Raideliikenteen opastimien valoyksiköiden koteloiden tuotekehitys

Nykyisin raideliikenteen käytössä olevan opastinjärjestelmän mukaiset opastimet ovat kunnossapidollisesti erittäin haastavia. Niiden korkeus aiheuttaa kunnossapitohenkilöstölle työturvallisuusriskin ja monimutkaiset opastinulokkeet ja - portaalit ovat kalliita rakentaa. Nykyisin käytössä oleva opastinjärjestelmä onkin tarkoitus korvata Opastinjärjestelmä 2010 -nimisellä järjestelmällä, jonka kehitystyö on aloitettu Ratahallintokeskuksessa vuonna 2006. Tämä diplomityö on osa kyseistä kehitystyötä. Työn tarkoituksena on raideliikenteen käyttöön tulevien Opastinjärjestelmä 2010:n mukaisten opastimien valoyksiköiden koteloiden rakenteen suunnittelu ja materiaalinvalinta. Suunnittelutyöhön sisältyvät myös valoyksiköiden häikäisysuojien suunnittelu, sekä opastimien koteloiden liittäminen opastimien jalkoihin. Uusille opastimille suunnitellaan myös putkipaaluperustus. Opastinjärjestelmä 2010:n mukaisten opastimien myötä opastinten sijoittelua voidaan parantaa, ja niiden kunnossapito helpottuu. Uuden järjestelmän opastimien kotelot tarjoavat opastimien valoyksiköille entistä avointa levyrakennetta paremman ilkivaltasuojan. Uusissa opastimissa otetaan käyttöön LED-valoyksiköt, joka vähentää kunnossapitokustannuksia lamppujen vaihtotarpeen pienentyessä.

Www-sovelluskehysten arviointi ja valinta

Useimmiten www-sovellusten käyttöliittymien rakentamiseen käytetään ohjelmistokehyksiä. Www-sovelluskehys voidaan valita lukuisista valmiista vaihtoehdoista. Valinta on kuitenkin ongelmallista. Vaikka hyviä vaihtoehtoja on paljon, www-sovelluskehykset ovat parhaimmillaan vain tietyissä tilanteissa. Tämän työn tavoitteena oli löytää keino vertailla www-sovelluskehyksiä. Menetelmän haluttiin olevan kustannustehokas. Työssä hyödynnettiin kirjallisuudesta löytyviä ohjeita ohjelmistokomponenttien ja työkalujen valintaan. Ohjeiden avulla valittiin www-sovelluskehyksien vertailuun sopivia arviointikriteerejä. Arviointikriteerien määrittelyä varten tutkittiin ohjelmistokehysten ja www-sovelluskehysten vaatimuksia. Ohjeiden avulla suoritettiin myös vertailu käytännössä. Työn tuloksena syntyneitä www-sovelluskehysten vaatimuksia ja arviointikriteerejä voidaan käyttää suoraan vertailuissa alustasta riippumatta. Tulosten avulla voidaan vähentää www-sovelluskehysten valintaan tarvittavan työn määrää. Työhön sisältyneen vertailun suorittamiseen kului kohtuullinen määrä aikaa, ja sillä kyettiin tunnistamaan eroja www-sovelluskehysten välillä.

Validação lateral em relações quantitativas entre estrutura e atividade farmacológica, QSAR

The comparative QSAR is a tool for validating any statistical model that seems to be reasonable in describing an interaction between a bioactive new chemical entity, BIONCE, and the biological system. In order to deeper the understanding of the relationships and the meaning of parameters within the model it is necessary some kind of lateral validation. This validation can be accomplished by chemical procedures using physicochemical organic reactions and by means of biological systems. In this paper we review some of such comparisons and also present a lateral validation between the same set of antimicrobial hydrazides acting against Saccharomyces cerevisiae yeast and Escherichia coli bacterium cells. QSARs are presented to shed light in this important way of stating that the QSAR model is not the endpoint, but the beginning.

