Explosive consolidation of amorphous cobalt-based alloys

This paper addresses the explosive consolidation of amorphous cobalt-based alloys. Using the experimental setup introduced in the present paper, specimens with high compact density, excellent magnetic properties and great wearability have been made. In comparison with permalloy and ferrite, the present specimens exhibit superior magnetic properties. Therefore, the compact is deemed as being a promising material for magnetic recording heads.

新型磁存储介质L10有序FePt薄膜研究综述

L10有序FePt合金薄膜有大的各向异性能、矫顽力和饱和磁化强度，而且根据制备工艺条件的不同，其易磁化轴可以平行或垂直于膜面，因此极有可能成为下一代超高密度磁存储的介质，近年来引起了广泛的关注，详细介绍了FePt薄膜近年来的研究结果，分析了其大矫顽力的机制、降低有序化温度、控制易磁化轴取向、降低粒子间相互作用的方法等对磁存储至关重要的问题，并对其在磁存储中的应用前景作了分析。

That Whole Business about the Cross

digital audio recording

Development of pure and doped gamma ferric oxide

Optimum conditions and experimental details for the formation of v-Fe203 from goethite have been worked out. In another method, a cheap complexing medium of starch was employed for precipitating acicular ferrous oxalate, which on decomposition in nitrogen and subsequent oxidation yielded acicular y-Fe203. On the basis of thermal decomposition in dry and moist nitrogen, DTA, XRD, GC and thermodynamic arguments, the mechanism of decomposition was elucidated. New materials obtained by doping ~'-Fe203 with 1-16 atomic percent magnesium, cobalt, nickel and copper, were synthesised and characterized

