Dust flux in the Arabian Sea

Eolian grain size and flux were measured on samples from 11 Arabian Sea sediment traps deployed 200-1250 km offshore. The timing of increased grain size is coincident with the onset of strong summer monsoon winds and dust storm activity over the Arabian Peninsula and Middle East. Data spanning a full annual cycle show that eolian grain size is highly correlated with barometric pressure (r=-0.91) and wind speed (r=0.84), enabling calibration of the downcore record in terms of these primary meteorological variables. Eolian flux is highly correlated with organic carbon flux (r=0.80); both increase 6-8 weeks after the grain size increase and summer monsoon onset. This lag, and the low correlation between eolian grain size and eolian flux (r=0.36), likely result from the differential sinking rates of large and small dust particles in the surface waters as well as biological scavenging associated with monsoon-induced productivity.

(Table 2) Annual mass fluxes, 230Th composition and organic geochemistry of sediment trap samples in the South Altantic

The scavenging of 231Pa and 230Th was investigated in the Atlantic Sector of the Southern Ocean by combining results from sediment trap and in situ filtration studies. We present the first high-resolution profile of dissolved 230Th and 231Pa in surface waters across the ACC, showing a dramatic southward increase of both radionuclides around the southern ACC Front at 533S. High dissolved 231Pa/230Th ratios combined with low 230Th/231Pa fractionation factors (F) in these surface waters result in extremely high 231Pa94/230Th94 ratios of material collected in the shallow traps. Particulate 231Pa94/230Th94 ratios in a shallow trap near Bouvet Island increase continuously during the productive period in austral summer, and drop back in the low flux period. This behavior, following the Rayleigh fractionation principle, is interpreted to be due to an increase in the dissolved 231Pa/230Th ratio in the euphotic zone resulting from preferential scavenging of 230Th relative to 231Pa, even in opal-dominated regions. In the post-bloom stage, the depleted radionuclide concentrations are replenished by upwelling of Circumpolar Deep Water. The high particulate 231Pa94/230Th94 signal is weakened during downward transport of the bloom particles in the water column by incorporation of deep suspended particles, which have a lower 231Pa94/230Th94 ratio. It is shown that under the special hydrographic conditions in the Southern Ocean scavenging from the upper water column significantly influences the budgets of 230Th and 231Pa in the sediment. Nevertheless, the budgets are still made up primarily by scavenging from the large standing stock of deep suspended particles.

Ostracode fauna of sediment core GIK23414-9 in the northeast Atlantic

Sediment core M23414 from the Rockall Plateau (North Atlantic) covering the last two climatic cycles, marine isotope stages (MIS) 7 to 1, was investigated for glacial-interglacial variations in the deep-sea benthic ostracode fauna. A highly diversified ostracode fauna including 98 species was found. Two climate-related assemblages were identified, associated with interglacial and peak glacial periods, respectively. The 'interglacial' group occurs during the end of MIS 7, 5 and 1 and is composed of the genera Henryhowella, Pelecocythere, Echinocythereis, Cytherella, Bradleya, Aversovalva and Eucytherura. The 'glacial' group consists of the genera Acetabulastoma (which is known as 'sea ice indicator' in the modern Arctic Ocean), Polycope, Bythoceratina, ?Rhombobythere, and some species possibly belonging to the genus Pseudocythere and is found during MIS 6, 4 and 2. These longer-term variations within the ostracode fauna seem related to the particular glacial and interglacial climate conditions that affected both deep-water production as well as primary production in the surface waters. However, a detailed comparison of ostracode abundances with the occurrence of events marked by increased ice-rafted debris reveals also much shorter-term climate related changes in the ostracode fauna. Thus, the temporal fluctuations within ostracode assemblages reflect long- and short-term alterations of the deep-sea environment that are clearly linked to climate changes.

Particle flux studies of sediment traps from the northern and equatorial Indian Ocean

The Asian monsoon system governs seasonality and fundamental environmental characteristics in the study area from which two distinct peculiarities are most notable: upwelling and convective mixing in the Arabian Sea and low surface salinity and stratification in the Bay of Bengal due to high riverine input and monsoonal precipitation. The respective oceanography sets the framework for nutrient availability and productivity. Upwelling ensures high nitrate concentration with temporal/spatial Si limitation; freshwater-induced stratification leads to reduced nitrogen input from the subsurface but Si enrichment in surface waters. Ultimately, both environments support high abundance of diatoms, which play a central role in the export of organic matter. It is speculated that, additional to eddy pumping, nitrogen fixation is a source of N in stratified waters and contributes to the low-d15N signal in sinking particles formed under riverine impact. Organic carbon fluxes are best correlated to opal but not to carbonate, which is explained by low foraminiferal carbonate fluxes within the river-impacted systems. This observation points to the necessity of differentiating between carbonate sources for carbon flux modeling. As evident from a compilation of previously published and new data on labile organic matter composition (amino acids and carbohydrates), organic matter fluxes are mainly driven by direct input from marine production, except the site off Pakistan where sedimentary input of (marine) organic matter is dominant during the NE monsoon. The explanation of apparently different organic carbon export efficiency calls for further investigations of, for example, food web structure and water column processes.

