La distruzione delle statue di Pausania nella Sparta tardoantica (Lib. Ep. 1518)

Abstract: The late antique destruction of two bronze statues of Pausanias - the Spartan general responsible for the Greek victory at the Battle of Plataea (479 BC) - housed in the temple of Athena Chalkioikos in Sparta (Lib. Ep. 1518), has been interpreted as one of the few cases of a violent conflict between pagan and Christian population in Greece. Nevertheless the sources suggest that late antique Sparta was a bastion of Hellenic paganism and give a picture of a small and quiet town ruled by a pagan educated élite, where pagans like Libanius wanted to live. Since there is no evidence of a violent conflict between pagans and Christians in Sparta, and Libanius confirms that in 365 AD all the temples and cult statues were still in place, this paper addresses the issue from a different point of view and offers a new contribution to the history of Sparta in Late Antiquity. By using literary, archaeological and epigraphic evidence the paper explores: 1) the relationship between Roman administration and Spartan élite in the IVth century AD; 2) the historical memory of Pausanias in Late Antiquity. It will be emphasized that the obscure burning of the two statues helped to remove from Sparta the memory of Pausanias - a controversial figure, misrepresented in Late Antiquity and connected to the ancient staseis in Laconia - in order to promote a positive image of Sparta as a city without conflicts and ruled by the political system of Lycurgus (eunomia). As documented by local inscriptions in praise of late Roman governors, the mythical lawgiver Lycurgus was the paradigm of the imperial governors who rebuilded the town in the IVth cent. AD. It can be assumed that while Rome, Constantinople, Antioch and Athens were troubled by political and religious violence or by seditions between different factions, Sparta aimed to revive its traditional model of civic order in the new historical context of Late Antiquity.

Arquitectura y funcionalidad del Gran Templo de Requem

Resumen: Hasta 1993 no se llevaron a cabo por primera vez las excavaciones en lo que prometía ser el emplazamiento de una de las construcciones más importantes de Petra, la impresionante capital del reino nabateo. Su edificación, cuya iniciación data del siglo I a.C., sufrió numerosas modificaciones, reconstrucciones y derrumbamientos a lo largo de sus más de quinientos años de funcionamiento. Pero a pesar de ello aun hoy se desconocen con certeza las funciones para las cuales fue diseñado ya que, al margen de los elementos constructivos, apenas se han localizado materiales y aun menos inscripciones que arrojen algo de luz a un problema sobre el que intentaremos aquí exponer diversas teorías que posibiliten un mayor acercamiento a su resolución.

Fatigue crack-growth rate in ferrite martensite dual-phase steel

An empirical study is made on the fatigue crack growth rate in ferrite-martensite dual-phase (FMDP) steel. Particular attention is given to the effect of ferrite content in the range of 24.2% to 41.5% where good fatigue resistance was found at 33.8%. Variations in ferrite content did not affect the crack growth rate when plotted against the effective stress intensity factor range  which was assumed to follow a linear relation with the crack tip stress intensity factor range ΔK. A high  corresponds to uniformly distributed small size ferrite and martensite. No other appreciable correlation could be ralated to the microstructure morphology of the FMDP steel. The closure stress intensity factor , however, is affected by the ferrite content with  reaching a maximum value of 0.7. In general, crack growth followed the interphase between the martensite and ferrite.

Dividing the fatigue crack growth process into Stage I and II where the former would be highly sensitive to changes in ΔK and the latter would increase with ΔK depending on the  ratio. The same data when correlated with the strain energy density factor range ΔS showed negligible dependence on mean stress or R ratio for Stage I crack growth. A parameter α involving the ratio of ultimate stress to yield stress, percent reduction of area and R is introduced for Stage II crack growth so that the  data for different R would collapse onto a single curve with a narrow scatter band when plotted against αΔS.

