黄土高原中部60万年来黄土—古土壤序列有机碳同位素研究

Vegetation is very sensitive to climate change. Carbon isotopes in paleosol have been widely used to contruct the propotion of plants using C3 and C4 photosynthetic pathways. δ13C of Loess organic matter were analyzed on the loess- paleosols samples from Jingchuan sections and Luochuan S4—S5 sequence. This paper presents a long carbon isotope time series, covering the last 600kyr. δ13C record of Loess organic matter in Jingchuan is correlated with marine oxygen isotope records. Basing on former research work, this paper discusses temperature, rainfall and P CO2 effect on δ13Corg value. In the interglacial periods, carbon isotope is more sensitive than other proxies and indicates several climate fluctuations. The main conclusions are as follows: 1. Obtained δ13C composition from paleosols and loess sediments in Jingchuan range of -20.0‰ to -24.6‰, the maximum biomass of C4 is 35%, indicating a C3 and C4 mixed steppe with C3 dominated. C4 plant is not always expansion during paleosols periods. The minimum values of Jingchuan section appeared in S4 soil, and the vegetation was almost pure C3 plant at that time. δ13Corg value in S5-2 is also lower than loess in S5, reaching the minimum valus of S5 soil. 2. PCO2 variation has little impact on δ13Corg value in interglacial periods for the last 600kyr. The correlation between δ13Corg value curve and magnetic susceptibility curve as proxy of summer monsoon in general, means summer monsoon drive C4 plant expansion during glacial and interglacial. 3. The lowerδ13Corg values in S4 and S5-2 appear at Jingchuan and Luochuan, suggest origin from woodland or C3 grassland. Whatever vegetation it is, indicate strengthened East Asian summer monsoon and increase of precipitation. C4 plant percentage is lower in S5-1 and S1 which have stronger summer monsoon, than S0 and S2. And it also indicates increase of precipitation.δ13Corg values has not always non-linearity correlation with summer monsoon. 4. The maximum entroy spectral analysis of δ13C values of the last 600kyr indicates there is 21 kyr cycles in Loess sequence. It means that summer monsoon in the Chinese Loess Plateau also has the precession cycles like its origin low latitude.

藏北措勤盆地白垩纪碳酸盐岩沉积相及缺氧事件响应研究

As a part of Gangdisi-Nianqingtanggula plate, Cuoqin basin (N 29°3O'～33°20'; E 80°～90°) is situated in the west of the Tibet autonomous Region, with an area of 100000 square kilometers. Cretaceous shallow-water carbonate is widely distributed in this basin. Its accumulative thickness is more than 1000 meters. Sedimentary facies of cretaceous shallow-water carbonate and carbon isotope feature are studied in details here. On basis of two main sections researched comprehensively, five facies marks are found. With the combination of Wilson's model and ramp model, a platform-mild slope model are put forward, which is thought to be a comprehensive model for this area. There are three sedimentary circles which are comprised of terrestrial clastic tidal flat and carbonate platform facies in Duoba Member of Duoni Formation. Langshan Formation is mainly comprised of carbonate platform facies. We also studied the carbon isotope features influenced by Cretaceous Aptian-Albian's oceanic anoxic events (OAE). After correlating the δ~(13)C curves of the studied section with that of Peregrina Canyon section in Mexico, we find that there are similar δ~(13)C curves fluctuation styles, namely there is also a δ~(13)C positive excursion in shallow-water carbonate in the studied area, and the degree of δ~(13)C positive excursion in shallow-water carbonate is much higher. There are two main causes which should interpret above δ~(13)C positive excursion feature: on the one hand ,much organic carbon take much 12C off when they are buried with a higher speed during the OAE, which lead to the ~(12)C rise of oceanic total dissolved carbon (TDC),on the other hand, during the OAE there are stratification structures in pale-ocean, in the upper mixed layer with high carbon fixation (HCML). There are so much plankton organisms which absorb much ~(12)C as the ~(13)C of shallow-water carbonate in this layer rise higher. Furthermore, on the basis of the theories of carbonate isotope strata, we suggest that the currently used boundary between Aptian and Albian in the studied area is possibly above the international one, which means the main parts of Duoba Member of Duoni Foramatiom in this area should be belong to Albian in stead of Aptian.

