Modelling thermodynamic properties of banana waste by analytical derivation of desorption isotherms

Banana is an agricultural product of great economic importance for various developing countries. The relationship between moisture content and water activity provides useful information for the processing and storage of banana waste. The water activity and moisture content of three banana (Mussa spp. Haploid AAB cv. Nanica) waste items were analyzed to determine the desorption isotherms at six different temperatures (20, 30, 40, 50, 60 and 70°C). The desorption isotherms of the peel, pedicel and pulp of overripe bananas were determined in wide ranges of moisture content (0.001-6.360 kg kg-1 d.b.) and water activity (0.02-0.907). The theoretical GAB model was used for modelling the desorption isotherms. An analytical solution of the Clausius-Clapeyron equation was proposed to compute the isosteric heat of sorption, the differential entropy and Gibbs' free energy by way of the GAB model when the effect of temperature on the hygroscopic equilibrium was considered. © 2012 de Gruyter. All rights reserved.

Lê cycles and Milnor classes

The purpose of this work is to establish a link between the theory of Chern classes for singular varieties and the geometry of the varieties in question. Namely, we show that if Z is a hypersurface in a compact complex manifold, defined by the complex analytic space of zeroes of a reduced non-zero holomorphic section of a very ample line bundle, then its Milnor classes, regarded as elements in the Chow group of Z, determine the global Lê cycles of Z; and vice versa: The Lê cycles determine the Milnor classes. Morally this implies, among other things, that the Milnor classes determine the topology of the local Milnor fibres at each point of Z, and the geometry of the local Milnor fibres determines the corresponding Milnor classes. © 2013 Springer-Verlag Berlin Heidelberg.

Experimental results and thermodynamic analysis of a natural gas small scale cogeneration plant for power and refrigeration purposes

In this work, experimental results are reported for a small scale cogeneration plant for power and refrigeration purposes. The plant includes a natural gas microturbine and an ammonia/water absorption chiller fired by steam. The system was tested under different turbine loads, steam pressures and chiller outlet temperatures. An evaluation based on the 1st and 2nd Laws of Thermodynamics was also performed. For the ambient temperature around 24°C and microturbine at full load, the plant is able to provide 19 kW of saturated steam at 5.3 bar (161 °C), corresponding to 9.2 kW of refrigeration at -5 °C (COP = 0.44). From a 2nd law point-of-view, it was found that there is an optimal chiller outlet temperature that maximizes the chiller exergetic efficiency. As expected, the microturbine presented the highest irreversibilities, followed by the absorption chiller and the HRSG. In order to reduce the plant exergy destruction, it is recommended a new design for the HRSG and a new insulation for the exhaust pipe. © 2013 Elsevier Ltd. All rights reserved.

An analysis of diurnal cycles in the mass of ambient aerosols derived from biomass burning and agro-industry

Strong diurnal cycles in ambient aerosol mass were observed in a rural region of Southeast Brazil where the trace composition of the lower troposphere is governed mainly by emissions from agro-industry. An optical particle counter was used to record size-segregated aerosol number concentrations between 13 May 2010 and 15 March 2011. The data were collected every 10 min and used to calculate aerosol mass concentrations. Aerosol samples were also collected onto filters during daytime (10:00-16:00 local time) and nighttime (20:00-06:00) periods, for subsequent analysis of soluble ions and water-soluble organic carbon. Biomass burning aerosols predominated during the dry winter, while secondary aerosols were most important in the summer rainy season. In both seasons, diurnal cycles in calculated aerosol mass concentrations were due to the uptake of water by the aerosols and, to a lesser extent, to emissions and secondary aerosol formation. In neither season could the observed mass changes be explained by changes in the depth of the boundary layer. In the summer, nighttime increases in aerosol mass ranged from 2.7-fold to 81-fold, depending on particle size, while in the winter, the range was narrower, from 2.2-fold to 9.5-fold, supporting the possibility that the presence of particles derived from biomass burning reduced the overall ability of the aerosols to absorb water. Key Points Diurnal cycle of agro-industrial aerosol mass governed by humidity Biomass burning emissions act to suppress particle growth Need to consider diurnal mass cycles in aerosol dry deposition models ©2013. American Geophysical Union. All Rights Reserved.

Biosorption of cadmium (II) and lead (II) from aqueous solution using exopolysaccharide and biomass produced by Colletotrichum sp.

