Brasil: dinámica de la industria de bienes de capital en el ciclo de expansivo 2003-2008 y tras la crisis mundial

La industria de bienes de capital es esencial para el desarrollo tecnológico y para garantizar un crecimiento económico a largo plazo sin restricciones externas. En el Brasil, después de un largo período de estancamiento, las inversiones volvieron a crecer a partir de 2003, dando nuevo impulso a la industria de bienes de capital. Sin embargo, se trata de una industria bastante heterogénea; mientras que en algunos sectores no se logró cubrir la expansión de la demanda, esto fue posible en otros que evidenciaron un elevado potencial tecnológico, como los proveedores de máquinas para las industrias del petróleo, la minería y la construcción, y los fabricantes de equipos de transporte y de generación y distribución de energía eléctrica. Esos sectores continuaron expandiéndose incluso en el período posterior a la crisis mundial de 2008 y casi no fueron afectados por la competencia internacional.

Democracia y desinstitucionalización : La expansión del espacio público y la transformación del lazo representativo

En varios aspectos, el retorno de la democracia en 1983 constituyó un escenario inédito en la historia política argentina, en el que se planteaba el problema de la transición en los términos de una mayor institucionalización y estabilidad política, que permitiera la gobernabilidad de una sociedad homogénea y previsible. Ninguna de esas expectativas se ha visto cumplida en los años posteriores. Tanto los partidos políticos como los sindicatos y los movimientos sociales irían fragmentándose, mientras los nuevos actores, como el movimiento piquetero, no llegarían a conformar las identidades unitarias de otras épocas, contribuyendo a un clima de inestabilidad caracterizado por recurrentes crisis económicas y estallidos sociales. No obstante, la democracia como régimen político y como valor cívico no ha sido puesta en cuestión, sino, al contrario, ha sido la fuente de resolución de conflictos e impasses institucionales. El presente estudio se propone analizar este conjunto de fenómenos, partiendo del supuesto de que nos encontramos en un proceso de transición y consolidación de una sociedad democrática, cuyo pilar fundamental se haya en la constitución de un espacio público conformado por una multiplicidad de actores relativamente heterogénea y fluctuante, y no en la estabilidad institucional anhelada en la década de los ochenta

Democracia y desinstitucionalización : La expansión del espacio público y la transformación del lazo representativo

En varios aspectos, el retorno de la democracia en 1983 constituyó un escenario inédito en la historia política argentina, en el que se planteaba el problema de la transición en los términos de una mayor institucionalización y estabilidad política, que permitiera la gobernabilidad de una sociedad homogénea y previsible. Ninguna de esas expectativas se ha visto cumplida en los años posteriores. Tanto los partidos políticos como los sindicatos y los movimientos sociales irían fragmentándose, mientras los nuevos actores, como el movimiento piquetero, no llegarían a conformar las identidades unitarias de otras épocas, contribuyendo a un clima de inestabilidad caracterizado por recurrentes crisis económicas y estallidos sociales. No obstante, la democracia como régimen político y como valor cívico no ha sido puesta en cuestión, sino, al contrario, ha sido la fuente de resolución de conflictos e impasses institucionales. El presente estudio se propone analizar este conjunto de fenómenos, partiendo del supuesto de que nos encontramos en un proceso de transición y consolidación de una sociedad democrática, cuyo pilar fundamental se haya en la constitución de un espacio público conformado por una multiplicidad de actores relativamente heterogénea y fluctuante, y no en la estabilidad institucional anhelada en la década de los ochenta

Recuperación de un sector urbano en la Ciudad de Buenos Aires : El caso de la Ex AU3. Intereses en disputa

La Ciudad sufrió en los últimos años cambios en su configuración socio-espacial así como en las formas de apropiación que reflejan los conflictos de clase e intereses de los actores que intervienen en el territorio. Esta construcción del espacio urbano supone una lucha de intereses entre los agentes que intervienen en él, profundizando las desigualdades y las controversias existentes en cada grupo social. El hábitat resultante se presenta desigual y segregador, siendo la demanda por el suelo urbano el epicentro de lucha de intereses de los diferentes sectores sociales. La selección del sector de la Traza de la Ex Autopista AU3 como caso de estudio, responde a la presencia de un área fragmentada y heterogénea a intervenir a través de políticas de gestión urbana sustentadas en la participación ciudadana. Este espacio físico compartido por los diferentes actores sociales (propietarios, ocupantes de inmuebles y Estado), generó una degradación socio-ambiental que aún hoy se verifica. Por ello, se torna necesario incorporar nuevos modelos a la gestión del gobierno local que dejen atrás viejas prácticas de orden jerárquico y concentrador de poder en torno a la toma de decisiones sobre lo público, para dar paso a un modelo de mayor gobernabilidad y gobernanza

