2060 Chiron back to a minimum of brightness

The results of photometric observations of comet/steroid 2060 Chiron at the Observatorio do Pico dos Dias (Brazil - OPD) and the Observatoire de Haute-Provence (France - OHP) during 1994 and 1995 are presented. The analysis of the data shows a decrease of 2060. Chiron brightness from its peak values of 1988-1991. The absolute magnitude, H-V, varies from a maximum of 6.6 in February 1994 up to a minimum of 6.8 in June 1995. Therefore 2060 Chiron is back to a minimum of activity close to that of 1983-1985. The slope parameter G is found to be G = 0.71 +/- 0.15. It is suggested that the H-G magnitude system, generally adopted to present 2060 Chiron brightness, is not the most appropriate due to the cometary activity of this object. Copyright (C) 1996 Elsevier B.V. Ltd.

Determination of herbicides and a metabolite in human urine by liquid chromatography-electrospray ionization mass spectrometry

A method was developed to determine simazine, atrazine and their metabolite, 2-chloro-4,6-diamino-1,3,5-triazine, in urine. The presence of these herbicides in urine may reflect possible exposure to pesticides. Sample preparation involved protein precipitation and solid-phase extraction. The samples were analyzed by high-performance liquid chromatography-mass spectrometry. The detection limits were 0.4 mug/l and the analytes have a linear response in the interval 6-800 mug/l. The precision of the method was reflected in the RSD of <2.4% for the herbicides studied. Based on the detectable herbicide levels from spiked urine samples collected from unexposed volunteers, this method can be used to determine the low levels necessary for establishing reference values of the selected herbicides and the metabolite. (C) 2002 Elsevier B.V. B.V. All rights reserved.

Sol-gel Er-doped SiO(2)-HfO(2) planar waveguides: A viable system for 1.5 mu m application

70SiO(2)-30HfO(2) planar waveguides, doped with Er(3+) concentrations ranging from 0.3 to 1 mol %, were prepared by sol-gel route, using dip-coating deposition on silica glass substrates. The waveguides show high densification degree, effective intermingling of the two components of the film, and uniform surface morphology. Propagation losses of about 1 dB/cm were measured at 632.8 nm. When pumped with 987 or 514.5 nm continuous-wave laser light, the waveguides show the (4)I(13/2)-->(4)I(15/2) emission band with a bandwidth of 48 nm. The spectral features are found independent both on erbium content and excitation wavelength. The (4)I(13/2) level decay curves presented a single-exponential profile, with a lifetime between 2.9 and 5.0 ms, depending on the erbium concentration. (C) 2002 American Institute of Physics.

Sequence, evolution and ligand binding properties of mammalian Duffy antigen/receptor for chemokines

The Duffy antigen/receptor for chemokine, DARC, acts as a widely expressed promiscuous chemokine receptor and as the erythrocyte receptor for Plasmodium vivax. To gain insight into the evolution and structure/function relations of DARC, we analyzed the binding of anti-human Fy monoclonal antibodies (mAbs) and human chemokines to red blood cells (RBCs) from 11 nonhuman primates and two nonprimate mammals, and we elucidated the structures of the DARC genes from gorilla, gibbon, baboon, marmoset, tamarin, night monkey and cattle. CXCL-8 and CCL-5 chemokine binding analysis indicated that the promiscuous binding profile characteristic of DARC is conserved across species. Among three mAbs that detected the Fy6 epitope by flow cytometric analysis of human and chimpanzee RBCs, only one reacted with night monkey and squirrel monkey. Only chimpanzee RBCs bound a significant amount of the anti-Fy3 mAb. Fy3 was also poorly detected on RBCs from gorilla, baboon and rhesus monkey, but not from new world monkeys. Alignment of DARC homologous sequences allowed us to construct a phylogenetic tree in which all branchings were in accordance with current knowledge of primate phylogeny. Although DARC was expected to be under strong internal and external selection pressure, in order to maintain chemokine binding and avoid Plasmodium vivax binding, respectively, our present study did not provide arguments in favor of a selection pressure on the extracellular domains involved in ligand specificity. The amino acid variability of DARC-like polypeptides was found to be well correlated with the hydrophylicity indexes, with the highest divergence on the amino-terminal extracellular domain. Analysis of the deduced amino acid sequences highlighted the conservation of some amino acid residues, which should prove to be critical for the structural and functional properties of DARC.

