Influence of structural disorder on the photoluminescence emission of PZT powders

Intense and broad visible photoluminescent (PL) band was observed at room temperature in disordered Pb(Zr(0.53)Ti(0.47))O(3) powders. Structural order-disorder was evaluated by different methods. XANES results pointed to the presence of different coordination modes of disordered Ti powders, and in the ordered sample the local structure around titanium atoms is characteristic of the structurally ordered PZT with only TiO(6) units. Only samples containing simultaneous structural order and disorder in their network present the intense visible PL emission at room temperature.

Disorder-dependent photoluminescence in Ba0.8Ca0.2TiO3 at room temperature

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Influence of the modifier on the short and long range disorder of stannate perovskites

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Depinning and vortex-glass-like transition in Nb with uncorrelated disorder

Studies of the third harmonic of the AC-susceptibility were conducted to detect the boundaries of the linear regime of the magnetic response of granular Nb samples. These studies reveal the extent of the region, on the phase diagram, where the magnetic response is linear, which corresponds to the disordered phase of Vortex Matter. The present work addresses the correlation between a linear response and experimental parameters such as the frequency and the amplitude of the excitation field. The order-disorder border has been extracted from the onset temperature of the third harmonic measured at low-frequencies and low-excitation fields in the presence of dc magnetic fields. © 2008 IOP Publishing Ltd.

Structural disorder-dependent upconversion in Er3+/Yb3+-doped calcium titanate

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Photoluminescence of BaZrO3 explained by a order/disorded transformation

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Photoluminescence of barium-calcium titanates obtained by the microwave-assisted hydrothermal method (MAH)

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Strutural and optical approach of CdS@ZnS core-shell system

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Intense blue and green photoluminescence emissions at room temperature in barium zirconate powders

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Intense visible photoluminescence in Ba(Zr0.25Ti0.75)O-3 thin films

Photoluminescence at room temperature in Ba(Zr0.25Ti0.75)O-3 thin films was explained by the degree of structural order-disorder. Ultraviolet-visible absorption spectroscopy, photoluminescence, and first principles quantum mechanical measurements were performed. The film annealed at 400 degrees C for 4 h presents intense visible photoluminescence behavior at room temperature. The increase of temperature and annealing time creates [ZrO6]-[TiO6] clusters in the lattice leading to the trapping of electrons and holes. Thus, [ZrO5]-[TiO6]/[ZrO6]-[TiO6] clusters were the main reason for the photoluminescence behavior.

Combined experimental and theoretical investigations of the photoluminescent behavior of Ba(Ti,Zr)O-3 thin films

The correlation between experimental data and theoretical calculations have been investigated to explain the photoluminescence at room temperature of Ba(Ti0.75Zr0.25)O-3 (BTZ) thin films prepared by the polymeric precursor method. The degree of structural order-disorder was investigated by X-ray diffraction, Fourier transform infrared spectroscopy, ultraviolet-visible absorption spectroscopy and photoluminescence (PL) measurements. First-principles quantum mechanical calculations based on density functional theory (B3LYP level) were employed to study the electronic structure of ordered and deformed asymmetric models. The electronic properties are analyzed and the relevance of the present theoretical and experimental results on the PL behavior is discussed. The presence of localized electronic levels and a charge gradient in the band gap due to a break in symmetry, are responsible for the PL in disordered BTZ lattice. (c) 2007 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

Voltage-composition profile and synchrotron X-ray structural analysis of low and high temperature LixCoO2 host material

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Synthesis, characterization, structural refinement and optical absorption behavior of PbWO(4) powders

The present paper describes the synthesis, characterization, structural refinement and optical absorption behavior of lead tungstate (PbWO(4)) powders obtained by the complex polymerization method heat treated at different temperatures for 2h in air atmosphere. PbWO(4) powders were characterized by X-ray diffraction (XRD), Rietveld refinement, Fourier transform Raman (FT-Raman) spectroscopy and ultraviolet visible (UV-vis) absorption spectroscopy measurements. XRD, Rietveld refinement and FT-Raman revealed that PbWO(4) powders are free of secondary phases and crystallizes in a tetragonal structure. The UV-vis absorption spectroscopy measurements suggest the presence of intermediary energy levels into the band gap of structurally disordered powders. (C) 2008 Elsevier B.V. All rights reserved.

Structural XANES characterization of Ca0.99Sm0.01TiO3 perovskite and correlation with photoluminescence emission

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Room temperature photoluminescence of BCT prepared by Complex Polymerization Method

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)