Direct Nucleophilic Substitution of Free Allylic Alcohols in Water Catalyzed by FeCl3⋅6 H2O: Which is the Real Catalyst?

The allylic substitution reaction, and particularly the direct allylic amination reaction, of free allylic alcohols in water catalyzed by FeCl3⋅6 H2O is described. This novel environmentally-friendly methodology allows the use of a wide variety of nitrogenated nucleophiles such as sulfonamides, carbamates, benzamides, anilines, benzotriazoles, and azides, generally giving good yields of the corresponding substitution products. The synthetic applicability of the process is also demonstrated because the reaction can be performed on gram-scale. Additionally, carbon nucleophiles such as silylated nucleophiles, aromatic compounds, and malonates also proved to be suitable for this transformation. Finally, the nature of the catalytic species present in aqueous media is unveiled, pointing towards the formation of hexaaquo iron(III) complexes.

Modeling the role of fixational eye movements in real-world scenes

Our eyes never remain still. Even when we stare at a fixed point, small involuntary movements take place in our eyes in an imperceptible manner. Researchers agree on the presence of three main contributions to eye movements when we fix the gaze: microsaccades, drifts and tremor. These small movements carry the image across the retina stimulating the photoreceptors and thus avoiding fading. Nowadays it is commonly accepted that these movements can improve the discrimination performance of the retina. In this paper, several retina models with and without fixational eye movements were implemented by mean of RetinaStudio tool to test the feasibility of these models to be incorporated in future neuroprostheses. For this purpose each retina model has been stimulated with natural scene images in two experiments. Results are discussed from the point of view of a neuroprosthesis development.

Building bridges… and properties aplenty: cultural problems in Spanish real estate marketing for prospective British buyers

N.B. reproduced with permission of Peter Lang Verlag. For citation, please, use the original reference, that is Campos Pardillos, M.A. and Balteiro Fernández, I. 2009. “Building bridges… and properties aplenty: cultural problems in Spanish real estate marketing for prospective British buyers”. In: Guillén-Nieto, V., C. Marimón-Llorca and C. Vargas-Sierra. Eds. Intercultural Business Communication and Simulation and Gaming Methodology. Bern: Peter Lang. Pp. 155-174.

Sobre la utilidad, seguridad y suavidad de la inoculación (1779). Discurso de Timoteo O'Scanlan (1726-1795) en la Real Academia de Medicina

Reconocido como una de las figuras clave en la difusión de la inoculación contra la viruela en España, el médico de origen irlandés Timoteo O'Scanlan dejó publicadas 3 obras y numerosos artículos de prensa en los que plasmó su pericia e interés por una práctica que se inició de forma tardía en nuestro país. Aceptado como miembro de la Real Academia Médica de Madrid en noviembre de 1778, leyó su discurso de ingreso en abril de 1779. El texto, que constituye la primera aproximación de O'Scanlan a la inoculación, que venía practicando con éxito desde 1771, fue incluido con algunas modificaciones y sin citar la fecha de redacción en la introducción de su primera obra, Práctica moderna de la inoculación (1784). El manuscrito se encuentra en el Archivo del Conde de Campomanes (Fundación Universitaria Española, Madrid).

Special Tax on Real Estate belonging to Non-resident Corporations in Spain

Análisis del impuesto español sobre bienes inmuebles de no residentes.

A note on the real projection of the zeros of partial sums of Riemann zeta function

This paper proves that the real projection of each simple zero of any partial sum of the Riemann zeta function ζn(s):=∑nk=11ks,n>2 , is an accumulation point of the set {Res : ζ n (s) = 0}.

Flexible Framework for Real-Time Embedded Systems Based on Mobile Cloud Computing Paradigm

The development of applications as well as the services for mobile systems faces a varied range of devices with very heterogeneous capabilities whose response times are difficult to predict. The research described in this work aims to respond to this issue by developing a computational model that formalizes the problem and that defines adjusting computing methods. The described proposal combines imprecise computing strategies with cloud computing paradigms in order to provide flexible implementation frameworks for embedded or mobile devices. As a result, the imprecise computation scheduling method on the workload of the embedded system is the solution to move computing to the cloud according to the priority and response time of the tasks to be executed and hereby be able to meet productivity and quality of desired services. A technique to estimate network delays and to schedule more accurately tasks is illustrated in this paper. An application example in which this technique is experimented in running contexts with heterogeneous work loading for checking the validity of the proposed model is described.

