Experimental study of the mechanical properties and durability of self-compacting mortars with nano materials (SiO2 and TiO2)

Resumo: Cement, as well as the remaining constituents of self-compacting mortars, must be carefully selected, in order to obtain an adequate composition with a granular mix as compact as possible and a good performance in the fresh state (self-compacting effect) and the hardened state (mechanical and durability-related behavior). Therefore in this work the possibility of incorporating nano particles in self-compacting mortars was studied. Nano materials are very reactive due mostly to their high specific surface and show a great potential to improve the properties of these mortars, both in mechanical and durability terms. In this work two nano materials were used, nano silica (nano SiO2) in colloidal state and nano titanium (nano TiO2) in amorphous state, in two types of self-compacting mortars (ratio binder:sand of 1:1 and 1:2). The self-compacting mortar mixes have the same water/cement ratio and 30% of replacement of cement with fly ashes. The influence of nano materials nano-SiO2 and nano-TiO2 on the fresh and hardened state properties of these self-compacting mortars was studied. The results show that the use of nano materials in repair and rehabilitation mortars has significant potential but still needs to be optimized. (C) 2015 Elsevier Ltd. All rights reserved.

O currículo e as necessidades educativas especiais : práticas de adequação curricular no terceiro ciclo

A responsabilidade da construção de uma escola para todos deve ser o grande objectivo de todo e qualquer professor, criando espaços de reflexão conjunta no sentido de serem traçados projectos curriculares diferenciados que dêem resposta a todos os alunos na sua diversidade plural. Assim, a concepção e construção da escola inclusiva implicam mudanças, quer nas atitudes e práticas dos agentes educativos, quer nas estruturas do sistema de ensino ao nível organizacional e da gestão curricular. Neste âmbito, a adequação do currículo às necessidades educativas especiais (NEE) dos alunos torna-se essencial na (re)construção e operacionalização dos diferentes processos curriculares. O trabalho que agora se apresenta foi desenvolvido através de um estudo de caso. Constitui uma tentativa de compreensão das percepções dos professores e das práticas pedagógicas que desenvolvem para efectuar adequações curriculares para alunos com NEE. Centrámo-nos nos professores de um conselho de turma do sétimo ano do terceiro ciclo do ensino básico (3º CEB) que inclui uma aluna com NEE, procurando saber o que pensam sobre o processo de adequação curricular, como o concebem e como o implementam. Como metodologia de recolha dos dados utilizamos as técnicas da entrevista, da análise documental e da observação naturalista. Concluímos que, apesar das dificuldades que expressam e demonstram, os professores assumem a necessidade de implementar adequações curriculares face às NEE dos alunos, como resposta às diferenças e particularidades de cada um, tendo em vista o desenvolvimento de competências essenciais e a conclusão da escolaridade obrigatória. As Adequações Curriculares são percepcionadas como muito vantajosas do ponto de vista da promoção do sucesso educativo para todos os alunos e em particular para os alunos com NEE, proporcionando a estes, acompanhar o currículo mais próximo do que é normal, sentirem-se como “iguais” aos seus colegas, melhorar a sua auto-estima, auto-confiança e motivação ABSTRACT The responsibility of building a school for all must be the ultimate goal of any teacher, creating spaces for joint reflection in order to draw differentiated curricular projects which respond to all students in their plural diversity. Thus, the design and construction of the inclusive school involve changes both in attitudes and practices of the educational agents, and in the structures of the education system regarding the organization and the curriculum management. In this context, the adequacy of the curriculum to students’ special educational needs (SEN) becomes essential in the (re) construction and operationalization of the different curriculum processes. The work now presented was developed through a case study. It attempts to understand the perceptions of teachers and the pedagogical practices they develop to make curricular adjustments for students with SEN. We focused on the teachers of a seventh year class of the third cycle of basic education (3rd CBE) which includes a pupil, a girl, with SEN, trying to find out what they think about the process of adapting the curriculum, how they conceive and implement it. As a methodology of data collection we used different techniques: the interview, the documentary analysis and the naturalistic observation. We concluded that, despite the difficulties that teachers express and demonstrate they assume the need to implement curricular adjustments in relation to pupils with SEN in response to the differences and particularities of each one in order to develop core competencies and to complete compulsory schooling. The Curriculum Adequacies are perceived as very advantageous from the standpoint of promoting educational success for all students and particularly for pupils with SEN, providing the latter the possibility of following the curriculum closer than usual, feeling as "equal" to their schoolmates, improving their self-esteem, self- confidence and motivation.