Akku ja vetypolttokenno sähköauton voimanlähteenä

Tässä kandidaatintyössä on käsitelty akkuja ja vetypolttokennoja sähköauton voimanlähteenä. Työssä on esitelty sähköautojen ja niiden voimanlähteiden teknologioiden periaatteita, energiankantajia, hyötysuhteita ja päästöjä. Lisäksi on tarkasteltu polttomoottorikäyttöisiä autotekniikoita vertailukohdan saamiseksi. Työn lopuksi on analysoitu sähköautojen markkinoita ja niiden yleistymiseen vaikuttavia tekijöitä. Sähköautot mahdollistavat vaihtoehtoisten energialähteiden käytön, joka antaa tilaisuuden saasteiden ja päästöjen keskitettyyn vähentämiseen ja talteenottoon. Niiden avulla päästään myös pois öljyriippuvuudesta ja paikallisesti aiheutuneista päästöistä. Nykyisten polttoaineiden helpon käsiteltävyyden, kohtuullisien energiatiheyksien ja laajojen infrastruktuurien vuoksi käytössä olevien tekniikoiden syrjäyttäminen on vaikeaa. Uusien tekniikoiden etuja ja haittoja voidaan tarkastella yksinkertaisilla metodeilla, kuten kustannusten, hyötysuhteiden, päästöjen ja polttoaineiden elinkaarien vertailulla. Vertailua vaikeuttaa tosin hintatasojen ja verotuksen eroavaisuudet eri maissa, ja se on siksi suoritettava osin maakohtaisesti. Suurimpia esteitä uusille tekniikoille ovat tällä hetkellä niiden tuomat lisäkustannukset, infrastruktuurien puuttuminen ja nykyisten polttoaineiden korvaaminen toisella.

Lipossomas: a bala mágica acertou?

Efficient drug delivery systems are as important as drug themselves. A powerful drug unable to reach the target cell is useless in practice. Ehrlich's Magic Bullet was the first carrier system to be proposed. The evolution in this domain has been quite slow as the natural mechanisms of mammals against foreign products are hard to overcome. However, lipid-based systems (liposomes and related vesicles) have attained reasonable success. The basic preparations and structural features of liposomes and related vesicles as well as their applications are addressed from the chemist's and biochemist's point of view.

Scale-up model obtained from the rheological analysis of highly concentrated emulsions prepared at three scales

We examine the scale invariants in the preparation of highly concentrated w/o emulsions at different scales and in varying conditions. The emulsions are characterized using rheological parameters, owing to their highly elastic behavior. We first construct and validate empirical models to describe the rheological properties. These models yield a reasonable prediction of experimental data. We then build an empirical scale-up model, to predict the preparation and composition conditions that have to be kept constant at each scale to prepare the same emulsion. For this purpose, three preparation scales with geometric similarity are used. The parameter N¿D^α, as a function of the stirring rate N, the scale (D, impeller diameter) and the exponent α (calculated empirically from the regression of all the experiments in the three scales), is defined as the scale invariant that needs to be optimized, once the dispersed phase of the emulsion, the surfactant concentration, and the dispersed phase addition time are set. As far as we know, no other study has obtained a scale invariant factor N¿Dα for the preparation of highly concentrated emulsions prepared at three different scales, which covers all three scales, different addition times and surfactant concentrations. The power law exponent obtained seems to indicate that the scale-up criterion for this system is the power input per unit volume (P/V).

Development a distributed simulation environment on a cluster of workstations

Simulation has traditionally been used for analyzing the behavior of complex real world problems. Even though only some features of the problems are considered, simulation time tends to become quite high even for common simulation problems. Parallel and distributed simulation is a viable technique for accelerating the simulations. The success of parallel simulation depends heavily on the combination of the simulation application, algorithm and message population in the simulation is sufficient, no additional delay is caused by this environment. In this thesis a conservative, parallel simulation algorithm is applied to the simulation of a cellular network application in a distributed workstation environment. This thesis presents a distributed simulation environment, Diworse, which is based on the use of networked workstations. The distributed environment is considered especially hard for conservative simulation algorithms due to the high cost of communication. In this thesis, however, the distributed environment is shown to be a viable alternative if the amount of communication is kept reasonable. Novel ideas of multiple message simulation and channel reduction enable efficient use of this environment for the simulation of a cellular network application. The distribution of the simulation is based on a modification of the well known Chandy-Misra deadlock avoidance algorithm with null messages. The basic Chandy Misra algorithm is modified by using the null message cancellation and multiple message simulation techniques. The modifications reduce the amount of null messages and the time required for their execution, thus reducing the simulation time required. The null message cancellation technique reduces the processing time of null messages as the arriving null message cancels other non processed null messages. The multiple message simulation forms groups of messages as it simulates several messages before it releases the new created messages. If the message population in the simulation is suffiecient, no additional delay is caused by this operation A new technique for considering the simulation application is also presented. The performance is improved by establishing a neighborhood for the simulation elements. The neighborhood concept is based on a channel reduction technique, where the properties of the application exclusively determine which connections are necessary when a certain accuracy for simulation results is required. Distributed simulation is also analyzed in order to find out the effect of the different elements in the implemented simulation environment. This analysis is performed by using critical path analysis. Critical path analysis allows determination of a lower bound for the simulation time. In this thesis critical times are computed for sequential and parallel traces. The analysis based on sequential traces reveals the parallel properties of the application whereas the analysis based on parallel traces reveals the properties of the environment and the distribution.

