Gas-phase Ion-molecular Reactions of C-60 and C-70 with Acetone and Quantum Chemistry Study

Gas-phase ion-molecular reactions of C-60 and C-70 with the ion system of acetone have been studied in this paper. The ions of protoned and acetylized C-60 and C-70 were formed by the reactions of C-60 and C-70 with some ions which existed in the ion system when mass spectrometer worked on chemical ionization conditions. The reactivity of C-70 is greater than that of C-60. Results of quantum chemical calculation for the adduct ions showed a sigma bond between the acyl carbon atom and C-60 may be Formed. These results will provide some valuable informations on the condense-phase acetylization of C-60.

STATISTICAL THERMODYNAMICS IN THE FRAMEWORK OF THE LATTICE FLUID MODEL .2. BINARY MIXTURE OF POLYDISPERSE POLYMERS OF SPECIAL DISTRIBUTION

In this paper, the Gibbs free energy, the equation of state and the chemical potentials of polydisperse multicomponent polymer mixtures are derived. For general binary mixtures of polydisperse polymers, we also give the Gibbs free energy, the equation of

聚醚酰亚胺/酚酞型聚醚醚酮共混体系相容性的稀溶液粘度法研究

近年来,有关高性能树脂聚酰亚胺共混物的研究日益引起人们的关注。已经发现许多种分子结构不同的聚酰亚胺之间,聚酰亚胺与聚苯并咪唑,或聚醚醚酮能形成完全相容的共混体系,从而扩大了高性能树脂聚酰亚胺的应用范围。 酚酞型聚醚醚酮(PEK-C)是由我所研究开发出的一种新型的聚醚醚酮类高性能树脂,它具有良好的可溶性,优异的机械强度和加工流动性,已广泛应用于结构材料及复合材料的制备。为进一步扩大该树脂的应用范围,本实验室在PEK-C共混物的研究做了大量的工作。本工作研究了聚醚酰亚胺(PEI)/PEK-C共混体系的相容性。PEI和PEK-C的分子结构如下:

RE_(0.06)La_(0.94)Nb_2O_6Cl的制备与光谱性质(RE=Pr、Eu、Tb、Dy)

本文采用真空下气体输运技术制备RE_(0.06)La_(0.94)Nb_2O_6Cl(RE=Pr、Eu、Tb、Dy)小单晶和多晶粉末样品。测定其晶体结构与LaNb_2O_6Cl的晶体结构相同,为正交晶系;Eu_(0.06)La_(0.94)Nb_2O_6Cl小单晶的晶胞参数为:a=9.751,b=7.321,c=8.364。观察RE_(0.06)La_(0.94)Nb_2O_6Cl(RE=Pr、Eu、Tb、Dy)的特征激发光谱和发射光谱及其能量传递现象。

A new species of Ptilagrostis Griseb. (Poaceae) from Xizang, China

Ptilagrostis macrospicula L.B.Cai, sp.nov. Fig.1

并联柔索驱动操作臂静刚度的理论分析

文章对并联柔索驱动机器人(PWDRs)的静态刚度问题进行了理论分析。首先，基于微分变换原理，提出并证明了关于柔索矩阵微小变化变分形式的命题，在此基础上推导了操作臂完整刚度的解析公式，它包括与结构参数有关的刚度及与柔索张力有关的刚度两部分。然后，对这一理论结果进行了数值仿真。研究结果表明：操作臂刚度不仅依赖于机构几何尺寸、柔索与电机刚度及操作臂位置与姿态等结构参数，还与柔索的张力有关、因此，可以通过改变柔索张力来调节PWDRs操作臂的刚度．实现机构变刚度。

一种具有虚拟力反馈的机器人遥操作实验系统

本文以基于网络的遥操作为背景，建立了虚拟力反馈的机器人遥操作实验系统，进行了控制系统结构、虚拟力对位置的转换模型、力觉和触觉再现等关键技术的研究.在该实验系统中，操作者可以根据显示器上的字符数据和图形环境的示意，在虚拟力的引导下操作移动机器人。实验结果表明，该系统中移动机器人对规则矩形的跟踪，具有虚拟障碍和虚拟墙引导时的操作性能很好。

基于传感器的模糊参数自整定柔性关节抑制震动的研究

本文以谐波驱动系统为例分析了柔性关节机械手的动力学特性，通过电机端和负载端PD控制结合负载端的加速度反馈控制，并采用模糊参数自整定方法，能有效的抑制负载端的振动，通过几种方法的仿真结果比较表明，提出的方法是有效的。