Divinidades y devotos indígenas en la "Tarraconensis": las dedicaciones colectivas

Presentado en: Acta Paleohispanica X. Actas do X Colóquio Internacional sobre Línguas e Culturas Paleo-Hispânicas. Lisboa, 26-28 de Fevereiro de 2009

Observaciones sobre la fórmula "in hono. Argael." en un epígrafe de Cacabelos, León (CIL II 5672)

Ejemplar dedicado a: Serta Palaeohispanica in honorem Javier de Hoz

Las fórmulas epigráficas honore contentus, honore accepto, honore usus en los homenajes hispanos. Estudio preliminar

Homenaje a Ignacio Barandiarán Maestu.

La representación de las élites locales y provinciales en los homenajes hispanos: la distinción honorífica pública y la intervención privada

Homenaje al Dr. Armin U. Stylow.

Nuevas lecturas de tres inscripciones de Clunia (Hispania Citerior) con repercusión sobre la expresión de algunas agrupaciones familiares celtibéricas

[ES] Revisión de tres inscripciones Funerarias procedentes de la ciudad de Clunia, con propuesta de nuevas lecturas que afectan a la interpretación de nombres personales y de agrupaciones familiares indígenas

Unidades organizativas indígenas del área indoeuropea de Hispania III: addenda

[ES] Se ofrecen los nuevos nombres, repetidos o no, de unidades organizativas indígenas (cognationes, gentes y gentilitates) aparecidos desde la década de los 90 del pasado siglo y documentados en la epigrafía latina y celtibérica de la Hispania indoeuropea

Capturing protein dynamics with time-resolved luminescence spectroscopy

The presented doctoral research utilizes time-resolved spectroscopy to characterize protein dynamics and folding mechanisms. We resolve millisecond-timescale folding by coupling time-resolved fluorescence energy transfer (trFRET) to a continuous flow microfluidic mixer to obtain intramolecular distance distributions throughout the folding process. We have elucidated the folding mechanisms of two cytochromes---one that exhibits two-state folding (cytochrome <italic>cb₅₆₂italic>) and one that has both a kinetic refolding intermediate ensemble and a distinct equilibrium unfolding intermediate (cytochrome <italic>c₅₅₂italic>). Our data reveal that the distinct structural features of cytochrome <italic>c₅₅₂italic> contribute to its thermostability.

We have also investigated intrachain contact dynamics in unfolded cytochrome <italic>cb₅₆₂italic> by monitoring electron transfer, which occurs as the heme collides with a ruthenium photosensitizer, covalently bound to residues along the polypeptide. Intrachain diffusion for chemically denatured proteins proceeds on the microsecond timescale with an upper limit of 0.1 microseconds. The power-law dependence (slope = -1.5) of the rate constants on the number of peptide bonds between the heme and Ru complex indicate that cytochrome <italic>cb₅₆₂italic> is minimally frustrated.

In addition, we have explored the pathway dependence of electron tunneling rates between metal sites in proteins. Our research group has converted cytochrome <italic>b₅₆₂italic> to a <italic>citalic>-type cytochrome with the porphyrin covalently bound to cysteine sidechains. We have investigated the effects of the changes to the protein structure (i.e., increased rigidity and potential new equatorial tunneling pathways) on the electron transfer rates, measured by transient absorption, in a series of ruthenium photosensitizer-modified proteins.

Catalytic conversion of nitrogen to ammonia by an iron model complex

Threefold symmetric Fe phosphine complexes have been used to model the structural and functional aspects of biological N₂ fixation by nitrogenases. Low-valent bridging Fe-S-Fe complexes in the formal oxidation states Fe(II)Fe(II), Fe(II)/Fe(I), and Fe(I)/Fe(I) have been synthesized which display rich spectroscopic and magnetic behavior. A series of cationic tris-phosphine borane (TPB) ligated Fe complexes have been synthesized and been shown to bind a variety of nitrogenous ligands including N₂H₄, NH₃, and NH₂-. These complexes are all high spin <italic>Sitalic> = 3/2 and display EPR and magnetic characteristics typical of this spin state. Furthermore, a sequential protonation and reduction sequence of a terminal amide results in loss of NH₃ and uptake of N₂. These stoichiometric transformations represent the final steps in potential N₂ fixation schemes.