Digitales stochastisches Magnetfeld-Sensorarray

Digitales stochastisches Magnetfeld-Sensorarray Stefan Rohrer Im Rahmen eines mehrjährigen Forschungsprojektes, gefördert von der Deutschen Forschungsgesellschaft (DFG), wurden am Institut für Mikroelektronik (IPM) der Universität Kassel digitale Magnetfeldsensoren mit einer Breite bis zu 1 µm entwickelt. Die vorliegende Dissertation stellt ein aus diesem Forschungsprojekt entstandenes Magnetfeld-Sensorarray vor, das speziell dazu entworfen wurde, um digitale Magnetfelder schnell und auf minimaler Fläche mit einer guten räumlichen und zeitlichen Auflösung zu detektieren. Der noch in einem 1,0µm-CMOS-Prozess gefertigte Test-Chip arbeitet bis zu einer Taktfrequenz von 27 MHz bei einem Sensorabstand von 6,75 µm. Damit ist er das derzeit kleinste und schnellste digitale Magnetfeld-Sensorarray in einem Standard-CMOS-Prozess. Konvertiert auf eine 0,09µm-Technologie können Frequenzen bis 1 GHz erreicht werden bei einem Sensorabstand von unter 1 µm. In der Dissertation werden die wichtigsten Ergebnisse des Projekts detailliert beschrieben. Basis des Sensors ist eine rückgekoppelte Inverter-Anordnung. Als magnetfeldsensitives Element dient ein auf dem Hall-Effekt basierender Doppel-Drain-MAGFET, der das Verhalten der Kippschaltung beeinflusst. Aus den digitalen Ausgangsdaten kann die Stärke und die Polarität des Magnetfelds bestimmt werden. Die Gesamtanordnung bildet einen stochastischen Magnetfeld-Sensor. In der Arbeit wird ein Modell für das Kippverhalten der rückgekoppelten Inverter präsentiert. Die Rauscheinflüsse des Sensors werden analysiert und in einem stochastischen Differentialgleichungssystem modelliert. Die Lösung der stochastischen Differentialgleichung zeigt die Entwicklung der Wahrscheinlichkeitsverteilung des Ausgangssignals über die Zeit und welche Einflussfaktoren die Fehlerwahrscheinlichkeit des Sensors beeinflussen. Sie gibt Hinweise darauf, welche Parameter für das Design und Layout eines stochastischen Sensors zu einem optimalen Ergebnis führen. Die auf den theoretischen Berechnungen basierenden Schaltungen und Layout-Komponenten eines digitalen stochastischen Sensors werden in der Arbeit vorgestellt. Aufgrund der technologisch bedingten Prozesstoleranzen ist für jeden Detektor eine eigene kompensierende Kalibrierung erforderlich. Unterschiedliche Realisierungen dafür werden präsentiert und bewertet. Zur genaueren Modellierung wird ein SPICE-Modell aufgestellt und damit für das Kippverhalten des Sensors eine stochastische Differentialgleichung mit SPICE-bestimmten Koeffizienten hergeleitet. Gegenüber den Standard-Magnetfeldsensoren bietet die stochastische digitale Auswertung den Vorteil einer flexiblen Messung. Man kann wählen zwischen schnellen Messungen bei reduzierter Genauigkeit und einer hohen lokalen Auflösung oder einer hohen Genauigkeit bei der Auswertung langsam veränderlicher Magnetfelder im Bereich von unter 1 mT. Die Arbeit präsentiert die Messergebnisse des Testchips. Die gemessene Empfindlichkeit und die Fehlerwahrscheinlichkeit sowie die optimalen Arbeitspunkte und die Kennliniencharakteristik werden dargestellt. Die relative Empfindlichkeit der MAGFETs beträgt 0,0075/T. Die damit erzielbaren Fehlerwahrscheinlichkeiten werden in der Arbeit aufgelistet. Verglichen mit dem theoretischen Modell zeigt das gemessene Kippverhalten der stochastischen Sensoren eine gute Übereinstimmung. Verschiedene Messungen von analogen und digitalen Magnetfeldern bestätigen die Anwendbarkeit des Sensors für schnelle Magnetfeldmessungen bis 27 MHz auch bei kleinen Magnetfeldern unter 1 mT. Die Messungen der Sensorcharakteristik in Abhängigkeit von der Temperatur zeigen, dass die Empfindlichkeit bei sehr tiefen Temperaturen deutlich steigt aufgrund der Abnahme des Rauschens. Eine Zusammenfassung und ein ausführliches Literaturverzeichnis geben einen Überblick über den Stand der Technik.

Carbon-decorated FePt nanoparticles

FePt magnetic nanoparticles are an important candidate material for many future magnetic applications. FePt exists as two main phases, that is, a disordered face-centered cubic (fcc) structure, which is generally prepared by chemical methods at low temperatures, and the high-temperature chemically ordered face-centered tetragonal (fct) structure. The fee FePt, with low coercivity but associated with superparamagnetic properties, may find applications as a magnetic fluid or as a nanoscale carrier for chemical or biochemical species in biomedical areas, while fct FePt is proposed for use in ultrahigh-density magnetic recording applications. However, for both of these applications an enhancement of the intrinsically weak magnetic properties, the avoidance of magnetic interferences from neighbor particles, and the improved stability of the small magnetic body remain key practical issues. We report a simple synthetic method for producing FePt nanoparticles that involves hydrothermal treatment of Fe and Pt precursors in glucose followed by calcination at 900 degrees C. This new method produces thermally stable spheroidal graphite nanoparticles (large and fullerene-like) that encapsulate or decorate FePt particles of ca. 5 nm with no severe macroscopic particle coalescence. Also, a low coercivity of the material is recorded; indicative of small magnetic interference from neighboring carbon-coated particles. Thus, this simple synthetic method involves the use of a more environmentally acceptable glucose/aqueous phase to offer a protective coating for FePt nanoparticles. It is also believed that such a synthetic protocol can be readily extended to the preparation of other graphite-coated magnetic iron alloys of controlled size, stoichiometry, and physical properties.