O QUE QUERES QUE EU TE FAÇA? - EM BUSCA DE UMA METODOLOGIA DA CONVIVÊNCIA NA AÇÃO PASTORAL PARA A POPULAÇÃO SOBRANTE DOS CENTROS URBANOS: ESTUDO DE CASO DA MISSÃO SAL EM SANTO A NDRÉ.

Um dos grandes desafios a serem enfrentados pelas cidades brasileiras é a problemática vivenciada pela população em situação de rua, cada vez mais numerosa nos centros urbanos. Essa população heterogênea e complexa vem sendo cada vez mais, alvo de discussões que buscam compreendê-la melhor, tentando quantificá-la e descrevê-la para delinear caminhos de intervenção em sua situação-limite, que melhor contemple suas necessidades. As ações pastorais adotadas com a população em situação de rua nas cidades, por sua vez, geralmente têm privilegiado o proselitismo e o assistencialismo, que acabam por reproduzir os mecanismos que os excluem e os tornam sobrantes em todos os aspectos da vida, inclusive da própria religião. Essa postura se explica por sua pastoral estar pautada no antigo paradigma de missão, no qual o assistido não tem voz e torna-se apenas um depositário de assistência e de dogmas. Na busca de uma ação pastoral alternativa, encontramos a Missão SAL, em Santo André, que realiza sua missão a partir da convivência familiar com pessoas sobrantes dos centros urbanos, como aquela que pode revelar-se uma importante expressão do rosto da missão para eles. Assim, a presente dissertação se propôs a analisar a ação pastoral da Missão SAL a partir da seguinte pergunta norteadora: A ação pastoral adotada pela Missão Sal possui suas bases em uma metodologia da convivência, que promova o diálogo, devolvendo a voz às pessoas sobrantes que acolhe, contribuindo para a construção de sua autonomia? A metodologia utilizada contou com dois momentos distintos. Iniciamos com a sistematização de referencial bibliográfico sobre a população em situação de rua, especialmente o que convencionamos chamar de sobrantes, bem como o contexto em que esta está inserida na contemporaneidade e a sistematização da bibliografia sobre o referencial teórico para uma avaliação crítica da metodologia de ação pastoral utilizada na Missão SAL. Em seguida nos detivemos ao estudo de caso, que teve como objeto a metodologia de ação pastoral da Missão SAL, em Santo André, que foi analisada a partir da observação participativa e de entrevistas não estruturadas com os moradores da casa. Essa dissertação está composta em três capítulos. O primeiro capítulo buscou apresentar os sobrantes que fazem parte de um exército de excluídos e marginalizados, que vivem em situação de rua nos centros urbanos, apontando sua relação com a cidade. O segundo capítulo apresentou os resultados obtidos no estudo de caso da Missão SAL e, por fim, o terceiro capítulo procurou apontar caminhos para uma metodologia da convivência na ação pastoral para a população sobrante dos centros urbanos, como aquela que pode contribuir para a autonomia dessa população.

HETEROGENEIDADE EM REDE: PRESENÇA E PRÁTICAS DE USO ENTRE ESTUDANTES DA UNIVERSIDADE METODISTA DE SÃO PAULO NAS REDES SOCIAIS

