Estabilidade, desempenho e observação de estado de sistemas chaveados afins: aplicações aos conversores CC-CC

Pós-graduação em Engenharia Elétrica - FEIS

Caracterização de polímeros unidimensionais (Poliacetileno, Poliazina e Poliazoeteno) através de cálculos espectroscópicos e transporte eletrônico

Neste trabalho é apresentado um estudo teórico da base neutro e bipolaron e estados excitados de moléculas a partir de polímeros isoeletrônicos compostos pelo Poliacetileno, Poliazina e Poliazoeteno. Os resultados obtidos, utilizando metodologia DFT e ab initio, revelam que uma boa descrição dos defeitos pode ser importante na investigação da transição isolante-metal de polímeros quase-unidimensional indicando um comportamento metálico em torno do nível de Fermi, como mecanismo de condutividade dos polímeros. Este resultado é consistente com dados experimentais e não faz menção a metodologia Su-Schrieffer-Heeger (SSH). E mais, os resultados são consistentes com características importantes como nanodispositivo e podem ser resumidos como: (i) poderia ser usado como retificador molecular uni-direcional com uma geometria conformacional com vantagem de pequeno acoplamento, (ii) a função de Green de não-equilíbrio presente na simulação poderia corrigir de tal maneira os Poliacetileno, Poliazina e Poliazoeteno sem corrente de porta, (iii) com base nas propriedades das ligações tipo, pode ser utilizada para projetar dispositivos com aplicações em eletrônica molecular.

Bright solitons in a quasi-one-dimensional dipolar Bose-Einstein condensate

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Amphiphilic planar membranes in ionic equilibrium: a study of pH position-dependent values

The pH values near a planar dissociating membrane are studied under a mean field approximation using the Poisson-Boltzmann equation and its linear form. The equations are solved in planar symmetry with the consideration that the charge density on the dissociating membrane surface results from an equilibrium process with the neighboring electrolyte. Results for the membrane dissociation degree are presented as a function of the electrolyte ionic strength and membrane surface charge density. Our calculations indicate that pH values have an appreciable variation within 2 nm from the membrane. It is shown that the dissociation process is enhanced due to the presence of bivalent ions and that pH values acquire better stability than in an electrolyte containing univalent ions.

Semi-analytical study of the rotational motion stability of artificial satellites using quaternions

This study at aims performing the stability analysis of the rotational motion to artificial satellites using quaternions to describe the satellite attitude (orientation on the space). In the system of rotational motion equations, which is composed by four kinematic equations of the quaternions and by the three Euler equations in terms of the rotational spin components. The influence of the gravity gradient and the direct solar radiation pressure torques have been considered. Equilibrium points were obtained through numerical simulations using the softwares Matlab and Octave, which are then analyzed by the Routh-Hurwitz Stability Criterion.

Development and Validation of A Stability-Indicating Mekc Method for Determination of Flucloxacillin Sodium in Capsules

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Markovian versus non-Markovian stochastic quantization of a complex-action model

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Propiedades Eléctricas en Membranas de Complejos Electrolitos Poliméricos PVA-OH/LI2SO4/PEG400

Lithium ion conducting polymer electrolytes based on polyvinyl Alcohol (PVA-OH) complexed with salt Li2SO4 and different weight percent ratios of PEG(400) plasticizer have been prepared by solution cast technique using deionized water as solvent. The thermogravimetric analysis (TGA) showed that the thermal stability of the materials depended on the plasticizer content. The FTIR study confirmed the polymer salt complex formation. The modulus spectra indicated the non-Debye nature of the material; a dominant relaxation process is visible being associated with the dynamic glass transition, relaxation-a. The maximum of each peak is shifted to higher frequencies as the plasticizer increases due to an enhancement of dipolar mobility in the origin of cooperative motions. A power law frequency dependence of the real part of the electrical conductivity is observed, which is characteristic of the effects of ion-ion and/or ion-chain correlations in ion motion. This variation is well fitted to a Jonscher's expression.