Another prefiltering algorithm for adaptive IIR filtering

An algorithm for adaptive IIR filtering that uses prefiltering structure in direct form is presented. This structure has an estimation error that is a linear function of the coefficients. This property greatly simplifies the derivation of gradient-based algorithms. Computer simulations show that the proposed structure improves convergence speed.

Small-scale method for the determination of selected organochlorine pesticides in soil

A small-scale method was developed for the simultaneous determination of γ-HCH, heptachlor, aldrin, dicofol, mirex, endosulfan I, endosulfan II and endosulfan sulphate in soil. The extraction and clean-up steps were combined into one step by transferring soil samples to chromatographic columns prepacked with neutral alumina. The pesticides elution was processed with n-hexane : dichloromethane (7:3) and the concentrated eluate was analysed using gas-liquid chromatography with electron capture detection. Analyses of the in vitro fortified samples with the selected pesticides were performed at three different levels. Mean recoveries for aldrin, γ-HCH and heptachlor, at levels of 2, 10 and 20 ng/g, ranged from 71 to 87%; for dicofol, at levels of 8, 40 and 80 ng/g, ranged from 97 to 103%; for endosulfan I and II, at levels of 5, 25 and 50 ng/g, ranged from 88 to 96%; for mirex, at levels of 6, 30 and 60 ng/g, ranged from 86 to 110%; and for endosulfan sulphate, at levels of 15, 75 and 150 ng/g, ranged from 93 to 104%. The method can be used for rapid determination of these pesticides in soil. © Springer-Verlag 1996.

Efeitos da restrição alimentar no desempenho de bovinos jovens confinados

The objective of the study was to evaluate compensatory weight gain in the performance of young bulls submitted to feed restriction, in the initial phase of confinement and to study the economic viability of the utilization of three protein sources. Sixty six crossbred bulls Simental-Nelore, eight months old and averaging 220 kg of weight were submitted to three feeding programs in the growth phase that lasted 84 days. The feeding programs were ad libitum, restriction + raw soybean grains and restriction + toasted soybean grains, with a restriction level of 25% on average. In the finishing phase, with a 61 day duration, animals fed with each of the three diets mentioned above received two types of supplementary diets: raw soybean grains and poultry litter. There were no differences between final weights of animals in finishing phase, but the bulls submitted to the restriction had more weight gain per day and better food conversion than ad libitum animals, for both raw soybean grains and poultry litter. The conclusion was that the feeding restriction and consequent compensatory weight gain, presented advantages for feeding efficiency, by decreasing maintenance requirements, although final cost had been equivalent to ad libitum animals.

An N2: CH4: H2O DC glow discharge plasma probed by optical and electric techniques: significance to the radiation chemistry of Titan's upper atmosphere in the presence of meteoritic water

This paper presents optical and electrical measurements on plasma generated by DC excited glow discharges in mixtures composed of 95% N2, 4.8% CH4 and 0.2% H2O at pressures varying from 1.064 mbar to 4.0 mbar. The discharges simulate the chemical reactions that may occur in Titan's atmosphere in the presence of meteorites and ice debris coming from Saturn's systems, assisted by cosmic rays and high energy charged particles. The results obtained from actinometric optical emission spectroscopy, combined with the results from a pulsed Langmuir probe, show that chemical species CH, CN, NH and OH are important precursors in the synthesis of the final solid products and that the chemical kinetics is essentially driven by electronic collision processes. It is shown that the presence of water is sufficient to produce complex solid products whose components are important in prebiotic compound synthesis. © 1998 Elsevier Science Ltd. All rights reserved.