As redes sociais pela internet ganham destaque nos processos comunicacionais atuais ao permitirem uma maior interação entre os conectados. Entretanto, o conceito de rede, ao contrário do senso comum e do que se convencionou no meio acadêmico, de fato não propõe uma organização simétrica, estática e homogênea. A rede é, por natureza, dinâmica e heterogênea, assim como a sociedade é. As redes sociais e as redes digitais demonstram isso. Elas aumentam e diminuem seus nós e possuem diferentes graus de conexões, e mesmo nestes graus de conexões são diversas. O presente estudo está dividido em duas partes fundamentais. A primeira visa compreender o conceito de rede, e para isso baseia-se em Milton Santos, Pierre Musso e Albert-Lásló Barabási. Na segunda parte, a partir de uma pesquisa com estudantes universitários, há a preocupação de identificar as heterogeneidades existentes nas suas presenças nas redes e suas práticas de uso, a partir de seis categorias de análise e atividades relacionadas: relações pessoais, estudo, trabalho, ativismo, entretenimento e lazer, e informações e notícias. A questão de fundo, a respeito das possibilidades das redes, é sobre os diferentes níveis de participação, ou seja, a heterogeneidade em rede. O resultado do estudo constata a heterogeneidade, na qual os estudantes, por mais que possuam semelhanças em função da idade aproximada, da condição social e pelo fato de estudarem em uma universidade particular, são diferentes entre si, em especial, se comparados pelas áreas de formação. Não só a presença nas redes sociais se dá em níveis diferentes, quanto suas práticas também são. Portanto, o conceito de redes heterogêneas contido no pensamento de Milton Santos, Pierre Musso e Albert-Lásló Barabási, é confirmado com a pesquisa aplicada aos estudantes universitários dos cursos de graduação presencial da Universidade Metodista de São Paulo, a partir da análise de suas presenças e práticas de uso.  

Formulações e algoritmos para o problema das p-medianas heterogêneo livre de penalidade

This work presents a new model for the Heterogeneous p-median Problem (HPM), proposed to recover the hidden category structures present in the data provided by a sorting task procedure, a popular approach to understand heterogeneous individual’s perception of products and brands. This new model is named as the Penalty-free Heterogeneous p-median Problem (PFHPM), a single-objective version of the original problem, the HPM. The main parameter in the HPM is also eliminated, the penalty factor. It is responsible for the weighting of the objective function terms. The adjusting of this parameter controls the way that the model recovers the hidden category structures present in data, and depends on a broad knowledge of the problem. Additionally, two complementary formulations for the PFHPM are shown, both mixed integer linear programming problems. From these additional formulations lower-bounds were obtained for the PFHPM. These values were used to validate a specialized Variable Neighborhood Search (VNS) algorithm, proposed to solve the PFHPM. This algorithm provided good quality solutions for the PFHPM, solving artificial generated instances from a Monte Carlo Simulation and real data instances, even with limited computational resources. Statistical analyses presented in this work suggest that the new algorithm and model, the PFHPM, can recover more accurately the original category structures related to heterogeneous individual’s perceptions than the original model and algorithm, the HPM. Finally, an illustrative application of the PFHPM is presented, as well as some insights about some new possibilities for it, extending the new model to fuzzy environments

Características estruturais e fotocatalíticas do compósito oxihidróxido de nióbio/vermiculita

The preparation of nanostructured materials using natural clays as support, has been studied in literature under the same are found in nature and consequently, have a low price. Generally, clays serve as supports for metal oxides by increasing the number of active sites present on the surface and can be applied for various purposes such as adsorption, catalysis and photocatalysis. Some of the materials that are currently highlighted are niobium compounds, in particular, its oxides, by its characteristics such as high acidity, rigidity, water insolubility, oxidative and photocatalytic properties. In this scenario, the study aimed preparing a composite material oxyhydroxide niobium (NbO2OH) / sodium vermiculite clay and evaluate its effectiveness with respect to the natural clay (V0) and NbO2OH. The composite was prepared by precipitation-deposition method and then characterized by X-ray diffraction, infrared spectroscopy (XRD), energy dispersive X-ray (EDS), thermal analysis (TG/DTG), scanning electron microscopy (SEM), N2 adsorption-desorption and investigation of distribution of load. The application of the material NbO2OH/V0 was divided in two steps: first through oxidation and adsorption methods, and second through photocatalytic activity using solar irradiation. Studies of adsorption, oxidation and photocatalytic oxidation monitored the percentage of color removal from the dye methylene blue (MB) by UV-Vis spectroscopy. The XRD showed a decrease in reflection d (001) clay after modification; the FTIR indicated the presence of both the clay when the oxyhydroxide niobium to present bands in 1003 cm-1 related to Si-O stretching bands and 800 cm-1 to the Nb-O stretching. The presence of niobium was also confirmed by EDS indicated that 17 % by mass amount of the metal. Thermal analysis showed thermal stability of the composite at 217 °C and micrographs showed that there was a decrease in particle size. The investigation of the surface charge of NbO2OH/V0 found that the material exhibits a heterogeneous surface with average low and high negative charges. Adsorption tests showed that the composite NbO2OH/V0 higher adsorption capacity to remove 56 % of AM, while the material removed from V0 only 13 % showed no NbO2OH and adsorptive capacity due to the formation of H-aggregates. The percent removal of dye color for the oxidation tests showed little difference from the adsorption, being 18 and 66 % removal of dye color for V0 and NbO2OH/V0 respectively. The NbO2OH/V0 material shows excellent photocatalytic activity managing to remove just 95,5 % in 180 minutes of the color of MB compared to 41,4 % and 82,2 % of V0 the NbO2OH, proving the formation of a new composite with distinct properties of its precursors.

