Mapping atmospheric pollutants emissions in European countries

In this paper we present a methodology which enables the graphical representation, in a bi-dimensional Euclidean space, of atmospheric pollutants emissions in European countries. This approach relies on the use of Multidimensional Unfolding (MDU), an exploratory multivariate data analysis technique. This technique illustrates both the relationships between the emitted gases and the gases and their geographical origins. The main contribution of this work concerns the evaluation of MDU solutions. We use simulated data to define thresholds for the model fitting measures, allowing the MDU output quality evaluation. The quality assessment of the model adjustment is thus carried out as a step before interpretation of the gas types and geographical origins results. The MDU maps analysis generates useful insights, with an immediate substantive result and enables the formulation of hypotheses for further analysis and modeling.

Patching up dipoles: can dipolar particles be viewed as patchy colloids?

We investigate whether the liquid-vapour phase transition of strongly dipolar fluids can be understood using a model of patchy colloids. These consist of hard spherical particles with three short-ranged attractive sites (patches) on their surfaces. Two of the patches are of type A and one is of type B. Patches A on a particle may bond either to a patch A or to a patch B on another particle. Formation of an AA (AB) bond lowers the energy by epsilon AA (epsilon AB). In the limit [image omitted], this patchy model exhibits condensation driven by AB-bonds (Y-junctions). Y-junctions are also present in low-density, strongly dipolar fluids, and have been conjectured to play a key role in determining their critical behaviour. We map the dipolar Yukawa hard-sphere (DYHS) fluid onto this 2A + 1B patchy model by requiring that the latter reproduce the correct DYHS critical point as a function of the isotropic interaction strength epsilon Y. This is achieved for sensible values of epsilon AB and the bond volumes. Results for the internal energy and the particle coordination number are in qualitative agreement with simulations of DYHSs. Finally, by taking the limit [image omitted], we arrive at a new estimate for the critical point of the dipolar hard-sphere fluid, which agrees with extrapolations from simulation.

Wrinkling Labyrinth Patterns on Elastomeric Janus Particles

We describe a novel, low-cost and low-tech method for the fabrication of elastomeric Janus particles with diameters ranging from micrometers to millimeters. This consists of UV-irradiating soft urethane/urea elastomer spheres, which are then extracted in toluene and dried. The spheres are thus composed of a single material: no coating or film deposition steps are required. Furthermore, the whole procedure is carried out at ambient temperature and pressure. Long, labyrinthine corrugations ("wrinkles") appear on the irradiated portions of the particles' surfaces, the spatial periodicity of which can be controlled by varying the sizes of particles. The asymmetric morphology of the resulting Janus particles has been confirmed by scanning electron microscopy, atomic force microscopy, and optical microscopy. We have also established that the spheres behave elastically by performing bouncing tests with dried and swollen spheres. Results can be interpreted by assuming that each sphere consists of a thin, stiff surface layer ("skin") lying atop a thicker, softer substrate ("bulk"). The skin's higher stiffness is hypothesized to result from the more extensive cross-linking of the polymer chains located near the surface by the UV radiation. Textures then arise from competition between the effects of bending the skin and compressing the bulk, as the solvent evaporates and the sphere shrinks.

Políticas públicas municipais na era global: o Programa Município VerdeAzul em questão

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Sigilo bancário

Mestrado em Contabilidade e Gestão das Instituições Financeiras

Os institutos culturais açorianos: uma análise sociológica sobre a comunidade intelectual

Dissertação de Mestrado, Sociologia, 5 de Novembro de 2013, Universidade dos Açores.

Nonmonotonic Magnetic Susceptibility of Dipolar Hard-Spheres at Low Temperature and Density

We investigate, via numerical simulations, mean field, and density functional theories, the magnetic response of a dipolar hard sphere fluid at low temperatures and densities, in the region of strong association. The proposed parameter-free theory is able to capture both the density and temperature dependence of the ring-chain equilibrium and the contribution to the susceptibility of a chain of generic length. The theory predicts a nonmonotonic temperature dependence of the initial (zero field) magnetic susceptibility, arising from the competition between magnetically inert particle rings and magnetically active chains. Monte Carlo simulation results closely agree with the theoretical findings. DOI: 10.1103/PhysRevLett.110.148306

Effective isotropic potential for dipolar hard spheres

A new effective isotropic potential is proposed for the dipolar hard-sphere fluid, on the basis of recent results by others for its angle-averaged radial distribution function. The new effective potential is shown to exhibit oscillations even for moderately high densities and moderately strong dipole moments, which are absent from earlier effective isotropic potentials. The validity and significance of this result are briefly discussed.