Application of liquid pre-column capillary electrophoresis technique to the study of interaction between drug enantiomers and human serum albumin

Based on the chiral separation of several basic drugs, dimetindene, tetryzoline, theodrenaline and verapamil, the liquid pre-column capillary electrophoresis (LPC-CE) technique was established. It was used to determine free concentrations of drug enantiomers in mixed solutions with human serum albumin (HSA). To prevent HSA entering the CE chiral separation zone, the mobility differences between HSA and drugs under a specific pH condition were employed in the LPC. Thus, the detection confusion caused by protein was totally avoided. Further study of binding constants determination and protein binding competitions was carried out. The study proves that the LPC technique could be used for complex media, particularly the matrix of protein coexisting with a variety of drugs.

Implantes em zircónio

Monografia apresentada à Universidade Fernando Pessoa para obtenção do grau de Licenciado em Medicina Dentária

TRADITION AND INNOVATION: ANALYSIS AND PERFORMANCE OF SELECTED COMPOSITIONS FOR VIOLONCELLO BY HEITOR VILLA-LOBOS

Brazilian composer Heitor Villa-Lobos (1887-1959) began his musical career as a cellist. When he was only twelve years old, it became imperativeupon the sudden and untimely death of his fatherthat the young Villa-Lobos earn money as a cellist to provide financial support for his mother and sisters. Villa-Lobos's intimate relationship with the cello eventually inspired him to compose great music for this instrument. This dissertation explores both the diversity of compositional technique and the evolution of style found in the music for cello written by Villa-Lobos. The project consists of two recorded recital performances and a written document exploring and analyzing those pieces. In the study of the music of Villa-Lobos, it is of great interest to consider the music's traditional European elements in combination (or even juxtaposition) with its imaginative and sometimes wildly innovative Brazilian character. His early works were greatly influenced by European Romantic composers such as Robert Schumann, Frédéric Chopin, and the virtuoso cellist/composer David Popper (whom Villa-Lobos idolized). Later, Villa-Lobos flourished in a newfound compositional independence and moved away from Euro-romanticism and toward the folk music of his Brazilian homeland. It is intriguing to experience this transition through an exploration of his cello compositions. The works examined and performed in this dissertation project are chosen from among the extensive number of Villa-Lobos's cello compositions and are his most important works for cello with piano, cello with another instrument, and cello with orchestra. The chosen works demonstrate the evolving range and combination of characteristic elements found in Villa-Lobos's compositional repertoire.

THE DISTINCTIVE VOICE OF PAUL HINDEMITH THROUGH THE VIOLA

Paul Hindemith has made numerous contributions to the viola, both as a composer and performer. As a composer, he has written 7 sonatas for the viola, as well as a number of chamber and orchestral works which feature the viola as a solo instrument. As a violist, Hindemith was one of the only virtuoso soloists of his lifetime, and premiered virtually all of his solo compositions. Many of his pieces remain an integral part of the viola repertoire; Der Schwanendreher is one of the three major Twentieth-Century concertos for the viola. While some of his pieces are well-known, there are many others which are not performed with much frequency, due in part to the sheer output of this prolific composer. In this dissertation project, I performed Hindemith's compositions for the viola as a solo instrument. Consideration was given to exclusively performing his 4 solo sonatas and 3 sonatas for viola and piano. His only viola duet, his only non-sonata written for viola and piano, and 2 of his viola concertos (Der Schwanendreher and Trauermusik) were included in this dissertation project to provide contrast and supplement the three recital programs. Through this dissertation project I have been able to gain a deeper understanding of the complex language of Hindemith and interpret his music in an approach that is accessible to both the performer and the audience. All performances took place in the Gildenhom Recital Hall and Ulrich Recital Hall at the University of Maryland. All collaborations with piano were performed with Eliza Ching. The Duett for Viola and Violoncello was performed with Daniel Shomper, and the assisting musicians performing in the Trauermusik were Joel Ciaccio, Daniel Sender, Daniel Shomper, Cassandra Stephenson and Dana Weiderhold.

