852 resultados para Critical Point Theory
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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
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The structural evolution in silica sols prepared from tetraethoxysilane (TEOS) sonohydrolysis was studied 'in situ' using small-angle x-ray scattering (SAXS). The structure of the gelling system can be reasonably well described by a correlation function given by gamma(r) similar to (1/R(2))(1/r) exp(- r/xi), where xi is the structure correlation length and R is a chain persistence length, as an analogy to the Ornstein-Zernike theory in describing critical phenomenon. This approach is also expected for the scattering from some linear and branched molecules as polydisperse coils of linear chains and random f-functional branched polycondensates. The characteristic length. grows following an approximate power law with time t as xi similar to t(1) (with the exponent quite close to 1) while R remains undetermined but with a constant value, except at the beginning of the process in which the growth of. is slower and R increases by only about 15% with respect to the value of the initial sol. The structural evolution with time is compatible with an aggregation process by a phase separation by coarsening. The mechanism of growth seems to be faster than those typically observed for pure diffusion controlled cluster-cluster aggregation. This suggests that physical forces (hydrothermal forces) could be actuating together with diffusion in the gelling process of this system. The data apparently do not support a spinodal decomposition mechanism, at least when starting from the initial stable acid sol studied here.
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A subjetividade é a argamassa de toda e qualquer produção e, diante disso, percebemos os processos de subjetivação presentes na feitura dos sujeitos, dos grupos e das instituições. Como ferramentas de análise, tomamos a ideia de dispositivo como um emaranhado de linhas que tecem as relações humanas, e dentre suas diversas linhas destacamos os gêneros como elementos importantes na escuta e intervenção clínica, de modo a ampliar o universo de referência presente nos encontros, no qual os corpos afetam e são afetados dentro de contextos marcados por processos psicossociais, políticos e culturais relevantes para uma prática psi ampliada. Neste trabalho, colocamos em análise a experiência que temos tido como supervisor de estágios em Psicologia Clínica-Institucional que realizamos no Programa Saúde da Família, na Vila Progresso, em Assis, SP, evidenciando a necessidade de diálogos com outros saberes, tais como os estudos culturais, a teoria queer e a esquizoanálise. Como resultados iniciais, percebemos nos relatos de nossos estagiários uma preocupação maior com o cuidado das pessoas atendidas que vão além das leituras psicológicas, que dialoga com questões sociais, econômicas, sexuais, de gênero, políticas e culturais, ampliando as análises e concebendo os seres humanos como híbridos, maquínicos e diferentes, o que evidencia a perspectiva de subjetividades em construção permanente. Surge a necessidade de nos orientarmos pelo viés de uma clínica crítica e ampliada.
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Este artigo apresenta o modelo de referência para estruturar o Seis Sigma, o qual é resultante da incorporação de teorias que contribuem para aumentar o potencial estratégico do Seis Sigma no sentido de incrementar o desempenho organizacional. em sua proposta, o modelo de referência engloba um direcionamento sobre certos requisitos primordiais para o sucesso do programa Seis Sigma. A base teórica de sustentação do modelo de referência foi construída a partir de estudos sobre a influência dos seguintes fatores: orientação estratégica e alinhamento estratégico; medição e gerenciamento do desempenho organizacional; uso de estatística (pensamento estatístico); capacitação/especialização de pessoas; implementação e gerenciamento de projetos; e uso de tecnologia de informação. Complementando a proposição do modelo, o artigo traz evidências empíricas acerca da contribuição dos fatores identificados na formulação do modelo de referência, expondo resultados decorrentes de estudos de caso realizados em quatro subsidiárias brasileiras de multinacionais de grande porte. A análise dos dados forneceu evidências positivas de que os fatores mencionados influenciam de forma efetiva o sucesso e a consolidação do Seis Sigma nas empresas estudadas.
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Monte Carlo simulations are used to assess the adequacy of the Tanford-Kirkwood prescription for electrostatic interactions in macromolecules. Within a continuum dielectric framework, the approach accurately describes salt screening of electrostatic interactions for moderately charged systems consistent with common proteins at physiological conditions. The limitations of the Debye-Huckel theory, which forms the statistical mechanical basis for the Tanford-Kirkwood result, become apparent for highly charged systems. It is shown, both by an analysis of the Debye-Huckel theory and by numerical simulations, that the difference in dielectric permittivity between macromolecule and surrounding solvent does not play a significant role for salt effects if the macromolecule is highly charged. By comparison to experimental data, the continuum dielectric model (combined with either an approximate effective Hamiltonian as in the Tanford-Kirkwood treatment or with exact Monte Carlo simulations) satisfactorily predicts the effects of charge mutation on metal ion binding constants, but only if the macromolecule and solvent are assigned the same or similar permittivities.