Synthesis and fabrication of a thin film containing silica-encapsulated face-centered tetragonal FePt nanoparticles

Self-assembly of monodisperse, silica-encapsulated, face-centered tetragonal FePt nanoparticles forms closely packed 2D arrays (see figure). Placing monodisperse FePt nanoparticles in silica nanocapsules allows the transition from a disordered face-centered cubic phase to a ferromagnetic crystalline face-centered tetragonal structure at elevated temperature without severe sintering. These materials are potential candidates for the generation of ultrahigh-density magnetic recording media.

Perpendicularly self-oriented and shape-controlled L1(0)-FePt nanorods directly synthesized by a temperature-modulated process

The synthesis and self-assembly of tetragonal phase-containing L1(0)-Fe(55)Pt(45) nanorods with high coercive field is described. The experimental procedure resulted in a tetragonal/cubic phase ratio close to 1:1 for the as-synthesized nanoparticles. Using different surfactant/solvent proportions in the process allowed control of particle morphology from nanospheres to nanowires. Monodisperse nanorods with lengths of 60 +/- 5 nm and diameters of 2-3 nm were self-assembled in a perpendicular oriented array onto a substrate surface using hexadecylamine as organic spacer. Magnetic alignment and properties assigned, respectively, to the shape anisotropy and the tetragonal phase suggest that the self-assembled materials are a strong candidate to solve the problem of random magnetic alignment observed in FePt nanospheres leading to applications in ultrahigh magnetic recording (UHMR) systems capable of achieving a performance of the order of terabits/in(2).

Formation Mechanism via a Heterocoagulation Approach of FePt Nanoparticles Using the Modified Polyol Process

Herein, we report a new approach of an FePt nanoparticle formation mechanism studying the evolution of particle size and composition during the synthesis using the modified polyol process. One of the factors limiting their application in ultra-high-density magnetic storage media is the particle-to-particle composition, which affects the A1-to-L1(0) transformation as well as their magnetic properties. There are many controversies in the literature concerning the mechanism of the FePt formation, which seems to be the key to understanding the compositional chemical distribution. Our results convincingly show that, initially, Pt nuclei are formed due to reduction of Pt(acac)(2) by the diol, followed by heterocoagulation of Fe cluster species formed from Fe(acac)(3) thermal decomposition onto the Pt nuclei. Complete reduction of heterocoagulated iron species seems to involve a CO-spillover process, in which the Pt nuclei surface acts as a heterogeneous catalyst, leading to the improvement of the single-particle composition control and allowing a much narrower compositional distribution. Our results show significant decreases in the particle-to-particle composition range, improving the A1-to-L1(0) phase transformation and, consequently, the magnetic properties when compared with other reported methods.

Filmes nanométricos de FeN e ALN crescidos por sputtering e aplicações do efeito peltier

This study will show the capability of the reactive/nonreactive sputtering (dc/rf) technique at low power for the growth of nanometric thin films from magnetic materials (FeN) and widegap semiconductors (AlN), as well as the technological application of the Peltier effect using commercial modules of bismuth telluride (Bi2Te3). Of great technological interest to the high-density magnetic recording industry, the FeN system represents one of the most important magnetic achievements; however, diversity of the phases formed makes it difficult to control its magnetic properties during production of devices. We investigated the variation in these properties using ferromagnetic resonance, MOKE and atomic force microscopy (AFM), as a function of nitrogen concentration in the reactive gas mixture. Aluminum nitride, a component of widegap semiconductors and of considerable interest to the electronic and optoelectronic industry, was grown on nanometric thin film for the first time, with good structural quality by non-reactive rf sputtering of a pure AlN target at low power (≈ 50W). Another finding in this study is that a long deposition time for this material may lead to film contamination by materials adsorbed into deposition chamber walls. Energy-dispersive X-ray (EDX) analysis shows that the presence of magnetic contaminants from previous depositions results in grown AlN semiconductor films exhibiting magnetoresistance with high resistivity. The Peltier effect applied to commercially available compact refrigeration cells, which are efficient for cooling small volumes, was used to manufacture a technologically innovative refrigerated mini wine cooler, for which a patent was duly registered