Estudo do comportamento da sinterização de compactos de cavacos de um aço SAE 1050 obtidos sob alta pressão

From an economic standpoint, the powder metallurgy (P/M) is a technique widely used for the production of small parts. It is possible, through the P/M and prior comminution of solid waste such as ferrous chips, produce highly dense sintered parts and of interest to the automotive, electronics and aerospace industries. However, without prior comminution the chip, the production of bodies with a density equal to theoretical density by conventional sintering techniques require the use of additives or significantly higher temperatures than 1250ºC. An alternative route to the production of sintered bodies with high density compaction from ferrous chips (≤ 850 microns) and solid phase sintering is a compression technique under high pressure (HP). In this work, different compaction pressures to produce a sintered chip of SAE 1050 carbon steel were used. Specifically, the objective was to investigate them, the effect of high pressure compression in the behavior of densification of the sintered samples. Therefore, samples of the chips from the SAE 1050 carbon steel were uniaxially cold compacted at 500 and 2000 MPa, respectively. The green compacts obtained were sintered under carbon atmosphere at 1100 and 1200°C for 90 minutes. The heating rate used was 20°C/min. The starting materials and the sintered bodies were characterized by optical microscopy, SEM, XRD, density measurements (geometric: mass/volume, and pycnometry) and microhardness measurements Vickers and Rockwell hardness. The results showed that the compact produced under 2000 MPa presented relative density values between 93% and 100% of theoretical density and microhardness between 150 HV and 180 HV, respectively. In contrast, compressed under 500 MPa showed a very heterogeneous microstructure, density value below 80% of theoretical density and structural conditions of inadequate specimens for carrying out the hardness and microhardness measurements. The results indicate that use of the high pressure of ferrous chips compression is a promising route to improve the sinterability conditions of this type of material, because in addition to promoting greater compression of the starting material, the external tension acts together with surface tension, functioning as the motive power for sintering process. Additionally, extremely high pressures allow plastic deformation of the material, providing an intimate and extended contact of the particles and eliminating cracks and pores. This tends to reduce the time and / or temperature required for good sintering, avoiding excessive grain growth without the use of additives. Moreover, higher pressures lead to fracture the grains in fragile or ductile materials highly hardened, which provides a starting powder for sintering, thinner, without the risk of contamination present when previous methods are used comminution of the powder.

Os estados no SUAS: uma análise da capacidade institucional dos governos estaduais na assistência social

This paper deals of the effects generated by institutional designs in the behavior of political actors. The literature that discusses the implications of federal arrangements in the production of public policies to dock at two opposing arguments: (1) the federal configuration would cause dispersion and variation in service provision between subnational governments; and (2) the central government would own mechanisms to induce the provision of national policies in more homogeneous levels, similar to unitary states. The research is part of this discussion because it analyzes the effects of the institutional design of the Sistema Único de Assistência Social (SUAS) in the decisions of states in Brazil. Therefore, we analyzed the institutional capacity built by the 26 state governments after the implementation of SUAS, conceiving this system as defined mechanism of government functions and federative cooperation.It is argued that the existence of a heterogeneous institutional capacity of state governments in social assistance is a result of the autonomy contained in the institutional design of SUAS to this level of government. This freedom of action relativize the idea that the implementation of national public policy systems would generate positive (or homogeneous) effects in all subnational governments, at the same time as it preclude to generalize the premise of fragility of the states in the brazilian federal plan.