Petri网理论在FMS中的应用

本文以Petri网理论为工具，对一类柔性制造系统进行了分析。首先进行了Petri网理论研究及与柔性制造系统结合等方面的全面综述，为Petri网理论在生产系统中的应用作好了准备。从Petri网理论的角度提出了DEDS稳定性的定义和分析方法，并分析了系统的死镇性、有界性、守恒性等一系列性质，以这些结论为基础，又研究了流水车间和作业车间的动态优化排序问题，得出以下结果。1．用时间事件圈分析流水车间，可以得出流水车间中任何排序都是可行排序，并且给定任何一种排序，只要初始时有足够的托盘配置，稳态好总能使瓶颈机器满负荷利用，系统生产率最大。2．同样分析作业车间，得出作业车间不可行排序的制定条件，并且给定任何一种排序，只要初始时有足够的资源托盘和半制品存在，总能使瓶颈机器满负荷利用，系统生产率最大。3．为使瓶颈机器满负荷利用，且在制品库存最少，得出了一个求解最少在制品库存的整数线性规划，并给出了几种求解整数线性规划的启发式算法。4．对一种类型的FMS，给出了托盘数的上限估计，缓冲器的最小容量等。对于减少在制品库存，降低生产成本，确保系统稳定运行，这些都是非常重要的条件。5．定义了过渡过程时间，分析了过渡过程问题，在某种条件下能使系统从初态直接进行稳态。

右江沉积盆地演化与微细浸染型金矿床成矿作用关系探讨

右江沉积盆地在大地构造位置上被称为右江印支褶皱带，其沉积一构造演化可划分为3个阶段：大陆边缘裂谷、弧后裂谷和坳陷盆地。桂西北地区是右江盆地的主体部分，该区典型微细浸染型金矿床(金牙、高龙)的含矿硅质岩特征、矿床的地质特征、地球化学特征、矿石组构学特征一致袁明矿床在沉积成岩期已形成，矿床属同生沉积成因。矿床的形成与右江沉积盆地演化密切相关。裂谷环境、盆地的岩相古地理、同沉积断裂等因素对矿床的形成起重要的控制作用。

Preparation of monolithic silica column with strong cation-exchange stationary phase for capillary electrochromatography

A monolithic silica based strong cation-exchange stationary phase was successfully prepared for capillary electrochromatography. The monolithic silica matrix from a sol-gel process was chemically modified by treatment with 3-mercaptopropyltrimethoxysilane followed by a chemical oxidation procedure to produce the desired function. The strong cation-exchange stationary phase was characterized by its substantial and stable electroosmotic flow (EOF), and it was observed that the EOF value of the prepared column remained almost unchanged at different buffer pH values and slowly decreased with increasing phosphate concentration in the mobile phase. The monolithic silica column with strong cation-exchange stationary phase has been successfully employed in the electrochromatographic separation of beta-blockers and alkaloids extracted from traditional Chinese medicines (TCMs). The column efficiencies for the tested beta-blockers varied from 210,000 to 340,000 plates/m. A peak compression effect was observed for atenolol with the mobile phase having a low phosphate concentration.

Carpeta de diseño.

6 hojas : ilustraciones.

Our life among the Iroquois Indians

http://www.archive.org/details/ourlifeamongiroq00caswiala

Chikungunya and dengue fever among hospitalized febrile patients in northern Tanzania.

Consecutive febrile admissions were enrolled at two hospitals in Moshi, Tanzania. Confirmed acute Chikungunya virus (CHIKV), Dengue virus (DENV), and flavivirus infection were defined as a positive polymerase chain reaction (PCR) result. Presumptive acute DENV infection was defined as a positive anti-DENV immunoglobulin M (IgM) enzyme-linked immunsorbent assay (ELISA) result, and prior flavivirus exposure was defined as a positive anti-DENV IgG ELISA result. Among 870 participants, PCR testing was performed on 700 (80.5%). Of these, 55 (7.9%) had confirmed acute CHIKV infection, whereas no participants had confirmed acute DENV or flavivirus infection. Anti-DENV IgM serologic testing was performed for 747 (85.9%) participants, and of these 71 (9.5%) had presumptive acute DENV infection. Anti-DENV IgG serologic testing was performed for 751 (86.3%) participants, and of these 80 (10.7%) had prior flavivirus exposure. CHIKV infection was more common among infants and children than adults and adolescents (odds ratio [OR] 1.9, P = 0.026) and among HIV-infected patients with severe immunosuppression (OR 10.5, P = 0.007). CHIKV infection is an important but unrecognized cause of febrile illness in northern Tanzania. DENV or other closely related flaviviruses are likely also circulating.