969 resultados para TETRAHYDROPYRAN RINGS


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In this paper we show that the quaternion orders OZ[ √ 2] ≃ ( √ 2, −1)Z[ √ 2] and OZ[ √ 3] ≃ (3 + 2√ 3, −1)Z[ √ 3], appearing in problems related to the coding theory [4], [3], are not maximal orders in the quaternion algebras AQ( √ 2) ≃ ( √ 2, −1)Q( √ 2) and AQ( √ 3) ≃ (3 + 2√ 3, −1)Q( √ 3), respectively. Furthermore, we identify the maximal orders containing these orders.

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The high electronegativity and small size of the fluorine atom and the high stability of C-F bonds impart interesting properties and applications to fluorine containing polymers. The unique properties of fluoropolymers include high thermal stability, improved chemical resistance, low surface energies, low coefficients of friction, and low dielectric constants. Applications of fluorinated polymers include use as noncorrosive materials, polymer processing aids, chemically resistant and antifouling coatings, as well as interlayer dielectrics. Fluorine-containing polymers can be directly synthesized via polymerization of fluorine-containing monomers or by post-polymerization modification. The latter method can be used to attach fluorinated species, such as perfluoroalkyl groups, onto conventional polymer chains, thereby imparting properties of fluorine-containing polymers into conventional polymers and widening their range of potential applications.

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In this paper we report original measurements of total cross sections (TCSs) for positron scattering from the cyclic ethers oxirane (C2H4O), 1,4-dioxane (C4H8O2), and tetrahydropyran (C5H10O). The present experiments focus on the low energy range from similar to 0.2 to 50 eV, with an energy resolution smaller than 300 meV. This study concludes our systematic investigation into TCSs for a class of organic compounds that can be thought of as sub-units or moieties to the nucleotides in living matter, and which as a consequence have become topical for scientists seeking to simulate particle tracks in matter. Note that as TCSs specify the mean free path between collisions in such simulations, they have enjoyed something of a recent renaissance in interest because of that application. For oxirane, we also report original Schwinger multichannel elastic integral cross section (ICS) calculations at the static and static plus polarisation levels, and with and without Born-closure that attempts to account for the permanent dipole moment of C2H4O. Those elastic ICSs are computed for the energy range 0.5-10 eV. To the best of our knowledge, there are no other experimental results or theoretical calculations against which we can compare the present positron TCSs. However, electron TCSs for oxirane (also known as ethylene oxide) and tetrahydropyran do currently exist in the literature and a comparison to them for each species will be presented. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.3696378]

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Let k be an algebraically closed field of characteristic zero and let L be an algebraic function field over k. Let sigma : L -> L be a k-automorphism of infinite order, and let D be the skew field of fractions of the skew polynomial ring L[t; sigma]. We show that D contains the group algebra kF of the free group F of rank 2.

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Let D be a division ring with center k, and let D-dagger be its multiplicative group. We investigate the existence of free groups in D-dagger, and free algebras and free group algebras in D. We also go through the case when D has an involution * and consider the existence of free symmetric and unitary pairs in D-dagger.

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This work reports the investigation on the structural differences between InAs quantum rings and their precursor quantum dots species as well as on the presence of piezoelectric fields and asymmetries in these nanostructures. The experimental results show significant reduction in the ring dimensions when the sizes of capped and uncapped ring and dot samples are compared. The iso-lattice parameter mapped by grazing-incidence x-ray diffraction has revealed the lateral extent of strained regions in the buried rings. A comparison between strain and composition of dot and ring structures allows inferring on how the ring formation and its final configuration may affect optical response parameters. Based on the experimental observations, a discussion has been introduced on the effective potential profile to emulate theoretically the ring-shape confinement. The effects of confinement and strain field modulation on electron and hole band structures are simulated by a multiband k.p calculation. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4733964]

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Abstract Background Obesity has been associated with a variety of disease such as type II diabetes mellitus, arterial hypertension and atherosclerosis. Evidences have shown that exercise training promotes beneficial effects on these disorders, but the underlying mechanisms are not fully understood. The aim of this study was to investigate whether physical preconditioning prevents the deleterious effect of high caloric diet in vascular reactivity of rat aortic and mesenteric rings. Methods Male Wistar rats were divided into sedentary (SD); trained (TR); sedentary diet (SDD) and trained diet (TRD) groups. Run training (RT) was performed in sessions of 60 min, 5 days/week for 12 weeks (70–80% VO2max). Triglycerides, glucose, insulin and nitrite/nitrate concentrations (NOx-) were measured. Concentration-response curves to acetylcholine (ACh) and sodium nitroprusside (SNP) were obtained. Expression of Cu/Zn superoxide dismutase (SOD-1) was assessed by Western blotting. Results High caloric diet increased triglycerides concentration (SDD: 216 ± 25 mg/dl) and exercise training restored to the baseline value (TRD: 89 ± 9 mg/dl). Physical preconditioning significantly reduced insulin levels in both groups (TR: 0.54 ± 0.1 and TRD: 1.24 ± 0.3 ng/ml) as compared to sedentary animals (SD: 0.87 ± 0.1 and SDD: 2.57 ± 0.3 ng/ml). On the other hand, glucose concentration was slightly increased by high caloric diet, and RT did not modify this parameter (SD: 126 ± 6; TR: 140 ± 8; SDD: 156 ± 8 and TRD 153 ± 9 mg/dl). Neither high caloric diet nor RT modified NOx- levels (SD: 27 ± 4; TR: 28 ± 6; SDD: 27 ± 3 and TRD: 30 ± 2 μM). Functional assays showed that high caloric diet impaired the relaxing response to ACh in mesenteric (about 13%), but not in aortic rings. RT improved the relaxing responses to ACh either in aortic (28%, for TR and 16%, to TRD groups) or mesenteric rings (10%, for TR and 17%, to TRD groups) that was accompanied by up-regulation of SOD-1 expression and reduction in triglycerides levels. Conclusion The improvement in endothelial function by physical preconditioning in mesenteric and aortic arteries from high caloric fed-rats was directly related to an increase in NO bioavailability to the smooth muscle mostly due to SOD-1 up regulation.