The biosorption of Cd(II) and Pb(II) ions on biomass and exopolysaccharide (EPS) produced by Colletotrichum sp. fungus has been investigated as a function of contact time, initial pH, initial metal ion concentration, and initial adsorbent concentration in a batch system. Adsorption equilibrium was described by Freundlich and Langmuir isotherms. Adsorption was characterized through granulometry, SEM and EDX analysis. Then, studies were performed to regenerate the adsorbent. Biosorption of metals by biomass and EPS were best described by the Langmuir and Freundlich isotherm, respectively. Results of thermodynamic investigations showed that adsorption reactions were spontaneous (ΔG° < 0), exothermal, and mainly physical. The EPS was able to remove 79 and 98% of cadmium and lead, respectively, and the biomass removed 85 and 84% of cadmium and lead, respectively, in a solution with initial concentration 100 mg L-1, and the four adsorption-desorption cycles of all adsorbents showed up with great regenerative capacity and relative stability after these four cycles, the high potential of these biological materials in sorption has been shown. © 2013 Copyright Balaban Desalination Publications.

Desenvolvimento e teste de um programa computacional para simulação de plantas térmicas e de potência

Pós-graduação em Engenharia Mecânica - FEIS

Modelagem e simulação de sistemas de geração de energia para o setor de petróleo e gás

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Birth of limit cycles bifurcating from a nonsmooth center

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Prediction of dopant atom distribution on nanocrystals using thermodynamic arguments

A theoretical approach aiming at the prediction of segregation of dopant atoms on nanocrystalline systems is discussed here. It considers the free energy minimization argument in order to provide the most likely dopant distribution as a function of the total doping level. For this, it requires as input (i) a fixed polyhedral geometry with defined facets, and (ii) a set of functions that describe the surface energy as a function of dopant content for different crystallographic planes. Two Sb-doped SnO2 nanocrystalline systems with different morphology and dopant content were selected as a case study, and the calculation of the dopant distributions expected for them is presented in detail. The obtained results were compared to previously reported characterization of this system by a combination of HRTEM and surface energy calculations, and both methods are shown to be equivalent. Considering its application pre-requisites, the present theoretical approach can provide a first estimation of doping atom distribution for a wide range of nanocrystalline systems. We expect that its use will support the reduction of experimental effort for the characterization of doped nanocrystals, and also provide a solution to the characterization of systems where even state-of-art analytical techniques are limited.

Study of Thermodegradation and Thermostabilization of Poly( lactide acid) Using Subsequent Extrusion Cycles

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Limit Cycles for a Class of Continuous and Discontinuous Cubic Polynomial Differential Systems

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Thermodynamic and economic analysis of hydrogen production integration in the Brazilian sugar and alcohol industry

One of the biggest challenges today is to develop clean fuels, which do not emit pollutant and with viable implementation. One of the options currently under study is the hydrogen production process. In this context, this work aims to study the technical and economical aspects of the incorporation process of hydrogen producing by ethanol steam reforming in the sugar cane industry and MCFC (molten carbonate fuel cell) application on it to generate electric power. Therefore, it has been proposed a modification in the traditional process of sugar cane industry, in order to incorporate hydrogen production, besides the traditional products (sugar, ethylic, hydrated and anhydric alcohol). For this purpose, a detailed theoretical study of the ethanol production process, describing the considerations to incorporate the hydrogen production will be performed. After that, there will be a thermodynamic study for analysing the innovation of this production chain, as well as a study of economic engineering to allocate the costs of products of the new process, optimising it and considering the thermoeconomics as being as an analysis tool. This proposal aims to improve Brazil's position in the ranking of international biofuels, corroborating the nation to be a power in the hydrogen era. (C) 2013 Elsevier Ltd. All rights reserved.

Limit cycles of cubic polynomial differential systems with rational first integrals of degree 2

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Short-term cycles of feed deprivation and refeeding promote full compensatory growth in the Amazon fish matrinxa (Brycon amazonicus)

Developing nutritional strategies that can reduce production costs for the fish industry without affecting productive performance is paramount to make the activity sustainable. We investigated if short-term cycles of feed deprivation and refeeding elicit compensatory growth in matrinxa (Brycon amazonicus) juveniles, using three feeding protocols for 60 days (Phase 1): two levels of deprivation (feed deprivation for two days and refeeding for three - D2R3, or four days - D2R4) and a control level (daily feeding). Following, all fish groups were fed daily at satiation for 15 days (Phase 2). At Phase 1, matrinxa achieved full compensatory growth in both deprivation levels by increasing feed intake and feed efficiency. Overall, deprived fish consumed 40% (D2R3) and 36% (D2R4) less feed than fish fed daily. In Phase 2, growth was similar for all fish. Feed intake increased in both deprived fish, but feed efficiency did not differ among groups and was lower than in Phase 1, indicating a reduced efficiency in feed utilization when food was freely available. We propose that intermittent cycles of feeding represent an effective means to reduce production costs. (C) 2014 Elsevier B.V. All rights reserved.