植物生活史繁殖对策与干扰关系的研究

植物生活史繁殖对策研究是涉及植物的适应或进化、生态系统退化与恢复过程、生物多样性保护等多方面理论生态学和应用生态学研究内容的生态学研究领域 .按Grime的植物生活史繁殖对策分类、植物营养繁殖与干扰适应、种子形态学与干扰适应、土壤种子库与干扰适应、植物繁殖体传播和萌发与干扰适应论述了当今极受关注的植物生活史繁殖对策与干扰关系 ,简述了我国干旱区干扰与植物生活史繁殖对策关系研究

基于桶内动态融合的透明现象的高效绘制

基于桶排序的顺序独立透明现象绘制算法,采用桶排序原理将投影收集到同一个像素上的多个片元并排序,当发生桶内片元冲突时会产生错误的绘制结果.为此,提出一种基于桶内动态融合的透明现象的高效绘制算法.此算法采用桶内动态融合和并发读/写的方法逐一融合落入同一个桶内的所有片元,并在后处理中按从前向后的顺序融合各个桶内的颜色值.由于同时发生桶内片元冲突和读/写冲突的概率非常小,因而可以大大提高绘制结果的准确性.实验结果表明,与基于桶排序的绘制算法相比,采用文中算法可以更准确地绘制场景,生成与真实结果非常相近的绘制效果,同时算法的效率基本保持不变.

Bulk ultrafine binderless (W0.4Al0.6)C prepared by high pressure sintering

Pure (W0.4Al0.6)C powder of about 1 mu m in diameter was sintered by the high pressure sintering (HPS) process without the addition of any binder phase. The microstructure, Vickers micro hardness and density versus the sintering time and temperature are well described. The most suitable sintering condition under pressure of 4.5 GPa is 1873 K for 8 min. Under this sintering condition, the hardness can reach 2295 kg mm(-2) and the relative density can reach 98.6%.

硬脂酸聚氧乙烯酯与聚乙烯接枝共聚物的制备与表征

以聚氧乙烯为起始原料,合成了一系列硬脂酸聚氧乙烯酯及其丙烯酸酯,用FTIR和1H NMR测试技术对其结构进行了表征,用最大气泡法测定了其表面张力.以其作为接枝单体,利用反应挤出接枝方法制备了系列功能化聚乙烯,用FTIR确定了接枝共聚物的结构和接枝率;用DSC、接触角测量仪对接枝共聚物的热性能、结晶行为和表面性质进行了测试分析。结果表明,含有不同分子量(200、600、1 000、2 000和6 000)聚氧乙烯的硬脂酸聚氧乙烯酯的表面张力分别为30.19、32.22、35.30、38.39和43.37 mN/m;相应的聚乙烯接枝共聚物的结晶温度分别为109.30、109.08、110.18、109.74和109.74℃,水接触角分别为81.06°、70.10°、72.25°、76.40°和95.55°。随着聚氧乙烯分子量的增加,表面活性剂的表面活性降...

杂多化合物及其负载型催化剂的研究进展

详细介绍了杂多化合物及其负载型催化剂的研究进展并对不同的催化剂载体进行了总结。对杂多化合物与载体之间的相互作用以及杂多化合物催化剂的反应机理进行了讨论。

桥联聚倍半硅氧烷的近期研究进展——单体合成及应用

桥联聚倍半硅氧烷作为一种新型的有机 无机杂化材料在近十年的研究中引起了人们的极大关注 ,这种材料的单体可以通过不同的合成方法获得 ,为材料的设计和剪裁提供了极大的便利。本文综述了桥联聚倍半硅氧烷单体的合成方法 ,对其在光学、催化、吸附等方面的应用作了评述 ,同时将发光稀土配合物引入桥联聚倍半硅氧烷的研究作了介绍 ,最后对桥联聚倍半硅氧烷将来的发展趋势作了展望