Azudes y acueductos del sistema de riego tradicional de la Vega Baja del Segura (Alicante, España)

En el presente trabajo se describen y analizan las principales obras hidráulicas del sistema de riego tradicional de la comarca de la Vega Baja del Segura, concretamente, los azudes y los acueductos. Los azudes de toma, construidos en el cauce del río Segura, representan el inicio del sistema, desde donde parte una extensa y compleja red de acueductos constituida por acequias y azarbes, como elementos fundamentales, que distribuyen el agua para el regadío. En este estudio se ha llevado a cabo una amplia y profunda investigación documental, tomado datos de campo y captado imágenes in situ que, junto con los diagramas aportados, resultan imprescindibles para comprender la magnitud del sistema. Los resultados obtenidos han servido no sólo para catalogar y caracterizar los elementos que integran el sistema hidráulico del regadío tradicional de la Vega Baja del Segura, sino también para poner de manifiesto un ejemplo real de optimización de recursos hídricos en una zona del sureste peninsular español de escasa e irregular pluviometría. Asimismo, el estudio efectuado revela un sistema de riego sumamente eficiente desde un punto de vista cuantitativo y no tanto desde el cualitativo, debido a la presencia, entre otros contaminantes, de altas concentraciones de sales.

Towards a real-time 3D object recognition pipeline on mobile GPGPU computing platforms using low-cost RGB-D sensors

In this project, we propose the implementation of a 3D object recognition system which will be optimized to operate under demanding time constraints. The system must be robust so that objects can be recognized properly in poor light conditions and cluttered scenes with significant levels of occlusion. An important requirement must be met: the system must exhibit a reasonable performance running on a low power consumption mobile GPU computing platform (NVIDIA Jetson TK1) so that it can be integrated in mobile robotics systems, ambient intelligence or ambient assisted living applications. The acquisition system is based on the use of color and depth (RGB-D) data streams provided by low-cost 3D sensors like Microsoft Kinect or PrimeSense Carmine. The range of algorithms and applications to be implemented and integrated will be quite broad, ranging from the acquisition, outlier removal or filtering of the input data and the segmentation or characterization of regions of interest in the scene to the very object recognition and pose estimation. Furthermore, in order to validate the proposed system, we will create a 3D object dataset. It will be composed by a set of 3D models, reconstructed from common household objects, as well as a handful of test scenes in which those objects appear. The scenes will be characterized by different levels of occlusion, diverse distances from the elements to the sensor and variations on the pose of the target objects. The creation of this dataset implies the additional development of 3D data acquisition and 3D object reconstruction applications. The resulting system has many possible applications, ranging from mobile robot navigation and semantic scene labeling to human-computer interaction (HCI) systems based on visual information.

Aspectos constructivos y decorativos de la villa romana de Puente de la Olmilla (Albaladejo, Ciudad Real)

El esquema constructivo de esta villa responde al modelo típico romano: una serie de estancias distribuidas alrededor de un patio central, que las ilumina y desde el que se accede a ellas mediante los pasillos circundantes, cubiertos con pisos de mosaico, al igual que varias habitaciones (dos de ellas adornadas con mosaicos figurativos). Puente de la Olmilla tenía un pórtico en la fachada, combinación que corresponde a un tipo de construcción poco común en Hispania. Esta villa es un claro testimonio del profundo proceso romanizador sufrido por el medio rural en este territorio. Sin duda, este ámbito de la Meseta Sur tenía para los romanos un carácter estratégico por su privilegiado emplazamiento geográfico dentro de la Península Ibérica y esa fue una de las causas de que lo incluyeran en su red viaria.