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We study the power series ring R= K[[x1,x2,x3,...]]on countably infinitely many variables, over a field K, and two particular K-subalgebras of it: the ring S, which is isomorphic to an inverse limit of the polynomial rings in finitely many variables over K, and the ring R', which is the largest graded subalgebra of R. Of particular interest are the homogeneous, finitely generated ideals in R', among them the generic ideals. The definition of S as an inverse limit yields a set of truncation homomorphisms from S to K[x1,...,xn] which restrict to R'. We have that the truncation of a generic I in R' is a generic ideal in K[x1,...,xn]. It is shown in Initial ideals of Truncated Homogeneous Ideals that the initial ideal of such an ideal converge to the initial ideal of the corresponding ideal in R'. This initial ideal need no longer be finitely generated, but it is always locally finitely generated: this is proved in Gröbner Bases in R'. We show in Reverse lexicographic initial ideals of generic ideals are finitely generated that the initial ideal of a generic ideal in R' is finitely generated. This contrast to the lexicographic term order. If I in R' is a homogeneous, locally finitely generated ideal, and if we write the Hilbert series of the truncated algebras K[x1,...,xn] module the truncation of I as qn(t)/(1-t)n, then we show in Generalized Hilbert Numerators that the qn's converge to a power series in t which we call the generalized Hilbert numerator of the algebra R'/I. In Gröbner bases for non-homogeneous ideals in R' we show that the calculations of Gröbner bases and initial ideals in R' can be done also for some non-homogeneous ideals, namely those which have an associated homogeneous ideal which is locally finitely generated. The fact that S is an inverse limit of polynomial rings, which are naturally endowed with the discrete topology, provides S with a topology which makes it into a complete Hausdorff topological ring. The ring R', with the subspace topology, is dense in R, and the latter ring is the Cauchy completion of the former. In Topological properties of R' we show that with respect to this topology, locally finitely generated ideals in R'are closed.

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Programa de doctorado: Oceanografía

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In this thesis, three different types of quantum rings arestudied. These are quantum rings with diamagnetic,paramagnetic or spontaneous persistent currents. It turns out that the main observable to characterizequantum rings is the Drude weight. Playing a key role inthis thesis, it will be used to distinguish betweendiamagnetic (positive Drude weight) and paramagnetic(negative Drude weight) ring currents. In most models, theDrude weight is positive. Especially in the thermodynamiclimit, it is positive semi-definite. In certain modelshowever, intuitivelysurprising, a negative Drude weight is found. This rareeffect occurs, e.g., in one-dimensional models with adegenerate ground state in conjunction with the possibilityof Umklapp scattering. One aim of this thesis is to examineone-dimensional quantum rings for the occurrence of anegative Drude weight. It is found, that the sign of theDrude weight can also be negative, if the band structurelacks particle-hole symmetry. The second aim of this thesis is the modeling of quantumrings intrinsically showing a spontaneous persistentcurrent. The construction of the model starts from theextended Hubbard model on a ring threaded by anAharonov-Bohm flux. A feedback term through which thecurrent in the ring can generate magnetic flux is added.Another extension of the Hamiltonian describes the energystored in the internally generated field. This model isevaluated using exact diagonalization and an iterativescheme to find the minima of the free energy. The quantumrings must satisfy two conditions to exhibit a spontaneousorbital magnetic moment: a negative Drude weight and aninductivity above the critical level. The magneticproperties of cyclic conjugated hydrocarbons likebenzene due to electron delocalization [magnetic anisotropy,magnetic susceptibility exaltation, nucleus-independent chemical shift (NICS)]---that have become important criteriafor aromaticity---can be examined using this model. Corrections to the presented calculations are discussed. Themost substantial simplification made in this thesis is theneglect of the Zeeman interaction of the electron spins withthe magnetic field. If a single flux tube threads a quantumring, the Zeeman interaction is zero, but in mostexperiments, this situation is difficult to realize. In themore realistic situation of a homogeneous field, the Zeemaninteraction has to be included, if the electrons have atotal spin component in the direction of the magnetic field,or if the magnetic field is strong.