Cetyltrimethylammonium chloride (CTAC) effect on the thermal stability of oxy-HbGp: Dynamic light scattering (DLS) and small angle X-ray scattering (SAXS) studies

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Control of instabilities in non-Newtonian free surface fluid flows

Free surface flows in inclined channels can develop periodic instabilities that are propagated downstream as shock waves with well-defined wavelengths and amplitudes. Such disturbances are called roll waves and are common in channels, torrential lava, landslides, and avalanches. The prediction and detection of such waves over certain types of structures and environments are useful for the prevention of natural risks. In this work, a mathematical model is established using a theoretical approach based on Cauchy's equations with the Herschel-Bulkley rheological model inserted into the viscous part of the stress tensor. This arrangement can adequately represent the behavior of muddy fluids, such as water-clay mixture. Then, taking into account the shallow water and the Rankine-Hugoniot's (shock wave) conditions, the equation of the roll wave and its properties, profile, and propagation velocity are determined. A linear stability analysis is performed with an emphasis on determining the condition that allows the generation of such instabilities, which depends on the minimum Froude number. A sensitivity analysis on the numerical parameters is performed, and numerical results including the influence of the Froude number, the index flow and dimensionless yield stress on the amplitude, the wavelength of roll waves and the propagation velocity of roll waves are shown. We show that our numerical results were in agreement with Coussot's experimental results (1994).

Non-perturbative fixed points and renormalization group improved effective potential

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Long-term dynamics of Methone, Anthe and Pallene

We numerically investigate the long-term dynamics of the Saturn's small satellites Methone (S/2004 S1), Anthe (S/2007 S4) and Pallene (S/2004 S2). In our numerical integrations, these satellites are disturbed by non-spherical shape of Saturn and the six nearest regular satellites. The stability of the small bodies is studied here by analyzing long-term evolution of their orbital elements.We show that long-term evolution of Pallene is dictated by a quasi secular resonance involving the ascending nodes (12) and longitudes of pericentric distances (pi) of Mimas (subscript 1) and Pallene (subscript 2), which critical argument is pi(2) - pi(1) - Omega(1) + Omega(2) Long-term orbital evolution of Methone and Anthe are probably chaotic since: i) their orbits randomly cross the orbit of Mimas in time scales of thousands years); ii) long-term numerical simulations involving both small satellites are strongly affected by small changes in the initial conditions.

Estudo das propriedades dinâmicas e sincronização no mapa de rede de Zaslavsky

Synchronization in nonlinear dynamical systems, especially in chaotic systems, is field of research in several areas of knowledge, such as Mechanical Engineering and Electrical Engineering, Biology, Physics, among others. In simple terms, two systems are synchronized if after a certain time, they have similar behavior or occurring at the same time. The sound and image in a film is an example of this phenomenon in our daily lives. The studies of synchronization include studies of continuous dynamic systems, governed by differential equations or studies of discrete time dynamical systems, also called maps. Maps correspond, in general, discretizations of differential equations and are widely used to model physical systems, mainly due to its ease of computational. It is enough to make iterations from given initial conditions for knowing the trajectories of system. This completion of course work based on the study of the map called ”Zaslavksy Web Map”. The Zaslavksy Web Map is a result of the combination of the movements of a particle in a constant magnetic field and a wave electrostatic propagating perpendicular to the magnetic field. Apart from interest in the particularities of this map, there was objective the deepening of concepts of nonlinear dynamics, as equilibrium points, linear stability, stability non-linear, bifurcation and chaos

Geometric singular perturbartion theory for non-smooth dynamical systems

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Estudo preliminar do potencial de alguns asteroides

A survey we conducted, and bring expressed in this text is a preliminary study on the shape of asteroids and allowed us to understand a little more the dynamics around these bodies, in order that the images we have of asteroids are the most irregular possible. In this work, the asteroid is modeled by the method of the polyhedron, which provides a very good accuracy of the irregular shape of the body. Through study of models for non-spherical gravitational potential bodies, implementation of computational algorithms and numerical simulations a preliminary analysis was performed in relation to the shape of asteroids 4179 Toutatis, 6489 Golevka, 2063 Bacchus, 1620 Geographos and 1998 ML14, as well as regions of stability instability, we compute the coefficients of the gravitational potential. The work not only enables expansion for the case of asteroids, but also for other non-spherical bodies, contributing to the development of targeted studies the origin and evolution of the solar system, and perhaps the origin of the earth, and new technologies for modeling and mapping of non-spherical bodies. The main results were obtained by analyzing the graphics format and planning of asteroids, which confirmed how these bodies are irregular and show how distribution of non-homogeneous mass. Observe the behavior of the curves of zero velocity and equipotential curves as well as their respective surfaces. Also, compute some values of the gravitational potential and the spherical harmonic coefficients of each object. Furthermore, we find possible equilibrium points of asteroids except 4179 Toutatis, and analyze its stability