911 resultados para TOF-SIMS


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Current understanding of rare earth element (REE) geochemistry in the ocean is given in the book. Chemical properties determining REE migration ability in natural processes, sources of REE in the ocean, behavior of REE in river-sea mixing zones, fractionation of dissolved and particulate REE in ocean waters under aerobic and anaerobic conditions, distribution of REE in terrigenous, authigenic, hydrothermal and biogenic sediment components (clay, bone detritus, barite, phillipsite, Fe- and Mn-oxyhydroxides, Fe-Ca hydroxophosphate, diatoms and foraminiferas) are under consideration.

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In this paper allivalites, coarse- and giant-textured olivine-anorthite rocks occurring as separate blocks in the eruption products of many volcanoes from the frontal part of the Kuril-Kamchatka Arc are under consideration. New data are reported on petrography, mineralogy, and composition of melt inclusions in minerals from ten allivalite samples collected at Ksudach, Ilinsky, Zavaritsky, Kudryavy, and Golovnin Volcanoes. Crystallization temperatures of allivalite minerals were estimated as 970-1080°C at melt water content of 3.0-3.5 wt % and oxygen fugacity NNO=1-2. Genetic connection was established between compositions of melt inclusions and interstitial glasses in allivalites and volcanic rocks. Cumulate nature of allivalites was demonstrated. Using mass balance calculations, degree of fractionation of primary melts during formation of cumulate layers was estimated for various volcanoes as 22-46%.

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(Einleitung) Im süddeutschen Jungmoränengebiet wurden während der letzten 25 Jahre verschiedene vegetationsgeschichtliche Arbeiten durchgeführt, die der Untersuchung der Späteiszeit galten. Die wichtigsten von ihnen stammen von G. Lang (1952), A. Bertsch (1961), H. Müller (1962) und H. Schmeidl (1971). Ohne Zweifel müssen die dabei gewonnenen Ergebnisse in anderen Landschaften des nördlichen Alpenvorlandes überprüft und verschiedene Probleme weiterhin verfolgt werden, wie z. B. das der Definition und Umgrenzung der Bölling-Zeit und der Älteren Tundrenzeit s. str. und die Abhängigkeit der Vegetationsentwicklung von der Meereshöhe. Die vorliegende Studie ging auch auf die Notwendigkeit zurück, die spätglazialen Ablagerungen bei dem Tonwerk Kolbermoor nahe Rosenheim, einer der klassischen Stätten der Quartärforschung im nördlichen Alpenvorland, einer vegetationsgeschichtlichen Neubearbeitung zu unterziehen. Die Untersuchungen wurden auf benachbarte Seen, den Sims-See und den Hofsrätter See, ausgedehnt, da die Ergebnisse von Kolbermoor faziell beeinflußt schienen (Niedermoore) und an limnischem Material überprüft werden mußten.

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The (231Pa/230Th)xs,0 records obtained from two cores from the western (MD97-2138; 1°25'S, 146°24'E, 1900 m) and eastern (ODP Leg 138 Site 849, 0°11.59'N, 110°31.18'W, 3851 m) equatorial Pacific display similar variability over the last 85000 years, i.e. from isotopic stages 1 to 5a, with systematically higher values during the Holocene, isotopic stage 3 and isotopic stage 5a, and lower values, approaching the production rate ratio of the two isotopes (0.093), during the colder periods corresponding to isotopic stages 2 and 4. We have also measured the 230Th-normalized biogenic preserved and terrigenous fluxes, as well as major and trace elements concentrations, in both cores. The (231Pa/230Th)xs,0 results combined with the changes in preserved carbonate and opal fluxes at the eastern site indicate lower productivity in the eastern equatorial Pacific during glacial periods. The (231Pa/230Th)xs,0 variations in the western equatorial Pacific (WEP) also seem to be controlled by productivity (carbonate and/or opal). The generally high (231Pa/230Th)xs,0 ratios (>0.093) of the profile could be due to opal and/or MnO2 in the sinking particles. The profiles of (231Pa/230Th)xs,0 and 230Th-normalized fluxes indicate a decrease in exported carbonate, and possibly opal, during isotopic stages 2 and 4 in MD97-2138. Using 230Th-normalized flux, we also show that sediments from the two cores were strongly affected by sediment redistribution by bottom currents suggesting a control of mass accumulation rates by sediment focusing variability.