Intense visible photoluminescence in Ba(Zr0.25Ti0.75)O-3 thin films


Autoria(s): Cavalcante, L. S.; Gurgel, M. F. C.; Simoes, A. Z.; Longo, Elson; Varela, José Arana; Joya, M. R.; Pizani, P. S.
Contribuinte(s)

Universidade Estadual Paulista (UNESP)

Data(s)

20/05/2014

20/05/2014

01/01/2007

Resumo

Photoluminescence at room temperature in Ba(Zr0.25Ti0.75)O-3 thin films was explained by the degree of structural order-disorder. Ultraviolet-visible absorption spectroscopy, photoluminescence, and first principles quantum mechanical measurements were performed. The film annealed at 400 degrees C for 4 h presents intense visible photoluminescence behavior at room temperature. The increase of temperature and annealing time creates [ZrO6]-[TiO6] clusters in the lattice leading to the trapping of electrons and holes. Thus, [ZrO5]-[TiO6]/[ZrO6]-[TiO6] clusters were the main reason for the photoluminescence behavior.

Formato

3

Identificador

http://dx.doi.org/10.1063/1.2425013

Applied Physics Letters. Melville: Amer Inst Physics, v. 90, n. 1, 3 p., 2007.

0003-6951

http://hdl.handle.net/11449/25429

10.1063/1.2425013

WOS:000243379900023

WOS000243379900023.pdf

Idioma(s)

eng

Publicador

American Institute of Physics (AIP)

Relação

Applied Physics Letters

Direitos

closedAccess

Tipo

info:eu-repo/semantics/article