MOCVD生长Al_(0.48)Gao_(0.52)N/Al_(0.54)Ga_(0.36)N多量子阱的结构和光学特性

采用金属有机物化学气相淀积(MOCVD)技术,在蓝宝石衬底上生长了Al_(0.48)Gao_(0.52)N/Al_(0.54)Ga_(0.36)N多量子阱(MQWs)结构.通过双晶X射线衍射(DCXRD)、原子力显微镜(AFM)和阴极荧光(CL)等测试技术,分别对样品的结构和光学特性进行了表征.在DCXRD图谱中,可以观察到明显的MQWs衍射卫星峰,通过拟和,MQWs结构中阱和垒的厚度分别为2.1和9.4 nm,Al组分分别为0.48和0.54.在AFM表面形貌图上,可以观察到清晰的台阶流,表明MQWs获得了二维生长;与此同时,MQWs结构存在一些裂缝,主要原因为AlGaNMQWs结构和下层GaN层间存在很大的应力.CL测试表明,AlGaN MQWs结构的发光波长为295 nm,处于深紫外波段,同时观察到处于蓝光、绿光波段的缺陷发光.

SiO2/Si波导应力双折射数值分析

采用有限元法对SiO2/Si掩埋光波导制备工艺中的应力变化进行了系统的分析,在此基础上,应用有限差分束传播法(FDBPM)对应力光波导的双折射进行了计算.结果表明上包层的玻璃化过程是SiO2/Si波导形成水平方向和垂直方向应力差的主要原因,相应的应力双折射系数B在10-4量级.进一步的分析表明上包层B,P重掺杂可明显减小波导的双折射系数.

科尔沁沙地全新世风沙沉积物的石英单测片蓝光释光测年和风沙活动年代学

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不同类型原油污染土壤生物修复技术研究

对不同类型原油污染土壤在实用规模的预制床上采用堆制技术进行生物修复 .通过投加肥料、菌剂、控制水分和pH ,可使微生物获得较好的生态环境 .当稀油、高凝油、特稠油和稠油污染的土壤中原油总量为 2 5 .8～ 77.2 g·kg-1土时 ,经过近 2个月的运行 ,石油总量的去除率可达 38.37%～ 5 6 .74 % .石油中芳烃、沥青和胶质混合物是制约石油快速降解的主要因素 .在处理过程中筛选出石油降解的优势菌株 ,其中有 6株真菌、6株细菌和 1株放线菌 .研究结果为石油污染土壤异位生物修复技术实用化提供了理论依据 .

抗生素产生菌的自身防卫机制研究

抗生素产生菌的自身防卫机制研究李明祺，吴文芳，张成刚（中国科学院沈阳应用生态研究所，１１００１５）抗生素是在微生物初级代谢过程中，由于特定的分支点受到阻碍而产生的物质，即所谓次级代谢物质。自然界中这种次级代谢物在微生物体内含量少，尚不至于对产生菌构成...

栽培模式、施氮和品种对冬小麦冠层结构和产量的影响

在黄土高原南部半湿润易旱区土垫旱耕人为土上进行大田试验,研究氮肥、品种和栽培模式对冬小麦叶面积指数(LAI)和透光率(DIFN)及产量的影响。结果表明,小麦生长过程中LAI先增大后减小,在开花期最大,成熟期最小,施氮能够显著增加LAI;DIFN的变化规律与LAI相反。不同品种间LAI和DIFN差异显著。全程覆膜和覆膜150 d的LAI极显著大于常规栽培、集雨面栽培和三密一稀栽培模式,DIFN与此相反;施氮后籽粒产量极显著增加。在不同栽培模式下,以全程覆膜、覆膜150 d和集雨面栽培模式的产量较高,但从维持土壤质量角度考虑,则覆膜150 d和集雨面2种栽培模式优于其它几种栽培模式;从冠层结构特征分析,这2种栽培模式更有利于增加群体光合能力。

Sensitive and Selective Determination of Cu2+ by Electrochemiluminescence of CdTe Quantum Dots

For the first time, we report a sensitive and selective method to detect Cu2+ based on the electrochemiluminescence quenching of CdTe quantum dots (QDs) in aqueous solution. The mercaptosuccinic acid (MSA) protected CdTe QDs were prepared and characterized with UV, fluorescence and ECL. The anodic ECL quenching mechanism was attributed to the fact that MSA capping was removed from the surface of the CdTe QDs and preferentially bound with Cu2+. The displacement of MSA capping layer created imperfections on the CdTe QDs surface, and eventually led to the ECL quenching.

Copper phthalocyanine organic thin-film transistors with calcium fluoride gate insulator

We report the fabrication of organic thin-film transistors (OTFTs) with copper phthalocyanine (CuPc) as the semiconductor and calcium fluoride (CaF2) as the gate dielectric on the glass substrate. The fabricated transistors show a gate voltage dependent carrier field effect mobility that ranges from 0.001 to 0.5 cm(2) V-1 s(-1). In the devices, the CaF2 dielectric is formed by thermal evaporation; thus OTFTs with a top-gate structure can be fabricated. This provides a convenient way to produce high-performance OTFTs on a large scale and should be useful for the integration of organic displays.

Nano-reactors for controlling the selectivity of the free radical grafting of maleic anhydride onto polypropylene in the melt

This paper reports on a successful application of the concept of nanoreactors to effectively controlling the selectivity of the free radical grafting of maleic anhydride (MAH) onto polypropylene (PP) in the melt, an industrially relevant process. More specifically, a free radical initiator of type ROOR was first confined into (or encapsulated by) the galleries of an organically modified montmorillonite (o-MMT) whose interdistance was 2.4 nm. Primary free radicals (RO center dot) formed inside the o-MMT galleries had to diffuse out before they could react with the PP backbone. The controlled release of the primary free radicals significantly increased the grafting degree of MAH onto PP and greatly reduced the level of the chain scission of the latter. Those results were better understood by electron spin resonance studies on model systems and by Monte Carlo simulations.

电感耦合等离子体原子发射光谱测定镁-钕合金中稀土和非稀土元素

本文研究了ICP-AES测定Mg-Nd合金样品中10种元素的分析方法。选择了同时测定合金中La、Ce、Pr、Sm、Fe、Al、Mo、Ni、Cu和高含量Nd(20％)的条件。得到了满意结果。

痕量汞分析的现状和展望

本文着重对汞的分离富集、形态分析、测定方法进行了评述,并讨论了汞分析方法的标准化问题。