Room temperature photoluminescence of BCT prepared by Complex Polymerization Method


Autoria(s): Motta, F. V.; Marques, A. P. A.; Espinosa, J. W. M.; Pizani, P. S.; Longo, Elson; Varela, José Arana
Contribuinte(s)

Universidade Estadual Paulista (UNESP)

Data(s)

20/05/2014

20/05/2014

01/01/2010

Resumo

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

It was used the Complex Polymerization Method to synthesize barium calcium titanate powders (BCT). Crystalline Ba(0.8)Ca(0.2)TiO(3) perovskite-type phase could be identified by X-ray diffraction and confirmed by Raman spectroscopy in the powders heat treated at 600 degrees C. Inherent defects, linked to structural disorder, facilitate the photoluminescence emission. The photoluminescent emission peak maximum was around of 533 nm (2.33 eV) for the Ba(0.8)Ca(0.2)TiO(3). The photoluminescence process and the band emission energy photon showed dependence of both the structural order-disorder and the thermal treatment history. The results revealed that Ba(0.8)Ca(0.2)TiO(3) (BCT20) is a highly promising candidate material for optical applications. (C) 2009 Elsevier B.V. All rights reserved.

Formato

16-20

Identificador

http://dx.doi.org/10.1016/j.cap.2009.04.005

Current Applied Physics. Amsterdam: Elsevier B.V., v. 10, n. 1, p. 16-20, 2010.

1567-1739

http://hdl.handle.net/11449/25558

10.1016/j.cap.2009.04.005

WOS:000270584900004

Idioma(s)

eng

Publicador

Elsevier B.V.

Relação

Current Applied Physics

Direitos

closedAccess

Palavras-Chave #Barium calcium titanate #Order-disorder transition #Optical properties #Photoluminescence
Tipo

info:eu-repo/semantics/article