Käytöntukijärjestelmän toiminnoista saatavat hyödyt ja niiden analysointi

Käytöntukijärjestelmä on ohjelmistokokonaisuus, jota käytetään käyttötoiminnan päätöksenteon tukena useissa verkkoyhtiöissä. Järjestelmä sisältää useita erilaisia sovelluksia, joiden käytön perustana on käytöntukijärjestelmään integroituneiden tietojärjestelmien tietojen hyödyntäminen. Tässä diplomityössä tutkitaan käytöntukijärjestelmän eri toimintoja ja analysoidaan niistä saatavia hyötyjä. Hyötyjen suuruuteen vaikuttaa merkittävästi verkon laajuus, automaatioaste sekä käyttöhenkilökunnan koulutustaso. Lopputuloksena verrataan käytöntukijärjestelmästä saatavaa maksimaalista hyötyä keskeytyskustannuksissa, järjestelmän käyttöönotosta aiheutuviin kustannuksiin. Lisäksi työssä arvioidaan verkkoyhtiön laajuudesta riippuen, onko sen järkevää hankkia käytöntukijärjestelmää ostamalla se itse, palveluntarjoajan kautta tai ei ollenkaan.

Heat transfer in superheaters of the bubbling fluidized bed boiler conversions

It is often reasonable to convert old boiler to bubbling fluidized bed boiler instead of building a new one. Converted boiler consists of old and new heat surfaces which must be fitted to operate together. Prediction of heat transfer in not so ideal conditions sets challenges for designers. Two converted boilers situated in Poland were studied on the grounds of acceptance tests and further studies. Calculation of boiler process was performed with boiler design program. Main interest was heat transfer in superheaters and factors affecting it. Theory for heat transfer is presented according to information found from literature. Results obtained from experimental studies and calculations have been compared. With correct definitions calculated parameters corresponded well to measured data at boiler maximum design load. However overload situations revealed to be difficult to model at least without considering changes in the combustion process which requires readjustments to the design program input values.

Determining risk potential through accidents and near-accidents: an empirical study in a steel factory

Fatal and permanently disabling accidents form only one per I cent of all occupational accidents but in many branches of industry they account for more than half the accident costs. Furthermore the human suffering of the victim and his family is greater in severe accidents than in slight ones. For both human and economic reasons the severe accident risks should be identified befor injuries occur. It is for this purpose that different safety analysis methods have been developed . This study shows two new possible approaches to the problem.. The first is the hypothesis that it is possible to estimate the potential severity of accidents independent of the actual severity. The second is the hypothesis that when workers are also asked to report near accidents, they are particularly prone to report potentially severe near accidents on the basis of their own subjective risk assessment. A field study was carried out in a steel factory. The results supported both the hypotheses. The reliability and the validity of post incident estimates of an accident's potential severity were reasonable. About 10 % of accidents were estimated to be potentially critical; they could have led to death or very severe permanent disability. Reported near accidents were significantly more severe, about 60 $ of them were estimated to be critical. Furthermore the validity of workers subjective risk assessment, manifested in the near accident reports, proved to be reasonable. The studied new methods require further development and testing. They could be used both in routine usage in work places and in research for identifying and setting the priorities of accident risks.

Models for the estimation of thermodynamic properties of layered double hydroxides: application to the study of their anion exchange characteristics

Several models for the estimation of thermodynamic properties of layered double hydroxides (LDHs) are presented. The predicted thermodynamic quantities calculated by the proposed models agree with experimental thermodynamic data. A thermodynamic study of the anion exchange process on LDHs is also made using the described models. Tables for the prediction of monovalent anion exchange selectivities on LDHs are provided. Reasonable agreement is found between the predicted and the experimental monovalent anion exchange selectivities.

Análise química de sais de cobre fabricados entre 1877 e 1995

Samples of copper compounds covering all of the XXth century and the end of the XIXth century were submitted to classical and instrumental quantitative analysis. The amount of impurities greatly decreased with time, reaching a constant level since the 1960's. The gravimetric method was suitable for the determination of copper although other procedures also gave good or reasonable results. However, for metal contaminants, atomic absorption spectrometry was the best choice because of its lower detection limits, being able to determine several elements in the oldest samples. Ion chromatography detected several anions in copper salts manufactured before the 1950's. An increasing quality of raw materials and a better sensitivity of analytical methods led to quality improvement of copper compounds with time.

