(Table 1) Geochemistry of surface sediment samples from the Chilean margin

Biogenic barium in marine sediments has been suggested to be a reliable proxy of export productivity from the surface ocean and algorithms have been developed to link these properties. However, problems arise when the proposed algorithms are applied to predominantly terrigenous sediments. A major source of error is incorrect estimates of the terrigenous Ba/Al ratio in normative calculations of the amount of biogenic barium in the sediment. Compared to an often used "global average" Ba/Al ratio, much better results can be obtained by estimating the terrigenous Ba/Al ratio from exponential regression of the Ba/Al ratios of surface sediments obtained from continental slope transects. This method has been applied to surface sediments from the Chilean continental slope. The calculated regional terrigenous Ba/Al ratios could be verified with purely terrigenous samples from Chilean rivers. The resulting accumulation rates of biogenic barium on the Chilean continental slope reliably reproduce the regional pattern of primary productivity in the southern Peru-Chile Current, indicating the potential of biogenic barium as a useful (paleo)productivity proxy.

Sedimentation rates calculated on surface sediment samples from different site of the Atlantic and Pacific Oceans (Table 1)

Radiocarbon ages on CaCO3 from deep-sea cores offer constraints on the nature of the CaCO3 dissolution process. The idea is that the toll taken by dissolution on grains within the core top bioturbation zone should be in proportion to their time of residence in this zone. If so, dissolution would shift the mass distribution in favor of younger grains, thereby reducing the mean radiocarbon age for the grain ensemble. We have searched in vain for evidence supporting the existence of such an age reduction. Instead, we find that for water depths of more than 4 km in the tropical Pacific the radiocarbon age increases with the extent of dissolution. We can find no satisfactory steady state explanation and are forced to conclude that this increase must be the result of chemical erosion. The idea is that during the Holocene the rate of dissolution of CaCO3 has exceeded the rain rate of CaCO3. In this circumstance, bioturbation exhumes CaCO3 from the underlying glacial sediment and mixes it with CaCO3 raining from the sea surface.

Radionuclides and sedimentation rates of sediment cores from the eastern South Atlantic

High-resolution records of the natural radionuclide 230Th were measured in sediments from the eastern Atlantic sector of the Antarctic circumpolar current to obtain a detailed reconstruction of the sedimentation history of this key area for global climate change during the late Quaternary. High-resolution dating rests on the assumption that the 230Thex flux to the sediments is constant. Short periods of drastically increased sediment accumulation rates (up to a factor of 8) were determined in the sediments of the Antarctic zone during the climate optima at the beginning of the Holocene and the isotope stage 5e. By comparing expected and measured accumulation rate of 230Thex, lateral sediment redistribution was quantified and vertical particle rain rates originating from the surface water above were calculated. We show that lateral contributions locally were up to 6.5 times higher than the vertical particle rain rates. At other locations only 15% of the expected vertical particle rain rate were deposited.

Beryllium concentrations and deposition rates in ODP holes from the north Atlantic

Increases in the production rate of cosmogenic radionuclides associated with geomagnetic excursions have been used as global tie-points for correlation between records of past climate from marine and terrestrial archives. We have investigated the relative timing of variations in 10Be production rate and the corresponding palaeomagnetic signal during one of the largest Pleistocene excursions, the Iceland Basin (IB) event (ca. 190 kyr), as recorded in two marine sediment cores (ODP Sites 1063 and 983) with high sedimentation rates. Variations in 10Be production rate during the excursion were estimated by use of 230Thxs normalized 10Be deposition rates and authigenic 10Be/9Be. Resulting 10Be production rates are compared with high-resolution records of geomagnetic field behaviour acquired from the same discrete samples. We find no evidence for a significant lock-in depth of the palaeomagnetic signal in these high sedimentation-rate cores. Apparent lock-in depths in other cores may sometimes be the result of lower sample resolution. Our results also indicate that the period of increased 10Be production during the IB excursion lasted longer and, most likely, started earlier than the corresponding palaeomagnetic anomaly, in accordance with previous observations that polarity transitions occur after periods of reduced geomagnetic field intensity prior to the transition. The lack of evidence in this study for a significant palaeomagnetic lock-in depth suggests that there is no systematic offset between the 10Be signal and palaeomagnetic anomalies associated with excursions and reversals, with significance for the global correlation of climate records from different archives.

Radionuclide analyses, and sedimentation and accumulation rates of sediment core PS2319-1

There is increasing evidence indicating that syndepositional redistribution of sediment on the seafloor by bottom currents is common and can significantly affect sediment mass accumulation rates. Notwithstanding its common incidence, this process (generally referred to as sediment focusing) is often difficult to recognize. If redistribution is near synchronous to deposition, the stratigraphy of the sediment is not disturbed and sediment focusing can easily be overlooked. Ignoring it, however, can lead to serious misinterpretations of sedimentary fluxes, particularly when past changes in export flux from the overlying water are inferred. In many instances, this problem can be resolved, at least for sediments deposited during the late Quaternary, by normalizing to the flux of 230Th scavenged from seawater, which is nearly constant and equivalent to the known rate of production of 230Th from the decay of dissolved 234U. We review the principle, advantages and limitations of this method. Notwithstanding its limitations, it is clear that 230Th normalization does provide a means of achieving more accurate interpretations of sedimentary fluxes and eliminates the risk of serious misinterpretations of sediment mass accumulation rates.

Sedimentology of cores from the Bellingshausen Sea, Antarctic

On the continental rise west of the Antarctic Peninsula there are nine large mounds interpreted as sediment drifts, separated by turbidity current channels. Drift 7 is 150 km long, 70 km wide and up to 700 m high and is asymmetric, with steep sides on the south-east (towards the continent) and south-west, and gentle slopes to north-west and north-east. Cores on the gentle sides of the drift show a cyclicity between brown, bioturbated, diatom-bearing mud with foraminifera and radiolarians, and grey, laminated, barren mud. Biostratigraphic evidence is consistent with a Late Quaternary age. Detailed lithostratigraphy and magnetic susceptibility data allow precise correlation over distances of tens of kilometres. On the basis of chemostratigraphy, the brown sediment is interpreted as interglacial (isotope stages 1 and 5) and the grey as glacial (stages 2-4 and 6). Sedimentation rates are 3.0-5.5 cm/ka. Cores on the steep sides of the drift recovered a condensed section with thinner cycles and hiatuses. Fine grain size, very poor sorting and the absence of a mode in the silt size range indicate deposition from suspension with only weak current activity, There is little evidence for cyclic changes in bottom current strength. Supply of sediment to the benthic nepheloid layer was by entrainment ofmud from turbidity currents, and by settling ofpelagic material (biogenic grains, IRD, sediment suspended in meltwater plumes). Cyclic changes in sediment supply include more biogenic supply in interglacials with less sea ice cover, more terrigenous supply from turbidites in glacials with ice sheets grounded to the shelf edge, and changes in IRD content.