35 resultados para Sarkovskii ordering
Resumo:
Tutkimuksen tavoitteena oli selvittää palveluvarastoinnin vaikutukset hankinnan kokonaiskustannuksiin ja luoda palveluvaraston toimintakonsepti. Toimintakonsepti pitää sisällään informaatio- ja materiaalivirtojen hallinta- ja ohjausprosessit toimittajan, palveluvaraston ja diplomityön kohdeyrityksen välillä. Tutkimuksen alussa tehtiin kustannusvertailu kahden vaihtoehtoisen toimittajan välillä. Toinen vaihtoehdoista edellyttää välivarastointia palveluvarastossa. Kustannusvertailun pohjalta kohdeyrityksessä päätettiin vaihtaa toimittajaa ja ottaa käyttöön palveluvarasto. Palveluvaraston toimintakonseptin luomista varten yrityksessä perustettiin projektiryhmä. Tutkimuksen kirjoittaja toimi projektiryhmän vetäjänä. Tutkimuksessa luotiin palveluvaraston toimintakonsepti, joka perustuu vendor- managed inventory-toimintamalliin. VMI-toimintaa varten kehitettiin ohjausraportti, jonka avulla kohdeyritys voi valvoa varastotasoja palveluvarastossa, ja jonka avulla toimittajat ohjaavat varastotäydennyksiä palveluvarastolle. Palveluvaraston ja kohdeyrityksen välille luotiin lisäksi RFID-teknologiaa hyödyntävä tilausprosessi. Kohdeyrityksessä voidaan tulevaisuudessa hyödyntää palveluvarastoa kansainvälisen hankinnan logistiikan hallintaan.
Resumo:
In this work, Sr2FeMoO6 (SFMO) thin films were studied with the main focus on their magnetic and magneto-transport properties. The fabrication process of pulsed laser deposited SFMO films was first optimized. Then the effects of strain, film thickness and substrate were thoroughly investigated. In addition to these external factors, the effect of intrinsic defects on the magnetic properties of SFMO were also clarified. Secondly, the magnetoresistivity mechanims of SFMO films were studied and a semiempirical model of the temperature dependence of resistivity was introduced. The films were grown on single crystal substrates using a ceramic target made with sol-gel method. The structural characterization of the films were carried out with X-ray diffraction, atomic force microscopy, transmission electron microscopy and high kinetic energy photoelectron spectroscopy. The magnetic properties were measured with SQUID magnetometer and the magneto-transport properties by magnetometer with a resistivity option. SFMO films with the best combination of structural and magnetic properties were grown in Ar atmosphere at 1050 °C . Their magnetic properties could not be improved by the ex situ post-annealing treatments aside from the treatments in ultra-high vacuum conditions. The optimal film thickness was found to be around 150 nm and only small improvement in the magnetic properties with decreasing strain was observed. Instead, the magnetic properties were observed to be highly dependent on the choice of the substrate due to the lattice mismatch induced defects, which are best avoided by using the SrTiO3 substrate. The large difference in the Curie temperature and the saturation magnetization between the SFMO thin film and polycrystalline bulk samples was connected to the antisite disorder and oxygen vacancies. Thus, the Curie temperature of SFMO thin films could be improved by increasing the amount of oxygen vacancies for example with ultra-high vacuum treatments or improving the B-site ordering by further optimization of the deposition parameters. The magneto-transport properties of SFMO thin films do not follow any conventional models, but the temperature dependence of resistivity was succesfully described with a model of two spin channel system. Also, evidences that the resistivity-temperature behaviour of SFMO thin films is dominated by the structural defects, which reduce the band gap in the majority spin band were found. Moreover, the magnetic field response of the resistivity in SFMO thin films were found to be superposition of different mechanisms that seems to be related to the structural changes in the film.
