Monitoring a CuO gas sensor at work: an advanced in situ X-ray absorption spectroscopy study
Contribuinte(s) |
Universidade Estadual Paulista (UNESP) |
---|---|
Data(s) |
07/12/2015
07/12/2015
08/06/2015
|
Resumo |
Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) Processo FAPESP: 2013/07296-2 Processo FAPESP: 2013/14647-6 Processo FAPESP: 2011/02408-1 X-ray absorption near edge structure (XANES) and electrical measurements were used to elucidate the local structure and electronic changes of copper(II) oxide (CuO) nanostructures under working conditions. For this purpose, a sample holder layout was developed enabling the simultaneous analysis of the spectroscopic and electrical properties of the sensor material under identical operating conditions. The influence of different carrier gases (e.g., air and N2) on the CuO nanostructures behavior under reducing conditions (H2 gas) was studied to analyze how a particular gas atmosphere can modify the oxidation state of the sensor material in real time. |
Formato |
18761-18767 |
Identificador |
http://dx.doi.org/10.1039/c5cp02150b Physical Chemistry Chemical Physics : Pccp, v. 17, n. 28, p. 18761-18767, 2015. 1463-9084 http://hdl.handle.net/11449/131505 10.1039/c5cp02150b 26119265 |
Idioma(s) |
eng |
Publicador |
Royal Society of Chemistry |
Relação |
Physical Chemistry Chemical Physics : Pccp |
Direitos |
closedAccess |
Tipo |
info:eu-repo/semantics/article |