Stepwise construction of [Os6(CO)18(μ6-P)]-, a hexanuclear osmium cluster monoanion with trigonal-prismatic co-ordination for phosphorus: X-ray crystal structures of [Os6(μ-H)2(CO)20(MeCN)(μ3-PH)] and [PPh3Me][Os6(CO)18(μ6-P)]

Treatment of the labile cluster [Os3(CO)11(MeCN)] with PH3 affords the substituted product [Os3(CO)11(PH3)](1) in high yield. Subsequent reaction of (1) with Na2CO3 in MeOH, followed by acidification, gives the hydrido phosphido cluster [Os3(µ-H)(CO)10(µ-PH2)](2). When (2) is heated to 45–60 °C in the presence of [Os3(CO)11(MeCN)] a hexanuclear complex with the formulation [Os6(µ-H)2(CO)21(µ3-PH)](3) is obtained. If this reaction is repeated using [Os3(CO)10(MeCN)2] instead of [Os3(CO)11(MeCN)], an acetonitrile-containing product, [Os6(µ-H)2(CO)20(MeCN)(µ3-PH)](4), is obtained. An X-ray analysis of (4) shows that two Os3 triangular units are linked by a µ3-phosphinidene ligand, which symmetrically bridges an Os–Os edge of one triangle and is terminally co-ordinated to one Os atom of the second triangle. When (3) is treated with a weak base, such as [N(PPh3)2]Cl or [PPh3Me] Br, deprotonation to the corresponding cluster monoanion [Os6(µ-H)(CO)21(µ3-PH)]–(5) occurs. Treatment of (5) with a weak acid regenerates (3) in quantitative yield. Thermolysis of (3) leads to a closing up of the metal framework, affording the cluster [Os6(µ-H)(CO)18(µ6-P)], which readily deprotonates to give the anion [Os6(CO)18(µ6-P)]–(7) in the presence of [N(PPh3)2] Cl or [PPh3Me]Br. The same anion (7) may also be obtained by direct thermolysis of (5). An X-ray analysis of the [PPh3Me]+ salt of (7) confirms that the phosphorus occupies an interstitial site in a trigonal-prismatic hexaosmium framework, and co-ordinates to all six metal atoms with an average Os–P distance of 2.31 (1)Å. Proton and 31P n.m.r. data on all the new clusters are presented, and the position of the phosphorus resonance in the 31P n.m.r. spectrum is related to the changes in the environment of the phosphorus atom.

En studie av elevers svårigheter i språkinlärning : Problematiken i spanskan på gymnasiet och förslag till lösningar

Detta examensarbetes undersökning har genomförts efter samtal med spansklärare och skolledarepå en gymnasieskola där det upplevs problem med spanska steg 3. Undersökningens syfte är attstudera anledningen till avhopp och till låga betyg i spanska steg 3. Efter att analysera dettaproblem syftar undersökningen till att diskutera möjliga lösningar för att kunna förbättraspanskundervisningen och verksamheten.Frågeställningar examensarbete försöker hitta svar på är tre: Hur svagt är resultatet i spanska steg3 på denna gymnasieskola? Vilka anledningar kan man hitta till det svaga resultatet? Vad kanverksamheten göra för att stödja eleverna i steg 3? Metoden som valts för att hitta svar är attundersöka elevers resultat på olika prov under kursen samt att fokusera på deras innehåll. Detsistnämnda för att kunna hitta möjliga anledningar tillsammans med skolledares och spanskläraresuppfattningar om problemet som inhämtades genom intervjuer på två olika gymnasieskolor.Resultatet visar att flera elever väljer bort kursen och att de som fortsätter sänker sina tidigarebetyg. Bland möjliga faktorer som påverkar det dåliga resultatet kan man nämna dåligaförkunskaper, omotiverade elever och allt svårare grammatiska moment. För att kunna lösaproblemet föreslås kommunikation mellan grundskolan och gymnasieskolan, varierandearbetssätt och lägre krav på form och grammatik bland annat.

Immunotherapy against experimental canine visceral leishmaniasis with the saponin enriched-Leishmune((R)) vaccine

In order to assess the immunotherapeutic potential on canine visceral leishmaniasis of the Leishmune (R) vaccine, formulated with an increased adjuvant concentration (1 mg of saponin rather than 0.5 mg), 24 mongrel dogs were infected with Leishmania (L.) chagasi. The enriched-Leishmune (R) vaccine was injected on month 6, 7 and 8 after infection, when animals were seropositive and symptomatic. The control group were injected with a saline solution. Leishmune (R)-treated dogs showed significantly higher levels of anti-FML IgG antibodies (ANOVA; p < 0.0001), a higher and stable IgG2 and a decreasing IgG I response, pointing to a TH1 T cell mediated response. The vaccine had the following effects: it led to more positive delayed type hypersensitivity reactions against Leishmania lysate in vaccinated dogs (75%) than in controls (50%), to a decreased average of CD4+ Leishmania-specific lymphocytes in saline controls (32.13%) that fell outside the 95% confidence interval of the vaccinees (41.62%, CI95% 43.93-49.80) and an increased average of the clinical scores from the saline controls (17.83) that falls outside the 95% confidence interval for the Leishmune (R) immumotherapy-treated dogs (15.75, CI95% 13.97-17.53). All dogs that received the vaccine were clustered, and showed lower clinical scores and normal CD4+ counts, whereas 42% of the untreated dogs showed very diminished CD4+ and higher clinical score. The increase in clinical signs of the saline treated group was correlated with an increase in anti-FML antibodies (p < 0.0001), the parasitological evidence (p = 0.038) and a decrease in Leishinania-specific CD4+ lymphocyte proportions (p = 0.035). These results confirm the immunotherapeutic potential of the enriched-Leishmune (R) vaccine. The vaccine reduced the clinical symptoms and evidence of parasite, modulating the outcome of the infection and the dog's potential infectiosity to phlebotomines. The enriched-Leishmune (R) vaccine was subjected to a safety analysis and found to be well tolerated and safe. (c) 2007 Elsevier Ltd. All rights reserved.

