788 resultados para AMPEROMETRIC SENSOR
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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
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The Internet of Things is a new paradigm where smart embedded devices and systems are connected to the Internet. In this context, Wireless Sensor Networks (WSN) are becoming an important alternative for sensing and actuating critical applications like industrial automation, remote patient monitoring and domotics. The IEEE 802.15.4 protocol has been adopted as a standard for WSN and the 6LoWPAN protocol has been proposed to overcome the challenges of integrating WSN and Internet protocols. In this paper, the mechanisms of header compression and fragmentation of IPv6 datagrams proposed in the 6LoWPAN standard were evaluated through field experiments using a gateway prototype and IEEE 802.15.4 nodes.
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The use of an amperometric biosensor for the salicylate determination in blood serum is described. The biosensor is based on salicylate hydroxylase (EC 1.14.13.1) electropolymerized onto a glassy carbon-working electrode with polypyrrole and glutaraldehyde, to improve the biosensor lifetime. The hexacyanoferrate (II) was also incorporated to work as a redox mediator to minimize possible interferences. The salicylate is enzymatically converted to catechol, which is monitored amperometrically by its electrooxidation at +0.170 V versus SCE (saturated calomel electrode). Salicylate determination was carried out maintaining the ratio between β-NADH and salicylate at 4:1 (30°C). The amperometric response of the biosensor was linearly proportional to the salicylate concentration between 2.3 x 10-6 and 1.4 x 10-5 mol l- 1, in 0.1 mol l-1 phosphate buffer (pH 7.8), containing 0.1 mol l-1 KCl and 5.0 x 10-4 mol l-1 Na2H2EDTA, as supporting electrolyte. The recovery studies, in the presence of several interfering compounds, showed recoveries between 96.4 and 104.8%. The useful lifetime of the biosensor in the concentration range evaluated was at least 40 days, in continuous use. Blood serum samples analyzed by this biosensor showed a good correlation compared to the spectrophotometric method (Trinder) used as reference, presenting relative deviations lower than 7.0%. (C) 2000 Elsevier Science B.V.
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A glassy carbon electrode chemically modified with nickel nanoparticles coupled with reversed-phase chromatography with pulsed amperometric detection was used for the quantitative analysis of furanic aldehydes in a real sample of sugarcane bagasse hydrolysate. Chromatographic separation was carried out in isocratic conditions (acetonitrile/water, 1:9) with a flow rate of 1.0 mL/min, a detection potential of -50 mV vs. Pd, and the process was completed within 4 min. The analytical curves presented limits of detection of 4.0 × 10(-7) mol/L and 4.3 × 10(-7) mol/L, limits of quantification of 1.3 × 10(-6) and 1.4 × 10(-6) mol/L, amperometric sensitivities of 2.2 × 10(6) nA mol/L and 2.7 × 10(6) nA mol/L for furfural and 5-hydroxymethylfurfural, respectively. The values obtained in this sample by the standard addition method were 1.54 ± 0.02 g/kg for 5-hydroxymethylfurfural and 11.5 ± 0.2 g/kg for furfural. The results demonstrate that this new proposed method can be used for the quick detection of furanic aldehydes without the interference of other electroactive species, besides having other remarkable merits that include excellent peak resolution, analytical repeatability, sensitivity, and accuracy.
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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O processo de retificação é considerado um dos últimos na cadeia de produção de peças de precisão. Assim, é essencial ter um sistema de monitoramento confiável para este processo. Neste trabalho é proposto um sistema de medição de vibração, rápido e versátil, baseado na plataforma de prototipagem eletrônica de hardware livre Arduino, com objetivo de monitorar em tempo real o processo de retificação plana, especialmente no que diz respeito à condição da peça retificada. Para este trabalho ensaios experimentais foram realizados numa máquina retificadora plana, empregando um rebolo de óxido de alumínio e uma peça de aço ABNT 1020. Por meio de um sensor piezelétrico de PZT (Pb-Lead Zirconate Titanate) de baixo custo, instalado junto à peça e conectado a uma das portas analógicas do hardware, foi possível medir o sinal de vibração durante o processo de retificação. Verificou-se que, a medida com que o rebolo perdia sua capacidade de corte, em função das consecutivas passadas sobre a peça, ocorria também uma significativa diminuição dos valores médios do sinal de vibração. Tal diminuição do sinal de vibração pode indicar o momento que o rebolo deve ser dressado, permitindo monitorar a qualidade superficial da peça durante o processo de retificação, evitando danos como é o caso da queima superficial. O princípio de operação e as principais características dessa técnica foram investigados, bem como algumas de suas limitações práticas.
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
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The electrical measures of the soil have been used as variables that correlate with its characteristics. This study aimed at developing an electrical capacitance sensor of low cost, to evaluate its performance on the field and verify the correlation between the measurements of electrical capacitance with physical properties (sand, silt and clay) and chemical properties of soil (pH, MO, P resin, H + Al, K, Ca, Mg, SB, CTC and V%) and the moisture content. The data sampling was performed at the farm named "Capão da Onça" which belongs to the State University of Ponta Grossa. The samples collection was conducted in an area of approximately 13 hectares, totalizing 81 samples. In each sampling the electrical capacitance of the soil was measured. After the sensor withdrawal, soil samples were collected and sent to be analysed in the laboratory of the College of Agronomics Science of the Paulista State University. The measuring instrument used to collect data on electric capacitance of the soil a digital multimeter was used. The data were submitted to the analysis of correlation and regression. The developed system presented a low cost and it was capable to measuring variation of the electrical capacitance of the soil. The obtained measures satisfactorily correlated with the levels of clay and sand, and weakly with the moisture content. This had demonstrated the possibility to use a sensor to verify the soil texture in not homogeneous areas. The measures of the electrical capacitance of the soil obtained by the sensor had significantly correlated with the soil attributes: calcium, magnesium, pH, SB and CTC. These results had demonstrated the possibility to use a sensor for soil fertility control.
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)