As relações intergeracionais e as sociedades envelhecidas : Envelhecer numa sociedade não Stop – O território multigeracional de Lisboa Oriental

A dissertação de mestrado subordinada ao tema das Relações Intergeracionais e as Sociedades Envelhecidas surgiu, no âmbito do Mestrado em Educação Social e Intervenção Comunitária, da Escola Superior de Educação de Lisboa e teve como ponto de partida saber se a participação em actividades intergeracionais promove o envelhecimento ativo de 8 mulheres com 65 e mais anos, residentes num território multigeracional de Lisboa Oriental. A abordagem concetual do envelhecimento social, do envelhecimento ativo, das relações intergeracionais e da participação conduziu o estudo, através da triangulação dos instrumentos de análise qualitativa de entrevistas de histórias de vida e de focus group. As mulheres entrevistadas têm entre 65 e 85 anos de idade cronológica, mas em média dizem sentir que têm menos 34 anos. Afirmam, ser jovens de espirito e por isso preferem ser chamadas de seniores. Manifestam que sempre foram e são, mulheres autónomas, livres, independentes, com poder de decisão, com auto-estima elevada e com qualidade de vida. Mulheres que ocupam o tempo em actividades da vida diária, em actividades de tempos livres, e voluntariado. Mulheres reivindicativas, proativas, frontais e determinadas que assumem um papel social ativo envolvendo-se socialmente em todas as actividades produtivas ou orientadas para a performance e em actividades colectivas e ou orientadas para a união, com vista alcançar objetivos comuns. Mulheres, que ganham prestígio e estatuto na comunidade por se envolverem socialmente no processo de tomadas de decisão, organização, execução e avaliação, com as gerações mais novas. São visionárias ancestrais de espirito jovem que abrem novas portas para a construção social da velhice nas sociedades neoliberais e desafiam os humanistas quando afirmam que as atividades produtivas na velhice dão sentido à própria existência. São histórias de mulheres que nos fazem acreditar que a participação social contribui espontaneamente para o diálogo entre as gerações, em todas as fases da vida. - Abstract A dissertation on the subject of Intergenerational Relationships and Societies Aged emerged within the Master of Education Social and Community Intervention, School of Education and Lisbon had as starting point whether participation promotes intergenerational activities on aging 8 active women aged 65 years and older, residing in the territory of Eastern Lisbon multigenerational. The conceptual approach of social aging, active aging, intergenerational relations and participation conducted the study through triangulation of instruments qualitative analysis of interviews and life stories focus group. The women interviewed are between 65 and 85 years of chronological age, but on average say they feel they are under 34 years old. They claim to be young in spirit and so they prefer to be called seniors. Demonstrate that have always been and are women autonomous, free, independent, decision-making, self-esteem and quality of life. Women who occupy the time in activities of daily life, in leisure activities, and volunteering. Women reivindicativas, proactive, front and determined to play an active social role by engaging in socially productive activities or any performance-oriented and collective activities and or targeted at the union in order to achieve common objectives. Women who gain prestige and status in the community by becoming involved socially in the process of decision making, organization, implementation and evaluation with the younger generations. They are young visionary spirit of ancestors that open new doors to the social construction of old age in neoliberal societies and challenge humanists say when productive activities in old age give meaning to their own existence. These are stories of women who have us believe that social participation contributes to spontaneous dialogue between generations, in all stages of life.

O portefólio e a aprendizagem no 1º Ciclo do Ensino Básico

O processo de autorregulação não se desenvolve nos alunos de forma espontânea. Neste sentido, é necessário preparar o trabalho com os alunos, a fim de se conseguir uma autorregulação eficaz e uma apropriação do significado dos objetivos de aprendizagem. No âmbito do Mestrado em Educação Pré-Escolar e Ensino do 1º Ciclo do Ensino Básico realizei um estudo com o objetivo de compreender o contributo do Portefólio, enquanto instrumento (auto) regulador da aprendizagem. Assim as nossas hipóteses de trabalho consistiram em analisar como se negociou com os alunos o processo de construção e como foi dinamizado e utilizado o portefólio, em sala de aula. Com esta análise procurámos perceber também como é que os alunos evoluíram neste percurso em termos da sua apropriação deste instrumento para o desenvolvimento das suas aprendizagens. A metodologia adotada inscreve-se numa abordagem qualitativa com um design próximo da investigação-ação. Os dados foram recolhidos através da observação, inquérito através de entrevistas e questionário e ainda através de análise documental dos portefólios dos alunos. Para a análise de dados utilizou-se a análise de conteúdo, em que as categorias se foram construindo no decurso do trabalho.Os resultados mostram que a apropriação de um trabalho novo é gradual e que a utilização do portefólio, enquanto instrumento de autorregulação, contribui para o desenvolvimento de um conjunto de aprendizagens que se relacionam com as áreas curriculares, mas também com a autonomia. O estudo também mostra que o portefólio assume-se como um instrumento por excelência para a atribuição de feedback, que também possibilita que os alunos melhorem o seu desempenho.

