Photoelectrochemical oxidation of p-nitrophenol on an expanded graphite-TiO2 electrode

In the quest for more efficient photoanodes in the photoelectrochemical oxidation processes for organic pollutant degradation and mineralisation in water treatment, we present the synthesis, characterisation and photoelectrochemical application of expanded graphite-TiO2 composite (EG-TiO2) prepared using the sol-gel method with organically modified silicate. The Brunauer-Emmett-Teller surface area analyser, ultraviolet-visible diffuse reflectance, scanning electron microscopy, energy dispersive spectroscopy, X-ray diffractometry, Raman spectrometry and X-ray photoelectron spectroscopy were employed for the characterisation of the composites. The applicability of the EG-TiO2 as photoanode material was investigated by the photoelectrochemical degradation of p-nitrophenol as a target pollutant in a 0.1 M Na2SO4 (pH 7) solution at a current density of 5 mA cm(-2). After optimising the TiO2 loading, initial p-nitrophenol concentration, pH and current density, a removal efficiency of 62% with an apparent kinetic rate constant of 10.4 x 10(-3) min(-1) was obtained for the photoelectrochemical process as compared to electrochemical oxidation and photolysis, where removal efficiencies of 6% and 24% were obtained respectively after 90 min. Furthermore, the EG-TiO2 electrode was able to withstand high current density due to its high stability. The EG-TiO2 electrode was also used to degrade 0.3 x 10(-4) M methylene blue and 0.1 x 10(-4) M Eosin Yellowish, leading to 94% and 47% removal efficiency within 120 reaction time. This confirms the suitability of the EG-TiO2 electrode to degrade other organic pollutants.

Structural, thermal and electrical properties of poly(methyl methacrylate)/CaCu3Ti4O12 composite sheets fabricated via melt mixing

Poly(methyl methacrylate) (PMMA) and CaCu3Ti4O12 (CCTO) composites were fabricated via melt mixing followed by hot pressing technique. These were characterized using X-ray diffraction, thermo gravimetric, thermo mechanical, differential scanning calorimetry, fourier transform infrared (FTIR) and Impedance analyser for their structural, thermal and dielectric properties. Composites were found to have better thermal stability than that of pure PMMA. However, there was no significant difference in the glass transition (T (g) ) temperature between the polymer and the composite. The appearance of additional vibrational frequencies in the range 400-600 cm(-1) in FTIR spectra indicated a possible interaction between PMMA and CCTO. The composite, with 38 vol% of CCTO (in PMMA), exhibited remarkably low dielectric loss at high frequencies and the low-frequency relaxation is attributed to the interfacial polarization/MWS effect. The origin of AC conductivity particularly in the high-frequency region was attributed to the electronic polarization.

Effect of thermal annealing on dual photoluminescence emission characteristics of chemically synthesized uncapped Mn2+ doped ZnS quantum dots

Dual photoluminescence (PL) emission characteristics of Mn2+ doped ZnS (ZnS:Mn) quantum dots (QDs) have drawn a lot of attention recently. However, here we report the effect of thermal annealing on the PL emission characteristics of uncapped ZnS:Mn QDs of average sizes similar to 2-3 nm, synthesized by simple chemical precipitation method by using de-ionized (DI) water at room temperature. As-synthesized samples show dual PL emissions, having one UV PL band centred at similar to 400 nm and the other in the visible region similar to 610 nm. But when the samples are isochronally annealed for 2 h at 100-600 degrees C temperature range in air, similar to 90% quenching of Mn2+ related visible PL emission intensity takes place at the annealing temperature of 600 degrees C. X-ray diffraction data show that the as-synthesized cubic ZnS has been converted to wurtzite ZnO at 600 degrees C annealing temperature. The nanostructural properties of the samples are also determined by transmission electron micrograph, electron probe micro-analyser and UV-vis spectrophotometry. The photocatalytic property of the annealed ZnS:Mn sample has been demonstrated and photo-degradation efficiency of the as-synthesized and 600 degrees C annealed ZnS:Mn sample has been found out to be similar to 35% and similar to 61%, respectively, for the degradation of methylene blue dye under visible light irradiation. The synthesized QDs may find significant applications in future optoelectronic devices. (C) 2014 Elsevier B.V. All rights reserved.