Resumo:
Imatralla tilaaja-tuottaja-malliin liittyvä nykyinen sopimusohjausmalli otettiin käyttöön teknisellä toimialalla marraskuussa 2014, jolloin kiinteistö- ja aluepalveluiden tuottamiseen perustettiin oma yhtiö. Tilaaminen ja tuottaminen muodostaa tilaus-toimitusketjun. Tämän työn tarkoituksena oli saada tietoa nykyisen kiinteistö- ja aluepalveluiden tilaus-toimitusketjun toimivuudesta sekä vahvuuksista ja puutteista. Työn teoriaosassa perehdyttiin strategiaprosessiin kunnissa, tilaaja-tuottaja-toimintatapaan sekä yhtiöittämiseen ja tuloksellisuuteen. Käytännön tietoa tilaus-toimitusketjusta saatiin strukturoidulla haastattelulla. Haastattelu jaettiin strategiseen, sopimusohjaustasoon sekä operatiiviseen tasoon. Haastateltavina oli toimitusketjun eri osapuolia. Työn tuloksena voidaan todeta, että strategian täytäntöönpanossa on vielä tekemistä, etenkin operatiivisella puolella. Sopimusohjausmalliin oltiin tyytyväisiä vaikka myös siitä löytyi vielä kehitettävää. Operatiivisella tasolla toiminnan tehokkuus on noussut verrattuna entiseen malliin, tehokkuutta voidaan kuitenkin vielä monin keinoin nostaa. Yleisesti nähtiin, että koko tilaus-toimitusketjun toiminta on tehostunut ja selkiytynyt.
Resumo:
In this work, a colossal magnetoresistive (CMR) Pr1−xCaxMnO3 (PCMO) man- ganite thin films and polycrystalline samples were studied with the main focus on the properties of the insulator to metal Mott phase transition. The polycrystalline PCMO samples were fabricated with the solid state reaction method. The polycrystalline sam- ples were further processed into the epitaxial thin films with the pulsed laser deposition method (PLD). The structural and magnetic properties of the samples were systemat- ically investigated and the thin films samples were further investigated with magneto- transport measurement where the thin films response to illumination was also studied. After the successful synthesis of polycrystalline PCMO samples with varying x = between 0.0 - 0.5, the magnetic characterization of the samples showed rich magnetic properties having the signatures of the magnetic phase coexistence of antiferromag- netic (AFM) and ferromagnetic (FM) ordering and cluster glass behaviour. With the increased doping concentration from x = 0.3 to 0.5, the AFM charge-order (CO) phase started to form up being strongest on the sample x = 0.5. This AFM CO phase could be melted with the high external magnetic field at temperatures below Neel’s tempera- ture TN inducing an irreversible first order metamagnetic AFM to FM phase transition. The strength of the AFM CO phase decreased with decreasing Ca concentration and increasing temperature. The polycrystalline PCMO samples with Ca concentrations of 0.3 - 0.5, showing metamagnetic behaviour, were selected for the fabrication of the thin film samples. The films were grown using two different in situ oxygen treatment temperatures at 500 ◦C and 700 ◦C in the PLD system. The films with x = 0.4 and 0.5 showed weaker AFM CO phase with greatly reduced melting fields when compared to polycrystalline samples. Also, the robustness of the AFM CO phase was further decreased in thin films with the lower oxygen treatment temperature of 500 ◦C. The magneto-transport measurements made on the thin films showed that the melting of AFM CO phase was connected to CMR effect where the increasing magnetic field induced an insulator to metal phase transition, which reduces the resistivity of the film around nine orders of magnitude. The use of illumination during the magneto-transport measurements showed a vari- ety of intriguing phenomena including magnetophotoresistance. The illumination had a huge effect to the insulator to metal transition (IMT) reducing the transition magnetic field significantly. Moreover, by magnetically biasing the thin films with the constant external magnetic field, the IMT could be induced by switching on the illumination.
Resumo:
In my thesis I examine J.R.R. Tolkien’s The Lord of the Rings (1954-55), the fantasy epic written on the basis of a fictional universe created by Tolkien, complete with elves, dwarves and other mystical creatures – with languages, alphabets and grammar created for all. While rich linguistically, Tolkien writes a decidedly male description of his world, often neglecting any acknowledgement of female existence. Tolkien’s monolithic stature amongst other fantasy authors made me conduct a feminist reading of The Lord of the Rings, with an eye for the way female experience is marginalized to the point of omission. Tolkien’s linguistic accomplishments have overshadowed the illogical aspects of his work, namely the omission of genders, societal classes and features of society necessary for the fictional universe to retain its cohesion. This cohesion suffers from a totally male experience in the novel which is willfully blind to these features I listed. My theoretical framework is built on ideas in Toril Moi’s Sex, Gender and the Body (2005) and bell hook’s Feminism is For Everybody (2000). Michel Foucault’s ideas of power and hidden histories assist in performing a close reading of the source text and interpreting the results. My thesis focuses on the transformation that the values associated with the concept of equality have undergone. This is best illustrated in the treatment of the few female characters in the novel – Galadriel, Éowyn and Arwen – as their beauty and existence interferes with the ordering of the male-dominated world.