challenges, almost all of reviewed regions consider financial resource as a common problem. Generally, it is learned from this study that RIS and regional sustainability are reinforcing each other mutually. In this study, the strong focus is given towards environmental sustainability in the regions although regional sustainability also includes economic and social aspects. A well-focused and prioritised RIS is beneficial for regional sustainable development.

Pankki- ja vakuutustoiminnan asiakaskannattavuus ja asiakkuuksien johtaminen

The main objective of this master’s thesis was to determine, what are the insights, challenges and problems related to differing business logics and principles of income generation and how can they be integrated in a financial group with insurance and banking operations from the perspective of customer profitability. Review of the industrial specific features had a high priority in the study. The study is a qualitative case study with empirical data collected from semi-structured interviews. Qualitative research method was chosen since it produces kind of data required to answer the research questions. Interviewees were chosen from different organizational levels to achieve a comprehensive big picture of the subject. The key result of the study is that the most important factor for the customer profitability on the financial sector is to find and fulfill the customer needs with a comprehensive service package. Also long-term customer relationships were considered significant and customer life cycle assessment essential. In the case-organization the most significant factors in this process were a strong local presence and the tacit knowledge of the customers’ business and activities, although there are major challenges in systematic exploitation of this information. The management of the customer profitability in case-organization faces great challenges because of the history of growth via acquisitions, which has led to so-called “problem of the two balance sheets”, conflict in corporate culture and establishment of the mutual goals and performance measurement.

Suunnittelun mahdollisuudet alumiiniveneen rungon valmistuskustannusten optimointiin mitoitusdirektiivi huomioiden

Tässä diplomityössä tutkittiin valmistuksellisia ja rakenteellisia mahdollisuuksia alumiiniveneen rungon valmistuskustannusten optimointiin vallitseva runkomitoitusdirektiivi huomioiden. Varsinaista kustannussäästötavoitetta työlle ei määritetty, mutta tavoitteena oli selvittää runkokonstruktion kustannusten painopisteiden mukaisesti kehityskohteet ja uusi kehitetty runkokonstruktio, joka täyttää mitoitusdirektiivin vaatimukset. Nykyistä ja kehitettyä runkokonstruktiota verrataan kustannusten sekä valmistettavuuden kannalta ja tehdään johtopäätökset. Kehityskohteiden löytämisessä sovellettiin valmistus- ja kokoonpanoystävällisen suunnittelun DFM(A)-periaatteita ja teoriaa, jotka esiteltiin työn teoriaosuudessa. Valmistuskustannusten määrittämisen tueksi teoriaosuudessa esiteltiin hitsauksen ja osavalmistuksen (laserleikkaus, särmäys) kustannusmallit, joita hyödynnettiin soveltuvin osin kustannuslaskennassa. Merkittävänä osana selvitystyötä oli myös SFS-EN ISO 12215-5-(6) runkomitoitusstandardin tulkitseminen ja referointi työn kannalta merkittäviin osa - alueisiin. Nykyisen runkokonstruktion kustannusanalyysin ja valmistettavuusarvion pohjalta päädyttiin rakenteellisiin ja valmistuksellisiin kehitystoimenpiteisiin, jotka täyttävät runkomitoitusdirektiivin rakenteelliset vaatimukset. Rakenteelliset toimenpiteet käsittivät mm. materiaalivahvuuksien, jäykisterakenteen ja osamäärän optimointia. Valmistukselliset toimenpiteet liittyivät mm. hitsauksen tuottavuuden tehostamiseen ja sen kustannusvaikutuksiin. Rakenteellisilla kehitystoimenpiteillä olisi mahdollista saavuttaa noin 6 % säästö ja valmistusmenetelmien kehittämisellä noin 17 % säästö valmistuskustannuksista.