Simultaneous enhancement in mechanical strength, electrical conductivity, and electromagnetic shielding properties in PVDF-ABS blends containing PMMA wrapped multiwall carbon nanotubes

A unique approach was adopted to drive the multiwall carbon nanotubes (MWNTs) to the interface of immiscible PVDF-ABS blends by wrapping the nanotubes with a mutually miscible homopolymer (PMMA). A tailor made interface with an improved stress transfer was achieved in the blends with PMMA wrapped MWNTs. This manifested in an impressive 108% increment in the tensile strength and 48% increment in the Young's modulus with 3 wt% PMMA wrapped MWNTs in striking contrast to the neat blends. As the PMMA wrapped MWNTs localized at the interface of PVDF-ABS blends, the electrical conductivity could be tuned with respect to only MWNTs, which were selectively localized in the PVDF phase, driven by thermodynamics. The electromagnetic shielding properties were assessed using a vector network analyser in a broad range of frequency, X-band (8-12 GHz) and Ku-band (12-18 GHz). Interestingly, enhanced EM shielding was achieved by this unique approach. The blends with only MWNTs shielded the EM waves mostly by reflection however, the blends with PMMA wrapped MWNTs (3 wt%) shielded mostly by absorption (62%). This study opens new avenues in designing materials, which show simultaneous improvement in mechanical, electrical conductivity and EM shielding properties.

Photoelectrochemical degradation of eosin yellowish dye on exfoliated graphite-ZnO nanocomposite electrode

In the quest for harnessing more power from the sun for water treatment by photoelectrochemical degradation, we prepared a novel photoanode of exfoliated graphite (EG)-ZnO nanocomposite. The nanocomposite was characterised by X-ray diffractometry, energy dispersive spectroscopy, Brunauer-Emmett-Teller surface area analyser, thermal gravimetric analyser, and X-ray photoelectron spectroscopy. The EG-ZnO nanocomposite was fabricated into a photoanode and applied for the photoelectrochemical degradation of 0.1 x 10(-4) M eosin yellowish dye in 0.1 M Na2SO4 under visible light irradiation. The degradation was monitored with a visible spectrophotometer. The photoelectrochemical degradation process resulted in enhanced degradation efficiency of ca. 93 % with kinetic rate of 11.0 x 10(-3) min(-1) over photolysis and electrochemical oxidation processes which exhibited lower degradation efficiencies of 35 and 40 % respectively.

Electrical conductivity and dielectric relaxation studies on microwave synthesized Na2SO4 center dot NaPO3 center dot MoO3 glasses

Electrical conductivity and dielectric relaxation studies on SO4 (2-) doped modified molybdo-phosphate glasses have been carried out over a wide range of composition, temperature and frequency. The d.c. conductivities which have been measured by both digital electrometer (four-probe method) and impedance analyser are comparable. The relaxation phenomenon has been rationalized using electrical modulus formalism. The use of modulus representation in dielectric relaxation studies has inherent advantages viz., experimental errors arising from the contributions of electrode-electrolyte interface capacitances are minimized. The relaxation observed in the present study is non-Debye type. The activation energies for relaxation were determined using imaginary parts of electrical modulus peaks which were close to those of the d.c. conductivity implying the involvement of similar energy barriers in both the processes. The enhanced conductivity in these glasses can be attributed to the migration of Na+, in expanded structures due to the introduction of SO4 (2-) ions.

气相爆轰波在障碍物上Mach反射后流场的分析

详细分析了气相爆轰波在斜劈上Mach反射后的流场。根据胞格结构的烟迹记录，得到了爆轰波Mach反射时三波点迹线与楔面的夹角X与楔角θ的定量关系，依此推算出爆轰波绕射楔块 时从规则反射向Mach反射转变的临界角范围。论文也分析了影响X角和Mach杆后压力的主要 因素。该结果有助于更深入了解爆轰波的本质，也为数值模拟气相爆轰波在障碍物上Mach反射现象提供了可靠的对照依据。

Determinación de las principales patologías reproductivas en hembras bovinas en el municipio de San Pedro de Lóvago (Chontales)

El impacto de las afecciones reproductivas disminuye enormemente la rentabilidad y crea un grave problema en la planificación estratégica en las unidades de producción de Nicaragua. Así en nuestro estudio realizado en comarcas de Sn Pedro Lovago las pérdidas se pueden presentar tanto causales como económicas. Es por eso que con la finalidad de contribuir al conocimiento de patologías reproductivas desarrollamos el estudio sobre "DETERMINACIÓN DE LAS PRINCIPALES PATOLOGÍAS REPRODUCTIVAS DE HEMBRAS BOVINAS EN EL MUNICIPIO DE SN PEDRO DE LOVAGO". Para lo que haciendo uso de registros reproductivos de las unidades de producción y con ayuda de formatos específicos, se analizó un total de 528 hembras ubicadas en cuatro comarcas (llano de los pedros , palo solo, potrero cerrado y sardina) del Municipio San Pedro de Lovago, de las cuales 78 presentaban trastornos reproductivas. Encontrándose que la patología de mayor persistencia fue la repetición de celos con un 76.9%, seguida de partos distócicos con 8% y metritis 5.1.%. Así como también entre las causas principales identificadas fueron la deficiencia de manejo y deficiencias nutricionales y al final se determinó que la comarca llano de los pedros presentó perdidas económicas de 94.541.00 córdobas (30%). De tal manera concluimos que el surgimiento y control de patologías reproductivas en las unidades de producción es de mucha importancia para mantener hatos saludables con altos índices reproductivos y que sean económicamente rentables al país.