20 Myr of eccentricity paced lacustrine cycles in the Cenozoic Ebro Basin

Long-period orbital forcing is a crucial component of the major global climate shifts during the Cenozoic as revealed in marine pelagic records. A complementary regional perspective of climate change can be assessed from internally drained lake basins, which are directly affected by insolation and precipitation balance. The Ebro Basin in northeastern Iberia embraces a 20 Myr long continuous sedimentary record where recurrent expansions and retractions of the central lacustrine system suggest periodic shifts of water balance due to orbital oscillations. In order to test climatic (orbital) forcing a key-piece of the basin, the Los Monegros lacustrine system, has been analyzed in detail. The cyclostratigraphic analysis points to orbital eccentricity as pacemaker of short to long-term lacustrine sequences, and reveals a correlation of maxima of the 100-kyr, 400-kyr and 2.4-Myr eccentricity cycles with periods of lake expansion. A magnetostratigraphy-based chronostratigraphy of the complete continental record allows further assessing long-period orbital forcing at basin scale, a view that challenges alternate scenarios where the stratigraphic architecture in foreland systems is preferably associated to tectonic processes. We conclude that while the location of lacustrine depocenters reacted to the long-term tectonic-driven accommodation changes, shorter wavelenght oscillations of lake environments, still million-year scale, claims for a dominance of orbital forcing. We suggest a decoupling between (tectonic) supply-driven clastic sequences fed from basin margins and (climatic) base level-driven lacustrine sequences in active settings with medium to large sediment transfer systems.

Parâmetros termodinâmicos da reação de adsorção de boro em solos tropicais altamente intemperizados

The driving force of boron adsorption on some tropical soils was evaluated by means of thermodynamic parameters. The batch method was employed, and the reaction was monitored at different pH values. The Langmuir equation successfully fitted the experimental results and provided reasonable isotherm parameters. Boron adsorption increased as a function of the pH of the soil solution and the concentration of added boron. The reaction was favorable and proceeded spontaneously, being strongly exoergic, as indicated by a negative free energy (deltaG) and a separation factor (K R) < 1. The boron adsorption phenomenon and the soil-solution interface were thermodinamically described using a theoretical model.

Methods for assessing the sustainability of integrated municipal waste management and

The general striving to bring down the number of municipal landfills and to increase the reuse and recycling of waste-derived materials across the EU supports the debates concerning the feasibility and rationality of waste management systems. Substantial decrease in the volume and mass of landfill-disposed waste flows can be achieved by directing suitable waste fractions to energy recovery. Global fossil energy supplies are becoming more and more valuable and expensive energy sources for the mankind, and efforts to save fossil fuels have been made. Waste-derived fuels offer one potential partial solution to two different problems. First, waste that cannot be feasibly re-used or recycled is utilized in the energy conversion process according to EU’s Waste Hierarchy. Second, fossil fuels can be saved for other purposes than energy, mainly as transport fuels. This thesis presents the principles of assessing the most sustainable system solution for an integrated municipal waste management and energy system. The assessment process includes: · formation of a SISMan (Simple Integrated System Management) model of an integrated system including mass, energy and financial flows, and · formation of a MEFLO (Mass, Energy, Financial, Legislational, Other decisionsupport data) decision matrix according to the selected decision criteria, including essential and optional decision criteria. The methods are described and theoretical examples of the utilization of the methods are presented in the thesis. The assessment process involves the selection of different system alternatives (process alternatives for treatment of different waste fractions) and comparison between the alternatives. The first of the two novelty values of the utilization of the presented methods is the perspective selected for the formation of the SISMan model. Normally waste management and energy systems are operated separately according to the targets and principles set for each system. In the thesis the waste management and energy supply systems are considered as one larger integrated system with one primary target of serving the customers, i.e. citizens, as efficiently as possible in the spirit of sustainable development, including the following requirements: · reasonable overall costs, including waste management costs and energy costs; · minimum environmental burdens caused by the integrated waste management and energy system, taking into account the requirement above; and · social acceptance of the selected waste treatment and energy production methods. The integrated waste management and energy system is described by forming a SISMan model including three different flows of the system: energy, mass and financial flows. By defining the three types of flows for an integrated system, the selected factor results needed in the decision-making process of the selection of waste management treatment processes for different waste fractions can be calculated. The model and its results form a transparent description of the integrated system under discussion. The MEFLO decision matrix has been formed from the results of the SISMan model, combined with additional data, including e.g. environmental restrictions and regional aspects. System alternatives which do not meet the requirements set by legislation can be deleted from the comparisons before any closer numerical considerations. The second novelty value of this thesis is the three-level ranking method for combining the factor results of the MEFLO decision matrix. As a result of the MEFLO decision matrix, a transparent ranking of different system alternatives, including selection of treatment processes for different waste fractions, is achieved. SISMan and MEFLO are methods meant to be utilized in municipal decision-making processes concerning waste management and energy supply as simple, transparent and easyto- understand tools. The methods can be utilized in the assessment of existing systems, and particularly in the planning processes of future regional integrated systems. The principles of SISMan and MEFLO can be utilized also in other environments, where synergies of integrating two (or more) systems can be obtained. The SISMan flow model and the MEFLO decision matrix can be formed with or without any applicable commercial or free-of-charge tool/software. SISMan and MEFLO are not bound to any libraries or data-bases including process information, such as different emission data libraries utilized in life cycle assessments.