Concentration of organic compounds in slush, under-ice water, and the snow-ice fast-ice cover of the southeast sector of the Antarctic in April 2008

Data are presented on concentration of hydrocarbons (HC) relative to concentrations of suspended matter, lipids, organic carbon, and chlorophyll a in surface waters and snow-ice cover of the East Antarctic coastal areas. It was shown that growth of concentrations of aliphatic HC (AHC) to 30 µg/l in surface waters takes place in frontal zones and under young ice formation. AHC concentration in snow increases with growth of aerosol concentration in the atmosphere. In the lower part of ice, at the boundary with seawater, despite low temperatures, autochthonous processes may provide high AHC concentrations (up to 289 µg/l). Within the snow-ice cover on fast ice, concentration co-variations of all the compounds considered take place.

Geochemistry and isotopes at DSDP Leg 80 Holes

Thirty-eight samples from DSDP Sites 549 to 551 were analyzed for major and minor components and trace element abundances. Multivariate statistical analysis of geochemical data groups the samples into two major classes: an organic-carbon- rich group (> 1% TOC) containing high levels of marine organic matter and certain trace elements (Cu, Zn, V, Ni, Co, Ba, and Cr) and an organic-carbon-lean group depleted in these components. The greatest organic and trace metal enrichments occur in the uppermost Albian to Turanian sections of Sites 549 to 551. Carbon-isotopic values of bulk carbonate for the middle Cenomanian section of Site 550 (2.35 to 2.70 per mil) and the upper Cenomanian-Turonian sections of Sites 549 (3.35 to 4.47 per mil) and 551 (3.13 to 3.72 per mil) are similar to coeval values reported elsewhere in the region. The relatively heavy d13C values from Sites 549 and 551 indicate that this interval was deposited during the global "oceanic anoxic event" that occurred at the Cenomanian/Turonian boundary. Variation in the d18O of bulk carbonate for Section 550B-18-1 of middle Cenomanian age suggests that paleosalinity and/or paleotemperature variations may have occurred concurrently with periodic anoxia at this site. Climatically controlled increases in surface-water runoff may have caused surface waters to periodically freshen, resulting in stable salinity stratification

Oxygen- and carbon-isotopes of Globigerina bulloides and Neogloboquadrina pachyderma at DSDP Holes 80-548 and 80-549A

Oxygen- and carbon-isotope analyses have been performed on the Quaternary planktonic foraminifers of Sites 548 and 549 (DSDP Leg 80) to investigate major water mass changes that occurred in the northeastern Atlantic at different glacial-interglacial cycles and to compare them with the well-defined picture of 18,000 yr. ago. Oxygen-isotope stratigraphy also provides a chronological framework for the more important data on the fauna and flora. Although bioturbation and sedimentary gaps obliterate the climatic and stratigraphic record, general trends in the oceanographic history can be deduced from the isotopic data. Isotopic stratigraphy has tentatively been delineated down to isotopic Stage 16 at Site 548 and in Hole 549A. This stratigraphy fits well with that deduced from benthic foraminiferal d18O changes and with bioclimatic zonations based on foraminiferal associations at Site 549. Variations in the geographic extension and in the flux of the Gulf Stream subtropical waters are inferred from both d18O and d13C changes. Maximal fluxes occurred during the late Pliocene. Northward extension of subtropical waters increased through the various interglacial phases of the early Pleistocene and decreased through the late Pleistocene interglacial phases. Conversely, glacial maxima were more intense after Stage 16. Isotopic Stages 12 and 16 mark times of important change in water mass circulation. Oxygen- and carbon-isotope analyses have been performed on the Quaternary planktonic foraminifers of Sites 548 and 549 (DSDP Leg 80) to investigate major water mass changes that occurred in the northeastern Atlantic at different glacial-interglacial cycles and to compare them with the well-defined picture of 18,000 yr. ago. Oxygen-isotope stratigraphy also provides a chronological framework for the more important data on the fauna and flora. Although bioturbation and sedimentary gaps obliterate the climatic and stratigraphic record, general trends in the oceanographic history can be deduced from the isotopic data. Isotopic stratigraphy has tentatively been delineated down to isotopic Stage 16 at Site 548 and in Hole 549A. This stratigraphy fits well with that deduced from benthic foraminiferal d18O changes and with bioclimatic zonations based on foraminiferal associations at Site 549. Variations in the geographic extension and in the flux of the Gulf Stream subtropical waters are inferred from both d18O and d13C changes. Maximal fluxes occurred during the late Pliocene. Northward extension of subtropical waters increased through the various interglacial phases of the early Pleistocene and decreased through the late Pleistocene interglacial phases. Conversely, glacial maxima were more intense after Stage 16. Isotopic Stages 12 and 16 mark times of important change in water mass circulation.