INNOVATIONS IN FRENCH CHAMBER MUSIC AND MÉLODIE (1886 – 1962) – A COLLABORATIVE PIANIST’S PERSPECTIVE

French chamber music in the last quarter of the nineteenth century displayed significant advances in musical innovations and technical developments. As the Parisian public began to favor instrumental music and mélodie over opera, vocal and chamber music with piano became one of the main genres to express French composers’ creativity and individuality. The composers Franck, Debussy, Fauré, Duparc, Ravel, Chausson and Poulenc were the major contributors to this unusually creative period in French music. French mélodies of this period blend precision with lyricism, and demand the performer’s elegance and wit. They show careful settings of the French language’s rhythmic subtleties and increased expressiveness in and importance of the piano accompaniment. The chamber works of this period demanded superior pianistic and instrumental virtuosity while displaying wide ranges of sonority, multiple tone colors, and rhythmic fluidity. The three recitals which comprise this dissertation project were performed at the University of Maryland Gildenhorn Recital Hall on 27 October 2006, All Nations Mission Church (Dayton, NJ) on 5 December 2009, and the Leah M. Smith Lecture Hall of the University of Maryland on 11 May 2010. The repertoire included Poulenc’s Sonata for Oboe and Piano (1962) with oboist Yeongsu Kim, French mélodies by Fauré, Chausson, Debussy, Ravel and Duparc with soprano Jung-A Lee and baritone Hyun-Oh Shin, Poulenc’s Sextet for Piano, Flute, Oboe, Clarinet, Bassoon and Horn (1932-1939) with flutist Katrina Smith, clarinetist Jihoon Chang, bassoonist Erich Heckscher, hornist Heidi Littman and oboist Yeongsu Kim, Debussy’s Sonata for Cello and Piano (1915) with cellist Ji-Sook Shin, Poulenc’s Sonata for Violin and Piano (1942-1949) with violinist Ji-Hee Lim, Franck’s Sonata for Violin and Piano (1886) with violinist Na-Young Cho, Ravel’s Piano Trio (1915) with cellist Ji-Sook Shin and violinist Yu-Jeong Lee and Ravel’s Sonata for Violin and Piano (1927) with violinist Yu-Jeong Lee. The recitals were recorded on compact discs and are archived within the Digital Repository at the University of Maryland (DRUM).

Tracking leatherback turtles (Dermochelys coriacea) during consecutive inter-nesting intervals: Further support for direct transmitter attachment

Over recent years there have been substantial efforts to record and interpret the post-nesting movements of leatherback turtles (Dermochelys coriacea) breeding in tropical regions. Less well documented are the movements undertaken by individual turtles during the breeding season itself, or more specifically between sequential nesting events. Such movements are of interest for two reasons: (1) gravid female leatherbacks may range extensively into the territorial waters and nesting beaches of neighbouring countries, raising questions for conservationists and population ecologists; and (2) the magnitude of movements themselves help elucidate underlying reproductive strategies (e.g. whether to rest near to the nesting or forage extensively). Here, satellite relay data loggers are used (SRDLs) to detail the movements and behaviour of two female leatherback turtles throughout three consecutive inter-nesting intervals in the Commonwealth of Dominica, West Indies. Both near-shore residence and extensive inter-nesting movements were recorded, contrasting previous studies, with movements away from the nesting beach increasing towards the end of the nesting season. Using this behavioural study as a backdrop, the suitability of attaching satellite transmitters directly to the carapace was additionally explored as an alternative approach to conventional harness deployments. Specifically, the principal aims were to (1) gather empirical data on speed of travel and (2) assess dive performance (aerobic dive limit) to enable comparisons with turtles previously fitted with harnesses elsewhere in the Caribbean (n = 6 turtles; Grenada, WI). This produced mixed results with animals bearing directly attached transmitters travelling significantly faster (55.21 km day(-1): SD 6.68) than harnessed individuals (39.80 km day(-1); SD 6.19); whilst no discernable difference in dive performance could be found between the two groups of study animals. (C) 2009 Elsevier B.V. All rights reserved.