丙烯在Zr/HZSM-5催化剂上齐聚反应性能的研究

中国科学院山西煤炭化学研究所

Possibility of design of nanodevices by confined macromolecular self-assembly

Computer simulation has revealed that dual nanostructures for the development of nanodevices as nanowires, optical nanofibres and nanobatteries be obtained by the self-assembly of block copolymers confined geometry. The formation of individual nanostructures depends on the structures of block copolymers the confinement geometry and the interactions block copolymers and the boundary of the confinement geometry. In order to obtain individual nanostructures experimentally, attention needs to be paid to the manufacture of the confinement geometry and the design of the interactions between block copolymers and the boundary of the confinement geometry, The recently developed lithography technique should make experiments successful.

Kinetic analysis of TNF immune complex by using surface plasmon resonane

The kinetic analysis of the interaction between tumor necrosis factor(TNF) and its monoclonal antibody was performed by surface plasmon resonance(SPR) technique. The monoclonal antibody was immobilized to the surface of CM5 sensor chip by amine coupling. TNF at different concentrations was injected across the mAb immobilized surface. The interaction was recorded in real time and could be seen on the sensorgram. One cycle, including association, dissociation and regeneration, lasted no more than 15 min. The interaction results was evaluated using 1 : 1 Langmuir binding model. The kinetic rate constants were calculated to be: k =1.68 X 10(3) L (.) mol(-1) (.) s(-1), k(d) = 1.73 X 10(-4) s(-1), and the affinity constants K-A = 9. 7 X 10(3) L (.) mol(-1), K-r)= 1. 03 X 10(-7) Mol (.) L-1. The X-2 was 3.47, which showed that the interaction is consistent with the 1 : I model. We can see from the results that although there are two binding sites in one mAb molecule, TNF reacts with each site in an independent and noncooperative manner.

Determination of surface pK(a) of HS(CH2)(10)COOH SAMs using an electrochemical titration method

The self-assembled monolayer(SAM) of 11-mercaptoundecanoic acid [HS(CH2)(10)COOH] was formed on a gold electrode and the effect of the charge of end group on the electrochemical response of Fe(CN)(6)(3-) at the SAM modified electrode was studied by cyclic voltammetry. At high pH, when the -COOH groups are dissociated, the current of Fe(CN)(6)(3-) is suppressed; as the solution pH is lowered, the current of Fe(CN)(6)(3-) increases. The electrochemical titration curve was obtained by correlating the currents of Fe(CN)(6)(3-) to the different pH values of electrolyte, from which the surface pK(a) was obtained to be 3. 0+/-0. 2. Furthermore, the reason of small pK(a) value was explained using SAMs of different surface coverage.

A ferric molybdenum phosphate with a tunnel: hydrothermal synthesis and structure of (NH3CH2CH2NH3)(2)center dot(NH3CH2CH2NH2)(3)center dot Na center dot[Fe2Mo12O30(PO4)(HPO4)(4)(H2PO4)(3)]center dot 7H(2)O

A new ferric molybdenum phosphate containing a tunnel structure and crystallographically different clusters has been hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction. A probe reaction of the oxidation of acetaldehyde with H2O2 using the tide compound as catalyst was carried out in a liquid-solid system, showing that the title compound had high catalytic activity in the reaction. (C) 1998 Elsevier Science S.A. All rights reserved.

用超微电极研究二茂铁等物质在聚电解质聚乙二醇·高氯酸锂中的伏安行为

用超微电极研究了聚电解质聚乙二醇·高氯酸锂（ＰＥＧ·ＬｉＣｌＯ４）的电化学性能。用伏安法研究了气体、有机小分子、温度、支持电解质、聚合链长的影响。结果表明，有机小分子有增塑效应；物质的扩散速率随温度的上升而增加，随支持电解质中阳离子半径增大而增加，随聚合物链长增加而减小。用粘度和自由体积理论解释了此现象。定性地描述了电子自交换对扩散的贡献。