Effects of fipronil (active ingredient of Frontline (R)) on salivary gland cells of Rhipicephalus sanguineus females (Latreille, 1806) (Acari: Ixodidae)

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Search for Heavy Neutrinos and W-R Bosons with Right-Handed Couplings in a Left-Right Symmetric Model in pp Collisions at root s=7 TeV

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Study of high-p(T) charged particle suppression in PbPb compared to pp collisions at root s(NN)=2.76 TeV

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Development of a low-Reynolds-number k-ω model for FENE-P fluids

A low-Reynolds-number k-ω model for Newtonian fluids has been developed to predict drag reduction of viscoelastic fluids described by the FENE-P model. The model is an extension to viscoelastic fluids of the model for Newtonian fluids developed by Bredberg et al. (Int J Heat Fluid Flow 23:731-743, 2002). The performance of the model was assessed using results from direct numerical simulations for fully developed turbulent channel flow of FENE-P fluids. It should only be used for drag reductions of up to 50 % (low and intermediate drag reductions), because of the limiting assumption of turbulence isotropy leading to an under-prediction of k, but compares favourably with results from k-ε models in the literature based on turbulence isotropy. © 2012 Springer Science+Business Media Dordrecht.

Otimização da aplicação de Fluazifop-P-Butil em pós-emergência na cultura de soja (Glycine max)

The objective of this study was to evaluate the possibility of reducing spray concentration and volume of Fluazifop-p-butyl applications on postemergence soybeans, while maintaining weed control and growth selectivity. The study was conducted in the experimental area of the Teaching and Research Farm of FCAV/Unesp - Jaboticabal Campus, during the agricultural season of 1998/99, carried out on a crop of soybean cultivar FT 2009. The experimental setup utilized was a randomized block design with 24 treatments, 20 following a factorial scheme 2 x 2 x 5 and 4 control treatments. The factors examined were: spray volume (100 and 200 L ha-1); reduced spray concentration - 75.2 and 112.8 g of fluazifop-p-butyl/ha (40 and 60% of the recommended concentration, respectively); and application schedule (5 A.M., 9 A.M., 1 P.M., 5 P.M. and 9 P.M.). The controls were applications at the recommended concentration (188.0 g fluazifop-p-butyl/ha), using volumes of 100 and 200 L ha-1, and treatments without weed control and weeds controlled with manual hoeing. The main species of weeds that emerged in the experimental area were: Cenchrus echinatus, comprising 60% of the infested sections; Digitaria horizontalis, 10%, and Eleusine indica, 30%. All fluazifop-p-butyl applications made up to 9 A.M. and from 5 P.M. effectively controlled the three species of weeds and provided a selective growth of soybeans. Therefore, the use of fluazifop-p-butyl can be optimized by reducing both the concentration and the volume of the spray for applications times providing favorable conditions for crop dusting.

Search for Top Squarks in R-Parity-Violating Supersymmetry Using Three or More Leptons and b-Tagged Jets

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Existence of solutions for a class of degenerate quasilinear elliptic equation in R-N with vanishing potentials

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Positive Solution for a Class of Degenerate Quasilinear Elliptic Equations in R-N

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Search for jet extinction in the inclusive jet-p(T) spectrum from proton-proton collisions at root s=8 TeV

The first search at the LHC for the extinction of QCD jet production is presented, using data collected with the CMS detector corresponding to an integrated luminosity of 10.7 fb-1 of proton-proton collisions at a center-of-mass energy of 8 TeV. The extinction model studied in this analysis is motivated by the search for signatures of strong gravity at the TeV scale (terascale gravity) and assumes the existence of string couplings in the strong-coupling limit. In this limit, the string model predicts the suppression of all high-transverse-momentum standard model processes, including jet production, beyond a certain energy scale. To test this prediction, the measured transverse-momentum spectrum is compared to the theoretical prediction of the standard model. No significant deficit of events is found at high transverse momentum. A 95% confidence level lower limit of 3.3 TeV is set on the extinction mass scale.

Measurement of the ratio of inclusive jet cross sections using the anti-k(T) algorithm with radius parameters R=0.5 and 0.7 in pp collisions at root s=7 TeV

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Evidence for collective multiparticle correlations in p-pb collisions

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Measurement of the W boson helicity in events with a single reconstructed top quark in p p collisions at root s=8 TeV

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)