Desde El libro del acedrex alfonsí hasta el Ludus sacc(h)orum de Jacopo de Cessolis : la circulación de un tópico

Resumen: Nuestro trabajo aborda, desde una perspectiva pragmática, la utilización del tópico del ajedrez como imago mundi en la traducción nacida en el marco del vasto proyecto cultural de Alfonso el Sabio, El Libro de los juegos, o Libro del ajedrez, dados y tablas (entre 1251 y 1283) y el Ludus Sacc(h)orum o Juego de Ajedrez del lombardo Jacopo De Cessolis (entre 1300-1330) en su primera versión española, realizada por el Licenciado Reyna en 1549. En la traducción de los textos orientales que sirven de “textos de partida” la estrategia del Scriptorium alfonsí es doble: casi literal en lo eminentemente didascálico e interpretativo en lo simbólico haciéndolo funcional a su intento de legitimación de la sociedad estamental que él representa como cúspide. La imago mundi del ajedrez se articula con la totalidad del orden diseñado por el conjunto de su obra jurídica, histórica y científica. Por otra parte, tanto el texto de De Cessolis cuanto la versión castellana del ignoto licenciado Martín Reyna pertenecen a la tradición medieval del “ajedrez moralizado”: la retórica del texto es un continuo discurrir de exempla moralizantes, en los que a los trebejos se asignan vicios y virtudes propios de un estado u oficio, y la imagen de mundo que se representa es la “batalla del humano linaje” por la movilidad, frente al inmovilismo del siglo XIII

Report of the PICES-STA Workshop on Monitoring Subarctic North Pacific Variability

The PICES Science Board and the Science and Technology Agency of Japan held a Workshop on Monitoring Subarctic North Pacific Vaiability,October 22-23,1994, in Nemuro,Hokkaido,Japan,in conjunction with the PICES Third Annual Meeting. The Workshop was not intended to discuss process studies or to review the science of the subaractic Pacific,but rather to focus on the longterm monitoring programs required for assessment of the physical and ecological responses to long-term forcing,both natural and man-made. (PDF contains 90 pages)

Short communication: Rapid separation of cis9, trans11- and trans7,cis9-18:2 (CLA) isomers from ruminant tissue using a 30 m SLB-IL111 ionic column

[EN]Rumenic acid (cis9,trans11-18:2) is the main natural isomer of conjugated linoleic acid (CLA). Rumenic acid has many purported health benefits, but effects of most other CLA isomers are unknown. Typically trans7,cis9-18:2 is the second most abundant CLA isomer, but it co-elutes with rumenic acid on conventional polar gas chromatography (GC) columns, requiring complimentary analysis with silver-ion high performance liquid chromatography (Ag(+)-HPLC). Herein we report a rapid method for analyzing rumenic acid and trans7,cis9-18:2 using a 30 m ionic-liquid GC column. Optimal resolution of the two CLA isomers was at 145 degrees C and analysis of backfat from barley-fed cattle compared well with GC/Ag(+)-HPLC (y =0.978x - 0.031, r =0.985, P <0.001).

Comissão parlamentar de inquérito : o fato determinado e os limites materiais como garantidores dos direitos fundamentais

Analisa a limitação dos poderes das comissões parlamentares de inquérito e do fato determinado como garantidores do exercício dos direitos fundamentais no âmbito dessas mesmas comissões, a partir da doutrina sobre o assunto e da jurisprudência do Supremo Tribunal Federal. O enorme espaço que as CPIs têm na sociedade, aliado ao "poder de investigação próprio de autoridades judiciais", conferido pela Constituição Federal, nem sempre é compreendido pela maioria dos seus membros, que, não hesitam em dar a ela poderes jurisdicionais, privativos do Judiciário, gerando, desta forma, a violência contra os direitos fundamentais das testemunhas e pessoas por ela investigadas.

Presencia e influencia del castellano en el manuscrito Lazarraga

Ponencia invitada presentada en las Terceras Jornadas de Lingüística Vasco-Románica / Euskara-Erromantze Linguistikaren III. Jardunaldiak (Bilbao, 2010)

Una historia forestal inédita. Las ordenanzas de Zumarraga de 1547: un ejemplo de desarrollo sostenible en el siglo XVI guipuzcoano

Este volúmen recoge las "IX Jornadas de Historia Local: de los fueros locales a las ordenanzas municipales en Euskal Herria" (Vitoria-Gasteiz, 2006)