Some advances in mathematical models for preference relations

Preference relations, and their modeling, have played a crucial role in both social sciences and applied mathematics. A special category of preference relations is represented by cardinal preference relations, which are nothing other than relations which can also take into account the degree of relation. Preference relations play a pivotal role in most of multi criteria decision making methods and in the operational research. This thesis aims at showing some recent advances in their methodology. Actually, there are a number of open issues in this field and the contributions presented in this thesis can be grouped accordingly. The first issue regards the estimation of a weight vector given a preference relation. A new and efficient algorithm for estimating the priority vector of a reciprocal relation, i.e. a special type of preference relation, is going to be presented. The same section contains the proof that twenty methods already proposed in literature lead to unsatisfactory results as they employ a conflicting constraint in their optimization model. The second area of interest concerns consistency evaluation and it is possibly the kernel of the thesis. This thesis contains the proofs that some indices are equivalent and that therefore, some seemingly different formulae, end up leading to the very same result. Moreover, some numerical simulations are presented. The section ends with some consideration of a new method for fairly evaluating consistency. The third matter regards incomplete relations and how to estimate missing comparisons. This section reports a numerical study of the methods already proposed in literature and analyzes their behavior in different situations. The fourth, and last, topic, proposes a way to deal with group decision making by means of connecting preference relations with social network analysis.

Esisuunnitteluohjelmiston kehitys BFB-höyrykattiloille

Tämä diplomityö käsittelee Andritz Oy:n BFB-voimalaitosten tarjoustoimintaan kehitettävää esisuunnitteluohjelmistoa. Tässä työssä on esitelty kattiloiden tarjoustoimintaan liittyviä seikkoja etenkin laskennan ja tekniikan näkökulmasta. Työssä on myös koottu tietoa polttoaineista ja BFB-kattiloiden suunnittelusta ja mitoituksesta. Työn aikana kehitettiin ohjelmisto, jolla on mahdollista luoda eri BFB-kattila tarjousprojekteja. Projekteille on mahdollista luoda useita eri taselaskelmia eri lähtöarvoilla ja useilla eri polttoaineilla, sekä niiden seoksilla. Ohjelmakehityksessä painotettiin suunnittelun joustavuutta eri konfiguraatioille, mahdollisimman tarkkaa laskentaa ja ylläpidon merkitystä. Ohjelmistokehityksessä päätettiin käyttää Microsoft Excel ohjelmistoa laskentaympäristönä. Tällöin pystyttiin luomaan käyttäjille tuttu käyttöympäristö ja mahdollistaa vanhojen hyväksi todettujen laskentapohjien käyttö apuna kehityksessä. Tämä mahdollistaa myös ylläpidon toimialueen ammattilaisten toimesta jatkossa.

Uusien uhkakuvien luominen: tapaus 'kiinalaiset kybersoturit' : lingvistinen uhka-analyysi kyberdiskurssista

Since his inauguration, President Barack Obama has emphasized the need for a new cybersecurity policy, pledging to make it a "national security priority". This is a significant change in security discourse after an eight-year war on terror – a term Obama announced to be no longer in use. After several white papers, reports and the release of the so-called 60-day Cybersecurity Review, Obama announced the creation of a "cyber czar" position and a new military cyber command to coordinate American cyber defence and warfare. China, as an alleged cyber rival, has played an important role in the discourse that introduced the need for the new office and the proposals for changes in legislation. Research conducted before this study suggest the dominance of state-centric enemy descriptions paused briefly after 9/11, but returned soon into threat discourse. The focus on China's cyber activities fits this trend. The aim of this study is to analyze the type of modern threat scenarios through a linguistic case study on the reporting on Chinese hackers. The methodology of this threat analysis is based on the systemic functional language theory, and realizes as an analysis of action and being descriptions (verbs) used by the American authorities. The main sources of data include the Cybersecurity Act 2009, Securing Cyberspace for the 44th Presidency, and 2008 Report to Congress of the U.S. - China Economic and Security Review Commission. Contrary to the prevailing and popularized terrorism discourse, the results show the comeback of Cold War rhetoric as well as the establishment of a state-centric threat perception in cyber discourse. Cyber adversaries are referred to with descriptions of capacity, technological superiority and untrustworthiness, whereas the ‘self’ is described as vulnerable and weak. The threat of cyber attacks is compared to physical attacks on critical military and civilian infrastructure. The authorities and the media form a cycle, in which both sides quote each other and foster each other’s distrust and rhetoric. The white papers present China's cyber army as an existential threat. This leads to cyber discourse turning into a school-book example of a securitization process. The need for security demands action descriptions, which makes new rules and regulations acceptable. Cyber discourse has motives and agendas that are separate from real security discourse: the arms race of the 21st century is about unmanned war.