Estudo da produção eletroquímica de espécies de cloro ativo para tratamento de efluentes sintéticos

The treatment of wastewater is essential to human health. One of the most important steps is the disinfection treatment which uses chlorine to eliminate bacteria as required by environmental agencies. However, the identification of potentially toxic byproducts generated by this method, such as trihalomethanes, has stimulated the development of new alternative disinfection technologies. Among them, heterogeneous photocatalysis, TiO2 photocatalysis and electrochemical disinfection are considered suitable alternatives to the chlorination method. Thus, the present dissertation analyzes the evolution of active chlorine species in a synthetic NaCl solution and it is tested to treat a synthetic solution of the dye Reactive Blue 19 using boron-doped diamond (BDD) and ruthenium oxide (Ti/Ru0.3Ti0.7O2) as anodes. The indirect electrochemical process was discussed in terms of mineralization of the total organic load and percentage of color removal in order to evaluate the applicability of electrochemical technology. Electrochemical experiments were carried out with different current densities (25, 50 and 75 mA.cm-2) during 120 minutes. On the other hand, other important parameter in this study was the influence of the proportion sp3/sp2 on BDD anode on the performance of the evolution of active chlorine species which was investigated by electrolytic techniques (linear polarization), with the intention of determining the related training oxidizing species and consumption energy to chemical or electrochemical reactions. From the results, it can be noted that the BDD electrode showed better efficiency throughout the electrochemical process.

Estudo da produção eletroquímica de espécies de cloro ativo para tratamento de efluentes sintéticos

The treatment of wastewater is essential to human health. One of the most important steps is the disinfection treatment which uses chlorine to eliminate bacteria as required by environmental agencies. However, the identification of potentially toxic byproducts generated by this method, such as trihalomethanes, has stimulated the development of new alternative disinfection technologies. Among them, heterogeneous photocatalysis, TiO2 photocatalysis and electrochemical disinfection are considered suitable alternatives to the chlorination method. Thus, the present dissertation analyzes the evolution of active chlorine species in a synthetic NaCl solution and it is tested to treat a synthetic solution of the dye Reactive Blue 19 using boron-doped diamond (BDD) and ruthenium oxide (Ti/Ru0.3Ti0.7O2) as anodes. The indirect electrochemical process was discussed in terms of mineralization of the total organic load and percentage of color removal in order to evaluate the applicability of electrochemical technology. Electrochemical experiments were carried out with different current densities (25, 50 and 75 mA.cm-2) during 120 minutes. On the other hand, other important parameter in this study was the influence of the proportion sp3/sp2 on BDD anode on the performance of the evolution of active chlorine species which was investigated by electrolytic techniques (linear polarization), with the intention of determining the related training oxidizing species and consumption energy to chemical or electrochemical reactions. From the results, it can be noted that the BDD electrode showed better efficiency throughout the electrochemical process.

Usos de membranas de quitosana na remoção de cobre em águas residuais

In this work a chitosan (CS) ionically crosslinked were manufactured by treatment with sulfuric acid solution for application in the treatment of wastewater from oil industry. Two crosslinking process were developed: homogeneous and heterogeneous. In the homogeneous process the ratio molar of SO42-/ NH3+ (1:6 and 1:4) were the variable analyzed, denominated CS16 and CS14 respectively. In the heterogeneous process the soaking time of the membranes in sulfuric acid solution were the variable studied, being used times of 5 (CS5) and 30 (CS30) minutes. FTIR-ATR results indicated no changes in the characteristics of chitosan after homogeneous crosslinking process, while heterogeneous crosslinking showed formation of ionic bonds between protonated groups from chitosan and the crosslinking agent sulfate ions. TG/DTG and XRD analysis confirmed the formation of these interactions, as also shown the new structure on the surface region of CS5 and CS30 membranes compared to CS, CS16 e CS14. Swelling test in aqueous medium have shown that crosslinking process reduced the membrane sorption capacity. Swelling test in acid medium demonstrated that CS16 and CS14 membranes increasing the adsorption capacity up to a maximum percentage of 140% approximately, whereas the CS5 e CS30 reached a maximum of 60%. The mechanical properties indicated the stiff and ductile behavior of crosslinked membrane. Adsorption experiments of CuCl2 results that CS16 membranes reached the efficiency maximum with 73% of copper removal at pH 5.0 and 87% at pH 4.0. The experiments with CuSO4 also obtained efficiency maximum to the CS16 membrane and 80% to the removal of Cu2+ ions. Also was verified that the increase of concentration and temperature cause a decrease in the adsorption capacity for all membranes. Kinetics study indicated that pseudo-second-order obtained characterized better the membranes. Equilibrium studies demonstrated that the CS, CS16 and CS14 follow the Langmuir model, whereas CS5 and CS30 follows Freundlich model. Filtration experiments results with rejection maximum to the CS16 and CS5 membranes, reaching 92 and 98% respectively.