Planktic foraminiferal sieve size specific d13C and d18O values and maximum test diameter from ODP sites 171-1051 and 120-748

Many genera of modern planktic foraminifera are adapted to nutrient-poor (oligotrophic) surface waters by hosting photosynthetic symbionts, but it is unknown how they will respond to future changes in ocean temperature and acidity. Here we show that ca. 40 Ma, some fossil photosymbiont-bearing planktic foraminifera were temporarily 'bleached' of their symbionts coincident with transient global warming during the Middle Eocene Climatic Optimum (MECO). At Ocean Drilling Program (ODP) Sites 748 and 1051 (Southern Ocean and mid-latitude North Atlantic, respectively), the typically positive relationship between the size of photosymbiont-bearing planktic foraminifer tests and their carbon isotope ratios (d13C) was temporarily reduced for ~100 k.y. during the peak of the MECO. At the same time, the typically photosymbiont-bearing planktic foraminifera Acarinina suffered transient reductions in test size and relative abundance, indicating ecological stress. The coincidence of minimum d18O values and reduction in test size-d13C gradients suggests a link between increased sea-surface temperatures and bleaching during the MECO, although changes in pH and nutrient availability may also have played a role. Our findings show that host-photosymbiont interactions are not constant through geological time, with implications for both the evolution of trophic strategies in marine plankton and the reliability of geochemical proxy records generated from symbiont-bearing planktic foraminifera.

Benthic foraminiferal d18O and Mg/Ca studies of sediment cores off tropical NW Africa

Benthic foraminiferal d18O and Mg/Ca of sediment cores off tropical NW Africa are used to study the properties of Atlantic central waters during the Last Glacial Maximum (LGM) and Heinrich Stadial 1 (HS1). We combined our core top data with published results to develop a new Mg/Ca-temperature calibration for Planulina ariminensis, which shows a Mg/Ca-temperature sensitivity of 0.19 mmol/mol per °C. Estimates of the LGM and HS1 thermocline temperatures are comparable to the present-day values between 200 and 400 m water depth, but were 1.2-1.5°C warmer at 550-570 m depth. The HS1 thermocline waters (200-570 m depth) did not show any warming relative to the LGM. This is in contrast to previous climate model studies, which concluded that tropical Atlantic thermocline waters warmed significantly when Atlantic meridional overturning circulation was reduced. However, our results suggest that thermocline temperatures of the northeastern tropical Atlantic show no pronounced sensitivity to changes in the thermohaline circulation during glacial periods. In contrast, we find a significant increase in thermocline-water salinity during the LGM (200-550 m depth) and HS1 (200-400 m depth) with respect to the present-day, which we relate to changes in the wind-driven circulation. We infer that the LGM thermocline (200-550 m depth) and the HS1 upper thermocline (200-400 m depth) in the northeastern tropical Atlantic was ventilated by surface waters from the North Atlantic rather than the southern-sourced waters. This suggests that the frontal zone between the modern South Atlantic and North Atlantic Central Waters was probably shifted southward during the LGM and HS1.

Planktonic foraminifera of ODP Site 117-722

Quantitative analysis of the late Cenozoic planktonic foraminiferal record from western Arabian Sea Site 722 revealed long term trends in the history of oceanography and climate. The modern western Arabian Sea surface waters are highly influenced by the monsoonal wind system. Summer upwelling, a result of southwestern winds, occurs along the coast of Somalia which produces distinct foraminiferal assemblages which are dominated by G. bulloides d'Orbigny. Consequently, variations in the distribution record of G. bulloides through time monitor the upwelling history associated with monsoonal activities. G. bulloides was a minor constituent of the foraminiferal fauna from the bottom of the hole (~14.5 Ma) until about 8.6 Ma ago. Then a rapid shift occurred toward higher values, up to 53% at 7.4 Ma. We interpret this rapid increase as a major step in the evolution of the monsoonal history. It is either the establishment of the system or at least a strong intensification of the monsoonal winds. At 5.5 Ma a significant drop of the G. bulloides relative abundance occurred which may indicate less upwelling, or alternatively other biota may have been favored in this period. From 5.0 Ma to Recent the G. bulloides record indicates that upwelling has occurred with minor fluctuations.