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Here we address the problem of bosonizing massive fermions without making expansions in the fermion masses in both massive QED(2) and QED(3) with N fermion flavors including also a Thirring coupling. We start from two-point correlators involving the U(1) fermionic current and the gauge field. From the tensor structure of those correlators we prove that the U(1) current must be identically conserved (topological) in the corresponding bosonized theory in both D=2 and D=3 dimensions. We find an effective generating functional in terms of bosonic fields which reproduces these two-point correlators and from that we obtain a map of the Lagrangian density (ψ) over bar (r)(ipartial derivative-m)psi(r) into a bosonic one in both dimensions. This map is nonlocal but it is independent of the electromagnetic and Thirring couplings, at least in the quadratic approximation for the fermionic determinant.
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We present the critical exponents nu (L2), eta (L2) and gamma (L) for an m-axial Lifshitz point at second order in an epsilon (L) expansion. We introduce a constraint involving the loop momenta along the m-dimensional subspace in order to perform two- and three-loop integrals. The results are valid in the range 0 less than or equal to m less than or equal to d. The case m = 0 corresponds to the usual Ising-like critical behaviour.
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We compute the leading radiative correction to the Casimir force between two parallel plates in the lambdaPhi(4) theory. Dirichlet and periodic boundary conditions are considered. A heuristic approach, in which the Casimir energy is computed as the sum of one-loop corrected zero-point energies, is shown to yield incorrect results, but we show how to amend it. The technique is then used in the case of periodic boundary conditions to construct a perturbative expansion which is free of infrared singularities in the massless limit. In this case we also compute the next-to-leading order radiative correction, which turns out to be proportional to lambda(3/2).
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We contrast four distinct versions of the BCS-Bose statistical crossover theory according to the form assumed for the electron-number equation that accompanies the BCS gap equation. The four versions correspond to explicitly accounting for two-hole-(2h) as well as two-electron-(2e) Cooper pairs (CPs), or both in equal proportions, or only either kind. This follows from a recent generalization of the Bose-Einstein condensation (GBEC) statistical theory that includes not boson-boson interactions but rather 2e- and also (without loss of generality) 2h-CPs interacting with unpaired electrons and holes in a single-band model that is easily converted into a two-band model. The GBEC theory is essentially an extension of the Friedberg-Lee 1989 BEC theory of superconductors that excludes 2h-CPs. It can thus recover, when the numbers of 2h- and 2e-CPs in both BE-condensed and non-condensed states are separately equal, the BCS gap equation for all temperatures and couplings as well as the zero-temperature BCS (rigorous-upper-bound) condensation energy for all couplings. But ignoring either 2h- or 2e-CPs it can do neither. In particular, only half the BCS condensation energy is obtained in the two crossover versions ignoring either kind of CPs. We show how critical temperatures T-c from the original BCS-Bose crossover theory in 2D require unphysically large couplings for the Cooper/BCS model interaction to differ significantly from the T(c)s of ordinary BCS theory (where the number equation is substituted by the assumption that the chemical potential equals the Fermi energy). (c) 2007 Published by Elsevier B.V.
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The paper aims to examine the treatment of lyrical in the aesthetics work of the young Lukacs. In The Soul and the Forms the author examines the poetry of Stefan George, finding on it formal elements that point out to the emergence of a new lyricism. This "significant form" allows the author to introduce an approach of the concept of modernity, in critical and phenomenological bias. Work that will be completed in The theory of Love, when the lyric trend will be exacerbated, contaminating and altering the settings of the other genera.
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In this paper we get some lower bounds for the number of critical periods of families of centers which are perturbations of the linear one. We give a method which lets us prove that there are planar polynomial centers of degree l with at least 2[(l - 2)/2] critical periods as well as study concrete families of potential, reversible and Lienard centers. This last case is studied in more detail and we prove that the number of critical periods obtained with our approach does not. increases with the order of the perturbation. (C) 2007 Elsevier Ltd. All rights reserved.
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A new approach to the experimental determination of the critical temperature of metamagnetic samples with non-zero demagnetizing factors is presented. The method is applied to metamagnetic Ni(NO3)2·2H2O, allowing the conclusion that this salt exhibits a tricritical point. Pressure dependence of the critical temperature, and the existence of a pressure-induced metamagnetic transition are also reported. © 1986.
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We compute correlation functions in N=2 non-critical superstrings on the sphere. Our calculations are restrained to the (s=0) bulk amplitudes. We show that the four-point function factorizes as a consequence of the non-critical kinematics, but differently from the N=0, 1 cases no extra discrete state appears in the ĉ→1- limit.
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We calculate three- and four-point functions in super Liouville theory coupled to a super Coulomb gas on world sheets with spherical topology. We first integrate over the zero mode and assume that a parameter takes an integer value. We find the amplitudes, give plausibility arguments in favor of the result, and formally continue the parameter to an arbitrary real number. Remarkably the result is completely parallel to the bosonic case.