Carbon chemistry in Galactic bulge planetary nebulae

Galactic bulge planetary nebulae show evidence of mixed chemistry with emission from both silicate dust and polycyclic aromatic hydrocarbons (PAHs). This mixed chemistry is unlikely to be related to carbon dredge-up, as third dredge-up is not expected to occur in the low-mass bulge stars. We show that the phenomenon is widespread and is seen in 30 nebulae out of 40 of our sample, selected on the basis of their infrared flux. Hubble Space Telescope (HST) images and Ultraviolet and Visual Echelle Spectrograph (UVES) spectra show that the mixed chemistry is not related to the presence of emission-line stars, as it is in the Galactic disc population. We also rule out interaction with the interstellar medium (ISM) as origin of the PAHs. Instead, a strong correlation is found with morphology and the presence of a dense torus. A chemical model is presented which shows that hydrocarbon chains can form within oxygen-rich gas through gas-phase chemical reactions. The model predicts two layers, one at A_V~ 1.5, where small hydrocarbons form from reactions with C+, and one at A_V~ 4, where larger chains (and by implication, PAHs) form from reactions with neutral, atomic carbon. These reactions take place in a mini-photon-dominated region (PDR). We conclude that the mixed-chemistry phenomenon occurring in the Galactic bulge planetary nebulae is best explained through hydrocarbon chemistry in an ultraviolet (UV)-irradiated, dense torus.

Galactic Bulge PNe:Carbon molecules in oxygen-rich environments

Galactic bulge planetary nebulae show evidence of mixed chemistry with emission from both silicate dust and PAHs. This mixed chemistry is unlikely to be related to carbon dredge up, as third dredge-up is not expected to occur in the low mass bulge stars. We show that the phenomenon is widespread, and is seen in 30 nebulae out of our sample of 40. A strong correlation is found between strength of the PAH bands and morphology, in particular, the presence of a dense torus. A chemical model is presented which shows that hydrocarbon chains can form within oxygen-rich gas through gas-phase chemical reactions. We conclude that the mixed chemistry phenomenon occurring in the galactic bulge planetary nebulae is best explained through hydrocarbon chemistry in an UV-irradiated, dense torus. © 2012 International Astronomical Union.

A systematic review and meta-analysis of the ethnic density effect in psychotic disorders

A number of studies have found an ethnic density effect in psychotic disorders, where the incidence for ethnic minorities increases as the neighbourhood proportional ethnic composition decreases [Morgan and Hutchinson, Psychol Med 40:705-709, (2010); Singh, Psychol Med 39:1402-1403, (2009); Schofield et al., Psychol Med 41:1263-1269, (2010)]. However, there is a mixed picture with some studies reporting no effect [Schofield et al., Psychol Med 41:1263-1269, (2010)]. This review aimed to establish the existence of the effect by answering the review question: is there an ethnic density dose effect in the prevalence of psychotic disorders?

Testing the Prebisch–Singer hypothesis since 1650: Evidence from panel techniques that allow for multiple breaks

In this paper, we re-examine two important aspects of the dynamics of relative primary commodity prices, namely the secular trend and the short run volatility. To do so, we employ 25 series, some of them starting as far back as 1650 and powerful panel data stationarity tests that allow for endogenous multiple structural breaks. Results show that all the series are stationary after allowing for endogenous multiple breaks. Test results on the Prebisch–Singer hypothesis, which states that relative commodity prices follow a downward secular trend, are mixed but with a majority of series showing negative trends. We also make a first attempt at identifying the potential drivers of the structural breaks. We end by investigating the dynamics of the volatility of the 25 relative primary commodity prices also allowing for endogenous multiple breaks. We describe the often time-varying volatility in commodity prices and show that it has increased in recent years.