Usos de membranas de quitosana na remoção de cobre em águas residuais

In this work a chitosan (CS) ionically crosslinked were manufactured by treatment with sulfuric acid solution for application in the treatment of wastewater from oil industry. Two crosslinking process were developed: homogeneous and heterogeneous. In the homogeneous process the ratio molar of SO42-/ NH3+ (1:6 and 1:4) were the variable analyzed, denominated CS16 and CS14 respectively. In the heterogeneous process the soaking time of the membranes in sulfuric acid solution were the variable studied, being used times of 5 (CS5) and 30 (CS30) minutes. FTIR-ATR results indicated no changes in the characteristics of chitosan after homogeneous crosslinking process, while heterogeneous crosslinking showed formation of ionic bonds between protonated groups from chitosan and the crosslinking agent sulfate ions. TG/DTG and XRD analysis confirmed the formation of these interactions, as also shown the new structure on the surface region of CS5 and CS30 membranes compared to CS, CS16 e CS14. Swelling test in aqueous medium have shown that crosslinking process reduced the membrane sorption capacity. Swelling test in acid medium demonstrated that CS16 and CS14 membranes increasing the adsorption capacity up to a maximum percentage of 140% approximately, whereas the CS5 e CS30 reached a maximum of 60%. The mechanical properties indicated the stiff and ductile behavior of crosslinked membrane. Adsorption experiments of CuCl2 results that CS16 membranes reached the efficiency maximum with 73% of copper removal at pH 5.0 and 87% at pH 4.0. The experiments with CuSO4 also obtained efficiency maximum to the CS16 membrane and 80% to the removal of Cu2+ ions. Also was verified that the increase of concentration and temperature cause a decrease in the adsorption capacity for all membranes. Kinetics study indicated that pseudo-second-order obtained characterized better the membranes. Equilibrium studies demonstrated that the CS, CS16 and CS14 follow the Langmuir model, whereas CS5 and CS30 follows Freundlich model. Filtration experiments results with rejection maximum to the CS16 and CS5 membranes, reaching 92 and 98% respectively.

Implementações metodológicas para o estudo eletrofisiológico e comportamental em um modelo animal de autismo

O autismo é um transtorno do desenvolvimento que se manifesta nos primeiros anos de vida e apresenta semiologia heterogênea. Esta patologia afeta a maturação do encéfalo e produz alterações sensoriais, de linguagem e de interação social no início na infância. O modelo experimental de autismo utilizando ácido valproico (VPA) durante o período gestacional tem sido demonstrado ter alta validade de face e permitir estudos tanto das bases neuropatológicas quanto neuro-funcionais durante o desenvolvimento. A despeito do recente interesse por este modelo como instrumento de compreensão dos aspectos básicos da fisiopatologia do autismo, a maioria dos estudos experimentais têm se concentrado nos aspectos comportamentais, histológicos e celulares. Neste trabalho, foram propostas estratégias experimentais de avaliação comportamental associadas a eletrofisiologia \textit{in vivo}, uma técnica que nunca fora utilizada para avaliação desse modelo. Animais controles e experimentais, submetidos previamente a um procedimento cirúrgico para implante de eletrodos crônicos, participaram de experimentos de livre exploração, interação social e condicionamento ao medo.