Temperature dependence and magnetocrystalline anisotropy studies of self-assembled L1(0)-Fe55Pt45 ferromagnetic nanocrystals

Temperature dependence and uniaxial magnetocrystalline anisotropy properties of the chemically synthesized 4 nm L1(0)-Fe55Pt45 nanoparticle assembly by a modified polyol route are reported. As-prepared nanoparticles are superparamagnetic presenting fcc structure, and annealing at 550 degrees C converts the assembly into ferromagnetic nanocrystals with large coercivity (H-C>1 T) in an L1(0) phase. Magnetic measurements showed an increasing in the ferromagnetically ordered fraction of the nanoparticles with the annealing temperature increases, and the remanence ratio, S=M-R/M-S congruent to 0.76, suggests an (111) textured film. A monotonic increase of the blocking temperature T-B, the uniaxial magnetocrystalline anisotropy constant K-U, and the coercivity H-C with increasing annealing temperature was observed. Magnetic parameters indicate an enhancement in the magnetic properties due to the improved Fe55Pt45 phase stabilizing, and the room-temperature stability parameter of 67, which indicates that the magnetization should be stable for more than ten years, makes this material suitable for ultrahigh-density magnetic recording application.(c) 2007 American Institute of Physics.

Colloidal particles: Spherical yttrium iron garnet

The purpose of this work is to obtain spherical particles YIG from micrometric to nanometric scales. The spherical particles were obtained from cation hydrolysis in acid medium by adding urea or ammonia in order to carry out a homogeneous nucleation process up to 90 degrees C. Different composition and morphology were achieved by changing reactant concentrations, precipitation agent and stabilizing agent. X-ray diffractometry, electrophoretic mobility, transmission and scanning electron microscopies were carried out on these particles to investigate the phase identification, mobility, morphology and particle size. Crystalline YIG, with spherical characteristics, was obtained. The surface potential presented different characteristics for different dispersion media.

Monodispersed spindle-type goethite nanoparticles from Fe-III solutions

A new synthetic route for producing monodispersed and single crystal acicular goethite particles with small particle size and a high axial ratio adequate for use as a high density magnetic recording media precursor is reported. It essentially consists of the hydrolysis of alkaline Fe-III suspensions in the presence of carbonate by a three-step procedure, the formation of ferrihydrite primary particles, the ferrihydrite dissolution and nucleation of goethite, and the growth of the goethite nuclei. Changing the temperature of heating during ageing achieved a separation of the two last stages. X-Ray diffraction, transmission electron microscopy, infrared spectroscopy and surface area data have been used to determine the mechanism responsible for the formation of goethite particles with controlled size and shape. The best conditions to prepare monodispersed goethite particles have been established. The results show that uniform goethite particles of (a) 60 nm length with an axial ratio of 6 and (b) 230 nm length with a high axial ratio of 10, can be obtained by using an [OH]/[Fe] molar ratio of 0.35 in the initial suspensions with carbonate or sodium hydroxide, respectively. The [OH]/[Fe] molar ratio determines the particle size and elongation by controlling the hydrolysis reaction rate, while the carbonate ions promote a constant [OH] in the solution, keeping the pH around 10 during the entire synthesis process. This procedure, associated with the appropriate temperature control, leads, under certain conditions, to highly homogeneous goethite particles with sizes smaller than those obtained using sodium hydroxide with the same [OH]/[Fe] ratio.

Análise da influência dos movimentos verticais e horizontais das barras de um pulverizador na aplicação da calda

Pós-graduação em Agronomia (Energia na Agricultura) - FCA

Estratégias para o ensino inclusivo de alunos com deficiência nas aulas de educação física

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)