Os peregrinos da cidade são: representações sociais de “sem-abrigo” emanadas pela sociedade civil lisboeta

Tomando por noção de espaço público o ambiente ou o território da vida social, que medeia entre a esfera privada e a autoridade pública, onde os cidadãos e as pessoas em geral podem encontrar-se livremente para tocarem ideias, conversarem, passearem, interagirem uns com os outros dentro dos limites impostos pela civilidade pública. E por ‘sem abrigo’ a situação generalizada de vivências que têm em comum o impedimento colectivo ou subjectivo do acesso a uma habitação. Habitação entendida não tanto como casa de família mas como alojamento, encarado como residência ou organização sedentária do espaço. O texto que se apresenta aborda o tema da responsabilização, organização e ocupação do espaço público com base nas representações sociais emanadas pelos representantes de algumas das organizações da sociedade civil lisboeta, que orientam a sua acção para a problçemática daqueles que fazem do espaço público o seu ‘domicílio’.

O espelho da velha: imagens da velhice institucionalizada

Dissertação de Mestrado, Ciências Sociais, 16 de Maio de 2014, Universidade dos Açores.

A trophic analysis of target species of macrobenthos in a subtropical coast community: a taxa relationship essay

Studies on the feeding habits of aquatic organisms are a requirement for the management and sustainable use of marine ecosystems. The aim of the present research was to analyze the habits and trophic similarities of decapods, starfish and fish in order to propose trophic relationships between taxa, using Hennigian methods of phylogenetic systematics. This new grouping hypothesis, based on shared and exclusive food items and food types, corresponds to the broad taxonomic groups used in the analysis. Our results indicate that algae, Mollusca, Polychaeta, Crustacea, Echinodermata and Actinopterygii are the most exploited common resources among the species studied. Starfish were differentiated from other organisms for being stenophagic, and were grouped for feeding on bivalve mollusks. A larger group of fish and crustaceans shares algae and mainly crustaceans as food items. A third group united all eight species of Actinopterygii. This largest subgroup of fish is typically carnivorous, feeding on Anthozoa and a great quantity of Crustacea. Synodus foetens has a special position among fishes, due to its unique feeding on nematodes. A Euclidean distance dendrogram obtained in a previous publication grouped S. foetens with starfish. That result was based on a few non-exclusive shared similarities in feeding modes, as well as on shared absences of items, which are not an adequate grouping factor. Starfish are stenophagic, eating bivalves almost exclusively. Synodus foetens and Isopisthus parvipinnis have restricted food items, and are thus intermediary in relation to starfish, decapods, and other fish, which are euryphagous. The trophic cladogram displays details of food items, whether or not shared by all species. The resulting trophic analysis is consistent with known historical relationships.

Infotainment - interesse público vs interesse do público: estudo de caso das médias e grandes reportagens da SIC

Relatório de estágio apresentado à Escola Superior de Comunicação Social como parte dos requisitos para obtenção de grau de mestre em Jornalismo.

Nanotech thin film photovoltaics

Trabalho Final de Mestrado para obtenção do grau de Mestre em Engenharia de Electrónica e Telecomunicações

Capillary bridging and long-range attractive forces in a mean-field approach

When a mixture is confined, one of the phases can condense out. This condensate, which is otherwise metastable in the bulk, is stabilized by the presence of surfaces. In a sphere-plane geometry, routinely used in atomic force microscope and surface force apparatus, it, can form a bridge connecting the surfaces. The pressure drop in the bridge gives rise to additional long-range attractive forces between them. By minimizing the free energy of a binary mixture we obtain the force-distance curves as well as the structural phase diagram of the configuration with the bridge. Numerical results predict a discontinuous transition between the states with and without the bridge and linear force-distance curves with hysteresis. We also show that similar phenomenon can be observed in a number of different systems, e.g., liquid crystals and polymer mixtures. (C). 2004 American Institute of Physics.

Tratamiento y presencia de las mujeres em la prensa

Este artículo presenta los resultados de un análisis de contenido sobre la representación de la mujer en la prensa española que forma parte de una investigación más amplia que abarca el periodo de 1974-2000. Nuestra investigación supone una importante contribución a otras investigaciones ya que analiza de forma comparativa, sistemática y longitudinal las representaciones sociales y políticas enfocadas en la prensa. Examinamos como en los medios de comunicación los periodistas utilizan frecuentemente distintas referencias para los diferentes tipos de actores a partir de recursos estilísticos que ayudan a enfatizar sus argumentos. En la mayoría de los casos, estos pasan desapercibidos pero en ocasiones se convierten en generalizaciones que parten de ideas preconcebidas y prejuicios. Nuestros resultados demuestran que los actores a los que los medios de comunicación dedican menos espacio son también los que reciben un peor tratamiento. Específicamente, las mujeres reciben una menor atención como colectivo en los medios de comunicación analizados. Además, aparecen como personajes pasivos, no son enfocadas como representantes públicas y son relegadas a la vida privada. Principalmente, las mujeres son enfocadas realizando actividades deportivas, culturales o de entretenimiento o cuando son víctimas, mientras que sólo una minoría de ellas merecen atención efectuando acciones políticas. Después de exponer este diagnóstico, realizaremos propuestas de estilo, lenguaje y producción de noticias para fomentar que los periódicos muestren de forma positiva una sociedad con igualdad de oportunidades.