Self-assembly in chains, rings, and branches: a single component system with two critical points

Agências financiadoras: FCT - PEstOE/FIS/UI0618/2011; PTDC/FIS/098254/2008 ERC-PATCHYCOLLOIDS e MIUR-PRIN

O efeito da música na relação entre marca e consumidor

Dissertação apresentada à Escola Superior de Comunicação Social como parte dos requisitos para obtenção de grau de mestre em Publicidade e Marketing.

Self-Scheduling for energy and spinning reserve of wind/CSP plants by a MILP approach

This paper is on the self-scheduling for a power producer taking part in day-ahead joint energy and spinning reserve markets and aiming at a short-term coordination of wind power plants with concentrated solar power plants having thermal energy storage. The short-term coordination is formulated as a mixed-integer linear programming problem given as the maximization of profit subjected to technical operation constraints, including the ones related to a transmission line. Probability density functions are used to model the variability of the hourly wind speed and the solar irradiation in regard to a negative correlation. Case studies based on an Iberian Peninsula wind and concentrated solar power plants are presented, providing the optimal energy and spinning reserve for the short-term self-scheduling in order to unveil the coordination benefits and synergies between wind and solar resources. Results and sensitivity analysis are in favour of the coordination, showing an increase on profit, allowing for spinning reserve, reducing the need for curtailment, increasing the transmission line capacity factor. (C) 2014 Elsevier Ltd. All rights reserved.

The nature of the ordered phase of the confined self-assembled rigid Rod model

We investigate the nature of the ordered phase and the orientational correlations between adjacent layers of the confined three-dimensional self-assembled rigid rod model, on the cubic lattice. We find that the ordered phase at finite temperatures becomes uniaxial in the thermodynamic limit, by contrast to the ground state (partial) order where the orientation of the uncorrelated layers is perpendicular to one of the three lattice directions. The increase of the orientational correlation between layers as the number of layers increases suggests that the unconfined model may also exhibit uniaxial ordering at finite temperatures.

Comunicação matemática - representações utilizadas pelos alunos

Relatório de Estágio apresentado à Escola Superior de Educação de Lisboa para obtenção de grau de mestre em Ensino do 1.º e do 2.º Ciclo do Ensino Básico

Design and construction of tunnels in zones subjected to high convergences

The economic development of a region depends on the speed that people and goods can travel. The reduction of people and goods travel time can be achieved by planning smooth road layouts, which are obtained by crossing natural obstacles such as hills, by tunneling at great depths, and allowing the reduction of the road alignment length. The stress state in rock masses at such depths, either because of the overburden or due to the tectonic conditions of the rock mass induces high convergences of the tunnel walls. These high convergence values are incompatible with the supports structural performance installed in the excavation stabilization. In this article it is intended to evaluate and analyze some of the solutions already implemented in several similar geological and geotechnical situations, in order to establish a methodological principle for the design of the tunnels included in a highway section under construction in the region influenced by the Himalayas, in the state of Himachal Pradesh (India) and referenced by "four laning of Kiratpur to Ner Chowk section".

Experimental study of the porosity and microstructure of self-compacting concrete (SCC) with binary and ternary mixes of fly ash and limestone filler

Abstract Self-compacting concrete (SCC) can soon be expected to replace conventional concrete due to its many advantages. Its main characteristics in the fresh state are achieved essentially by a higher volume of mortar (more ultrafine material) and a decrease of the coarse-aggregates. The use of over-large volumes of additions such as fly ash (FA) and/or limestone filler (LF) can substantially affect the concrete's pore structure and consequently its durability. In this context, an experimental programme was conducted to evaluate the effect on the concrete's porosity and microstructure of incorporating FA and LF in binary and ternary mixes of SCC. For this, a total of 11 SCC mixes were produced: 1 with cement only (C); 3 with C + FA in 30%, 60% and 70% substitution (fad); 3 with C + LF in 30%, 60% and 70% fad; 4 with C + FA + LF in combinations of 10-20%, 20-10%, 20-40% and 40-20% fad, respectively. The results enabled conclusions to be established regarding the SCC's durability, based on its permeability and the microstructure of its pore structure. The properties studied are strongly affected by the type and quantity of additions. The use of ternary mixes also proves to be extremely favourable, confirming the beneficial effect of the synergy between these additions. © 2015 Elsevier Ltd. All rights reserved.