Real-time monitoring of electrochemically active biofilm developing behavior on bioanode by using EQCM and ATR/FTIR

In the current study, the relationship between current and biomass and bio-adhesion mechanism of electrogenic biofilm on electrode were investigated using EQCM and ATR-SEIRAS linking electrochemistry. The results indicated that cellular biomass of biofilm on QCM-crystal surface showed maximum value of 6.0 μg/cm2 in initial batch and 11.5 μg/cm2 in the second batch on mature biofilm, producing a similar maximum current density of 110 μA/μg. Especially, the optimum cell biomass linking high electricity production ratio (110 μA/μg) occurred before maximum biomass coming, implying that over-growth mature biofilm is not an optimum state for enhancing power output of MFCs. On the other hand, the spectra using ATR-SEIRAS technique linking electrochemistry obviously exhibited water structure adsorption change at early biofilm formation and meanwhile the water adsorption accompanied the adsorbed bacteria and the bound cells population on the electrode increased with time. Meanwhile, the direct contact of bacteria and electrode via outer-membrane protein can be confirmed via a series spectra shift at amide I and amide II modes and water movement from negative bands displacing by adsorbed bacteria. Our study provided supplementary information about the interaction between the microbes and electrode beyond traditional electrochemistry.

Almonastires y rábitas: espiritualidad islámica individual y defensa colectiva de la comunidad. Espiritualidad y geopolítica en los orígenes de Almonaster la Real

Primeramente se describe el ŷihād, su origen coránico, la escatología asociada y el derecho musulmán asociado al mismo, para acabar explicando cómo el espíritu colectivo y estatal del ŷihād evolucionó hacia la espiritualidad individual del ribāṭ en Al-Andalus. En la segunda parte se enumeran los topónimos al-Munastīr en la península Ibérica, asociados a construcciones eclesiásticas visigodas precedentes, y se explica la geopolítica de Almonaster la Real: en la vía romana que comunicaba Sevilla y Huelva por la montaña onubense con Beja, esta vía de origen romano se usó hasta fin del s. X. La vigilancia en época omeya de este itinerario esencial de comunicación con Portugal dio origen a este “lugar de ribāṭ” que fue Almonaster, fundado sobre restos tardorromanos precedentes.

Construction of 17-19th century domes in the province of Alicante (Spain): the case of San Juan Bautista in Cox

From the late seventeenth to early nineteenth centuries, many religious temples have been built in the province of Alicante (south east of Spain) with brick domes as their main characteristic feature. Often, the limited data available about these remarkable constructions make rehabilitation interventions become into real research projects, with a high value for their historic conservation over time. The aim of this paper is to show a detailed refurbishment analysis of a religious temple built in 1778, showing the need of preservation of historic buildings as a part of the architectural heritage by establishing a common pattern of materials, geometry and constructive systems, specifically in their domes. In most cases, there was not an architectural project for the construction, that is why the analysis of any documentary and archival sources available is essential to find different ways to proceed on the use and maintenance of these religious buildings.

La expresión gráfica del proyecto arquitectónico en la provincia de Alicante. Evolución en documentos de archivo desde finales del siglo XIX hasta la actualidad

Es indiscutible que, desde hace varios siglos, la documentación exigida a la hora de formalizar oficialmente un Proyecto de Arquitectura ha evolucionado constantemente hacia nuevos criterios, bien establecidos por la administración o bien por la sociedad donde se inserta. Una evolución que se ha desarrollado tanto en el ámbito gráfico como en el ámbito documental, incluyendo nueva información a medida que aparecen determinadas normativas, requerimientos o herramientas gráficas. El objetivo del presente trabajo es el estudio de la evolución en la documentación existente en los proyectos arquitectónicos de la provincia de Alicante desde finales del siglo XIX hasta la actualidad. La comprensión y análisis sintético de sus características materiales permitirá discernir las necesidades de generación de documentación gráfica y su materialización según distintas décadas, analizando siete ejemplos de épocas diferentes. Así, el trabajo sintetiza la información existente en varios ejemplos edificatorios, mostrando las transformaciones que han formado parte de los Proyectos de Arquitectura en Alicante en el último siglo.

Dynamical Approach for Real-Time Monitoring of Agricultural Crops

In this paper, a novel approach for exploiting multitemporal remote sensing data focused on real-time monitoring of agricultural crops is presented. The methodology is defined in a dynamical system context using state-space techniques, which enables the possibility of merging past temporal information with an update for each new acquisition. The dynamic system context allows us to exploit classical tools in this domain to perform the estimation of relevant variables. A general methodology is proposed, and a particular instance is defined in this study based on polarimetric radar data to track the phenological stages of a set of crops. A model generation from empirical data through principal component analysis is presented, and an extended Kalman filter is adapted to perform phenological stage estimation. Results employing quad-pol Radarsat-2 data over three different cereals are analyzed. The potential of this methodology to retrieve vegetation variables in real time is shown.