Correlação entre argamassas e betões com base em análise reométrica

O presente trabalho teve como objetivo principal estudar a correlação no estado fresco e no estado endurecido entre argamassas e betões com pozolanas, nomeadamente, um metacaulino e uma diatomite. Este trabalho procurou também otimizar a utilização dos materiais pozolânicos na produção de argamassas e betões. O estudo do comportamento reológico inicia-se com a avaliação da argamassa padrão e do betão padrão, utilizando para tal reómetros adequados a cada material. O comportamento reológico das argamassas com pozolanas foi analisado em função do comportamento da argamassa padrão. Verificou-se que é possível ajustar o comportamento reológico de argamassas com pozolanas ao comportamento da argamassa padrão e, deste modo, obter-se também betões correspondentes (com pozolanas) dentro do intervalo de trabalhabilidade pretendido e pré-definido para o betão padrão. Também foi possível concluir que, até um determinado teor de material pozolânico, se verificava uma correlação entre os parâmetros reológicos (viscosidade e tensão de cedência) das argamassas e os seus betões correspondentes. Na caracterização das argamassas e betões no estado endurecido, verificou-se a existência de uma correlação entre a resistência à compressão das argamassas e as resistências dos betões correspondentes para a maioria das formulações. Quando o ajuste de trabalhabilidade foi efetuado através da alteração do teor de água, apenas as formulações com metacaulino apresentavam uma relação linear entre as resistências das argamassas e a dos betões correspondentes. Usando um agente redutor de água de amassadura para o ajuste de trabalhabilidade, as formulações com metacaulino continuam a apresentar uma relação linear entre as resistências das argamassas e as resistências dos betões. As formulações mistas, com metacaulino e diatomite, também apresentam uma relação linear entre o valor das resistências das argamassas e dos betões. As composições com diatomite não mostram esta relação linear entre a resistência das argamassas e a resistência dos betões, embora exista uma correlação entre elas. O estudo de algumas propriedades no estado endurecido de betões mostrou que a utilização de água como elemento de ajuste de trabalhabilidade diminui sempre a resistência à compressão dos betões com o aumento do teor em pozolana. O uso de um agente redutor de água de amassadura, principalmente no caso da utilização do metacaulino, aumenta a resistência dos betões face ao padrão devido à sua maior reatividade pozolânica relativamente à diatomite. Estas tendências para os resultados observados na resistência mecânica foram também visíveis no módulo de elasticidade e justificáveis pela evolução da microestrutura avaliada conjuntamente por porosimetria, análises térmicas e microscopia eletrónica de varrimento. Finalmente, no estudo da influência dos materiais pozolânicos sobre a durabilidade dos betões, especificamente sobre a resistência à penetração de cloretos, ambas as pozolanas mostraram um efeito bloqueador à penetração de cloretos e, também aqui esse efeito foi mais evidente em composições com metacaulino e na presença de um agente redutor de água de amassadura.

Entangled semantics

In the context of monolingual and bilingual retrieval, Simple Knowledge Organisation System (SKOS) datasets can play a dual role as knowledge bases for semantic annotations and as language-independent resources for translation. With no existing track of formal evaluations of these aspects for datasets in SKOS format, we describe a case study on the usage of the Thesaurus for the Social Sciences in SKOS format for a retrieval setup based on the CLEF 2004-2006 Domain-Specific Track topics, documents and relevance assessments. Results showed a mixed picture with significant system-level improvements in terms of mean average precision in the bilingual runs. Our experiments set a new and improved baseline for using SKOS-based datasets with the GIRT collection and are an example of component-based evaluation.

Relatório de estágio

I (Prática Pedagógica) - O estágio foi realizado na Academia de Música de Almada (AMA) com três alunos de níveis diferentes: Aluno x, Iniciação Musical; Aluna y, 2º grau; e Aluna z, 5º grau. A planificação do trabalho foi feita com a colaboração do professor Vasco Broco e sob a supervisão do professor Pedro Saglimbeni Muñoz, tendo por base o programa da AMA e procurando corresponder às necessidades individuais de cada aluno, bem como respeitar os diferentes ritmos de aprendizagem. Dadas as diferenças de idade e de nível, os objectivos que procurei atingir com cada aluno durante o ano lectivo são naturalmente díspares, bem como a perspectiva de cada um em relação ao próprio instrumento e ao ensino da música. Enquanto que os mais novos encaram a aprendizagem musical como uma actividade meramente recreativa, pelo menos por enquanto, a Aluna z ambiciona fazer uma carreira como instrumentista. Mesmo entre os mais novos há diferenças, pois apesar de o Aluno x ainda estar a frequentar a Iniciação Musical, já iniciou a sua aprendizagem há mais tempo do que a Aluna y, encarando o ensino com mais seriedade. A AMA tem a vantagem de ter um pianista acompanhador disponível para cada dia da semana, o que tornou possível desenvolver um trabalho consistente com os alunos em termos de ensaios e audições. As audições e momentos de avaliação foram marcados em reuniões de Departamento Curricular, à excepção da calendarização das Provas Globais que foi feita em reunião de Conselho Pedagógico. O aproveitamento foi positivo para os três alunos no final do estágio, tendo todos transitado para o nível de ensino seguinte.