294 resultados para 4-oxo-3-aza-bicyclo[3.1.0]hexane


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Pressing scientific questions concerning the Greenland ice sheet's climatic sensitivity, hydrology, and contributions to current and future sea level rise require hydrological datasets to resolve. While direct observations of ice sheet meltwater losses can be obtained in terrestrial rivers draining the ice sheet and from lake levels, few such datasets exist. We present a new dataset of meltwater river discharge for the vicinity of Kangerlussuaq, Southwest Greenland. The dataset contains measurements of river stage and discharge for three sites along the Akuliarusiarsuup Kuua (Watson) River's northern tributary, with 30 minute temporal resolution between June 2008 and August 2010. Additional data of water temperature, air pressure, and lake water depth and temperature are also provided. Discharge data were measured at sites with near-ideal properties for such data collection. Regardless, high water bedload and turbulent flow introduce considerable uncertainty. These were constrained and quantified using statistical techniques, thereby providing a high quality dataset from this important site. The greatest data uncertainties are associated with streambed elevation change and measurements. Large portions of stream channels deepened according to statistical tests, but poor precision of streambed depth measurements also added uncertainty. Quality checked data are freely available for scientific use as supplementary online material.

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The air trapped in freshly formed ice gives information concerning the ice formation processes as weH as concerning severa,l environmental parameters at the time of ice formation. Air arnount, air composition, and the size and form of bubbles may change with time. Possible processes responsible for such changes are discussed. In very cold ice air content and air composition remain almost unchanged. Samples of ancient atmospheric air are therefore very weH preserved in cold ice. In temperate ice changes of the air amount and air composition depend on the intergranular water fiow through the glacier. This waterfiow can be estimated by measuring air amount and air composition in ice sampIes.

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The Th content of the sediment samples from "Meteor" core GIK12310-4 (3080 m water depth, off NW Africa) on a carbonate-free basis lies around the average of 12.4 ppm and is similar to the average content of the earth crust. On the contrary, uranium was found to be up to 3.5-fold enriched in the core section between 60 and 330 cm (within the Wuerm Glacial) where reducing conditions occur, due to deposition of authigenic uranium (9 µg/cm**2 1000 yrs.). The authigenic uranium content is correlated to the organic matter content (U/Corg ratio = 6 * 10**4). On the basis of the uranium content of the oxidized section uranium was split into a detritic and an authigenic component and the amount of supported ionium was calculated. From the profile of the specific Io-cxcess activity (= Io-total - Io-supported) with depth, average sedimentation rates of 3.3 ± 0.6 cm/1000 yrs. for the warmer stages and of 5 ± 1 cm/l000 yrs. for the cooler periods were estimated.

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The International Bathymetric Chart of the Southern Ocean (IBCSO) Version 1.0 is a new digital bathymetric model (DBM) portraying the seafloor of the circum-Antarctic waters south of 60° S. IBCSO is a regional mapping project of the General Bathymetric Chart of the Oceans (GEBCO). IBCSO Version 1.0 DBM has been compiled from all available bathymetric data collectively gathered by more than 30 institutions from 15 countries. These data include multibeam and single beam echo soundings, digitized depths from nautical charts, regional bathymetric gridded compilations, and predicted bathymetry. Specific gridding techniques were applied to compile the DBM from the bathymetric data of different origin, spatial distribution, resolution, and quality. The IBCSO Version 1.0 DBM has a resolution of 500 x 500 m, based on a polar stereographic projection, and is publicly available together with a digital chart for printing from the project website (http://www.ibcso.org) and from the two data sets shown at the bottom of this page.

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The majority of global ocean production and total export production is attributed to oligotrophic oceanic regions due to their vast regional expanse. However, energy transfers, food-web structures and trophic relationships in these areas remain largely unknown. Regional and vertical inter- and intra-specific differences in trophic interactions and dietary preferences of calanoid copepods were investigated in four different regions in the open eastern Atlantic Ocean (38°N to 21°S) in October/November 2012 using a combination of fatty acid (FA) and stable isotope (SI) analyses. Mean carnivory indices (CI) based on FA trophic markers generally agreed with trophic positions (TP) derived from d15N analysis. Most copepods were classified as omnivorous (CI ~0.5, TP 1.8 to ~2.5) or carnivorous (CI >=0.7, TP >=2.9). Herbivorous copepods showed typical CIs of <=0.3. Geographical differences in d15N values of epi- (200-0 m) to mesopelagic (1000-200 m) copepods reflected corresponding spatial differences in baseline d15N of particulate organic matter from the upper 100 m. In contrast, species restricted to lower meso- and bathypelagic (2000-1000 m) layers did not show this regional trend. FA compositions were species-specific without distinct intra-specific vertical or spatial variations. Differences were only observed in the southernmost region influenced by the highly productive Benguela Current. Apparently, food availability and dietary composition were widely homogeneous throughout the oligotrophic oceanic regions of the tropical and subtropical Atlantic. Four major species clusters were identified by principal component analysis based on FA compositions. Vertically migrating species clustered with epi- to mesopelagic, non-migrating species, of which only Neocalanus gracilis was moderately enriched in lipids with 16% of dry mass (DM) and stored wax esters (WE) with 37% of total lipid (TL). All other species of this cluster had low lipid contents (< 10% DM) without WE. Of these, the tropical epipelagic Undinula vulgaris showed highest portions of bacterial markers. Rhincalanus cornutus, R. nasutus and Calanoides carinatus formed three separate clusters with species-specific lipid profiles, high lipid contents (>=41% DM), mainly accumulated as WE (>=79% TL). C. carinatus and R. nasutus were primarily herbivorous with almost no bacterial input. Despite deviating feeding strategies, R. nasutus clustered with deep-dwelling, carnivorous species, which had high amounts of lipids (>=37% DM) and WE (>=54% TL). Tropical and subtropical calanoid copepods exhibited a wide variety of life strategies, characterized by specialized feeding. This allows them, together with vertical habitat partitioning, to maintain high abundance and diversity in tropical oligotrophic open oceans, where they play an essential role in the energy flux and carbon cycling.