Gas-chromatographic determination of deltamethrin in crops

A rapid and economical method is described for the determination of deltamethrin in wheat, rice, peanuts and corn. It is based on simultaneous extraction and clean-up on a column packed with alumina and silica gel using n-hexane-ethyl ether (8:2, v/v), followed by a derivatization step and gas-chromatographic analysis. Recoveries from fortified cereal and peanut samples were determined at four concentration levels and ranged from 73 to 109%. The detection limits were 0.01 to 0.03 mg/ kg. This method simplifies the traditional procedures in terms of sample size, solvent consumption and analysis time. © Springer-Verlag 1998.

Dynamics of some fictitious satellites of Venus and Mars

The dynamics of some fictitious satellites of Venus and Mars are studied considering only solar perturbation and the oblateness of the planet, as disturbing forces. Several numerical integrations of the averaged system, taking different values of the obliquity of ecliptic (a), show the existence of strong chaotic motion, provided that the semi major axis is near a critical value. As a consequence, large increase of eccentricities occur and the satellites may collide with the planet or cross possible internal orbits. Even starting from almost circular and equatorial orbits, most satellites can easily reach prohibitive values. The extension of the chaotic zone depends clearly on the value ε, so that, previous regular regions may become chaotic, provided ε increases sufficiently. © 1999 Elsevier Science Ltd. All rights reserved.

The stability evolution of a family of simply periodic lunar orbits

The present work deals with a family of simply periodic orbits around the Moon in the rotating Earth Moon-particle system. Taking the framework of the planar, circular, restricted three-body problem, we follow the evolution of this family of periodic orbits using the numerical technique of Poincaré surface of section. The maximum amplitude of oscillation about the periodic orbits are determined and can be used as a parameter to measure the degree of stability in the phase space for such orbits. Despite the fact that the whole family of periodic orbits remain stable, there is a dichotomy in the quasi-periodic ones at the Jacobi constant Cj = 2.85. The quasi-periodic orbits with Cj < 2.85 oscillate around the periodic orbits in a different way from those with Cj > 2.85. © 1999 Elsevier Science Ltd. All rights reserved.

Perturbations to Saturn's F-ring strands at their closest approach to Prometheus

The strange morphology of the F ring of Saturn is thought to be caused by the perturbing effects of two close satellites, Prometheus and Pandora. The F ring and the satellites also experience periodic close encounters as a result of differential precession arising from Saturn's oblateness. Using the orbits of the F-ring strands derived by Murray et al. (1997, Icarus 129, 304-316) the behaviour of the ring particles at their closest approach to Prometheus is analysed using numerical simulations. The results show that a gap and a wave are formed in the ring at each encounter with the satellite. However, the gap is expected to have a short lifetime due to keplerian shear. © 2000 Elsevier Science Ltd. All rights reserved.

Analysis of aluminum plates under heating in electrical and natural gas furnaces

This paper analyzes the thermal storage characteristics of aluminum plates in furnaces during their heating for lamination under two sources of heat: an electrical resistance bank and a combustion process carried out with natural gas. The set of equations to model the furnace under operation with electrical energy, for air as the fluid, is presented. This supports the theoretical analysis for the system under operation with natural gas combustion products. A numerical procedure, using the software ANSYS, is applied to determine the convection heat transfer coefficients for heating by the air flow. Temperatures measured in a plate inside a real furnace are used as parameters to determine these coefficients. Then convection and radiation heat transfer coefficients are determined for the natural gas combustion products. Results are compared, indicating a possible gain of 5.5 h in relation to a 19.5 h period of conventional electrical heating per plate.

Application of HPLC-NMR coupling using C30 phase in the separation and identification of flavonoids of taxonomic relevance

The on-line separation and identification of two important taxonomic markers for plant species of the Paepalanthus genus, the flavonoids 6-methoxykaempferol-3-O-β-D-glucopyranoside and 6-methoxykaempferol-3-O-β-D-6″(p-coumaroyl)glucopyranoside, has been performed with an HPLC-NMR coupling using C30 phase. 1D spectra have been recorded in the stopped-flow mode for the two predominant chromatographic peaks. This is the first application of HPLC-NMR coupling using C30 phase to a taxonomic problem. The technique drastically reduces the required amount of sampling for structure determination. © Springer-Verlag 2000.