Treatment of an anionic FeN₂ complex with excess acid also results in the formation of some NH₃, suggesting the possibility of a catalytic cycle for the conversion of N₂ to NH₃ mediated by Fe. Indeed, use of excess acid and reductant results in the formation of seven equivalents of NH₃ per Fe center, demonstrating Fe mediated catalytic N₂ fixation with acids and protons for the first time. Numerous control experiments indicate that this catalysis is likely being mediated by a molecular species.

A number of other phosphine ligated Fe complexes have also been tested for catalysis and suggest that a hemi-labile Fe-B interaction may be critical for catalysis. Additionally, various conditions for the catalysis have been investigated. These studies further support the assignment of a molecular species and delineate some of the conditions required for catalysis.

Finally, combined spectroscopic studies have been performed on a putative intermediate for catalysis. These studies converge on an assignment of this new species as a hydrazido(2-) complex. Such species have been known on group 6 metals for some time, but this represents the first characterization of this ligand on Fe. Further spectroscopic studies suggest that this species is present in catalytic mixtures, which suggests that the first steps of a distal mechanism for N₂ fixation are feasible in this system.

Chain-forming zintl antimonides as novel thermoelectric materials

Zintl phases, a subset of intermetallic compounds characterized by covalently-bonded "sub-structures," surrounded by highly electropositive cations, exhibit precisely the characteristics desired for thermoelectric applications. The requirement that Zintl compounds satisfy the valence of anions through the formation of covalent substructures leads to many unique, complex crystal structures. Such complexity often leads to exceptionally low lattice thermal conductivity due to the containment of heat in low velocity optical modes in the phonon dispersion. To date, excellent thermoelectric properties have been demonstrated in several Zintl compounds. However, compared with the large number of known Zintl phases, very few have been investigated as thermoelectric materials.

From this pool of uninvestigated compounds, we selected a class of Zintl antimonides that share a common structural motif: anionic moieties resembling infinite chains of linked MSb₄ tetrahedra, where $M$ is a triel element. The compounds discussed in this thesis (<italic>Aitalic>₅<italic>Mitalic>₂Sb₆ and A₃MSb₃, where A = Ca or Sr and M = Al, Ga and In) crystallize as four distinct, but closely related "chain-forming" structure types. This thesis describes the thermoelectric characterization and optimization of these phases, and explores the influence of their chemistry and structure on the thermal and electronic transport properties. Due to their large unit cells, each compound exhibits exceptionally low lattice thermal conductivity (0.4 - 0.6 W/mK at 1000 K), approaching the predicted glassy minimum at high temperatures. A combination of Density Functional calculations and classical transport models were used to explain the experimentally observed electronic transport properties of each compound. Consistent with the Zintl electron counting formalism, <italic>Aitalic>₅<italic>Mitalic>₂Sb₆ and A₃MSb₃ phases were found to have filled valence bands and exhibit intrinsic electronic properties. Doping with divalent transition metals (Zn²⁺ and Mn²⁺) on the M³⁺ site, or Na¹⁺ on the A³⁺ site allowed for rational control of the carrier concentration and a transition towards degenerate semiconducting behavior. In optimally-doped samples, promising peak zT values between 0.4 and 0.9 were obtained, highlighting the value of continued investigations of complex Zintl phases.

La atracción de la falsa palabra y del código prohibido en Margaret Atwood: "Nolite te bastardes carborundorum"

Este trabajo ha sido realizado dentro del Grupo de Investigación GIU 10–19 “LITTERARVM. Grupo de Investigación en Literatura, Retórica y Tradición Clásica” de la UPV/EHU.

La onomástica de las inscripciones romanas del País Vasco. Estructura del nombre personal y estatuto jurídico

Este trabajo se ha desarrollado a partir de la edición de las inscripciones romanas del País Vasco dentro del proyecto PETRAE Hispaniarum (Université Michel de Montaigne-Bordeaux III, Francia).

Inscripciones romanas de Segovia, III: "addenda et corrigenda" a «Epigrafía romana de Segovia y su provincia»

[ES] En este artículo presentamos nuestra tercera aportación de novedades de la epigrafía de época romana de la provincia de Segovia, con seis piezas nuevas, recogemos dos ya publicadas, de una aportamos nueva lectura e interpretación, e introducimos un apartado de corrigenda con dos entradas.