Mechanical performance of concrete made with aggregates from construction and demolition waste recycling plants

This research aims at analysing the mechanical performance of concrete with recycled aggregates (RA) from construction and demolition waste (CDW) from various locations in Portugal. First the characteristics of the various aggregates (natural and recycled) used in the production of concrete were thoroughly analysed. The composition of the RA was determined and several physical and chemical tests of the aggregates were performed. In order to evaluate the mechanical performance of concrete, compressive strength (in cubes and cylinders), splitting tensile strength, modulus of elasticity and abrasion resistance tests were performed. Concrete mixes with RA from CDW from several recycling plants were evaluated, in order to understand the influence that the RA's collection point, and consequently their composition, has on the characteristics of the mixes produced. The analysis of the mechanical performance allowed concluding that the use of RA worsens most of the properties tested, especially when fine RA are used. On the other hand, there was an increase in abrasion resistance when coarse RA were used. In global terms, the use of this type of aggregates, in limited contents, is viable from a mechanical viewpoint. (C) 2015 Elsevier Ltd. All rights reserved.

Study of the rheology of self-compacting concrete with fine recycled concrete aggregates

This work studies the effect of incorporating fine recycled aggregates on the rheology of self-compacting concrete over time (at 15,45 and 90 min). The fine fraction of the natural aggregates was replaced at 0%, 20%, 50% and 100% with recycled sand. The fresh-state properties were studied by empirical tests (slump-flow, J-Ring, L-Box) and fundamental ones in an ICAR rheometer. The mixes with 50% and 100% recycled sand lost their SCC characteristics at 90 min. Contrarily the mix with 20% replacement maintained suitable passing and filling ability. The causes of this trend were an initial increase of plastic viscosity and afterwards an increase of yield stress. The compressive strength of the 50% and 100% replacement mixes decreased significantly and that of the 20% replacement mix less than 10%. (C) 2015 Elsevier Ltd. All rights reserved.

Self-scheduling and bidding strategies of thermal units with stochastic emission constraints

This paper is on the self-scheduling problem for a thermal power producer taking part in a pool-based electricity market as a price-taker, having bilateral contracts and emission-constrained. An approach based on stochastic mixed-integer linear programming approach is proposed for solving the self-scheduling problem. Uncertainty regarding electricity price is considered through a set of scenarios computed by simulation and scenario-reduction. Thermal units are modelled by variable costs, start-up costs and technical operating constraints, such as: forbidden operating zones, ramp up/down limits and minimum up/down time limits. A requirement on emission allowances to mitigate carbon footprint is modelled by a stochastic constraint. Supply functions for different emission allowance levels are accessed in order to establish the optimal bidding strategy. A case study is presented to illustrate the usefulness and the proficiency of the proposed approach in supporting biding strategies. (C) 2014 Elsevier Ltd. All rights reserved.

Durability performance of self-compacting concrete (SCC) with binary and ternary mixes of fly ash and limestone filler

The basic objective of this work is to evaluate the durability of self-compacting concrete (SCC) produced in binary and ternary mixes using fly ash (FA) and limestone filler (LF) as partial replacement of cement. The main characteristics that set SCC apart from conventional concrete (fundamentally its fresh state behaviour) essentially depend on the greater or lesser content of various constituents, namely: greater mortar volume (more ultrafine material in the form of cement and mineral additions); proper control of the maximum size of the coarse aggregate; use of admixtures such as superplasticizers. Significant amounts of mineral additions are thus incorporated to partially replace cement, in order to improve the workability of the concrete. These mineral additions necessarily affect the concrete’s microstructure and its durability. Therefore, notwithstanding the many well-documented and acknowledged advantages of SCC, a better understanding its behaviour is still required, in particular when its composition includes significant amounts of mineral additions. An ambitious working plan was devised: first, the SCC’s microstructure was studied and characterized and afterwards the main transport and degradation mechanisms of the SCC produced were studied and characterized by means of SEM image analysis, chloride migration, electrical resistivity, and carbonation tests. It was then possible to draw conclusions about the SCC’s durability. The properties studied are strongly affected by the type and content of the additions. Also, the use of ternary mixes proved to be extremely favourable, confirming the expected beneficial effect of the synergy between LF and FA. © 2015 RILEM.